Prof Vlatko Vedral FInstP

Abstract:

We construct a quantumness witness following the work of Alicki & van Ryn (AvR). We reformulate the AvR test by defining it for quantum states rather than for observables. This allows us to identify the necessary quantities and resources to detect quantumness for any given system. The first quantity turns out to be the purity of the system. When applying the witness to a system with even moderate mixedness, the protocol is unable to reveal any quantumness. We then show that having many copies of the system leads the witness to reveal quantumness. This seems contrary to the Bohr correspondence, which asserts that, in the large-number limit, quantum systems become classical, whereas the witness shows quantumness when several non-quantum systems, as determined by the witness, are considered together. However, the resources required to detect the quantumness increase dramatically with the number of systems. We apply the quantumness witness for systems that are highly mixed but in the large-number limit that resembles nuclear magnetic resonance (NMR) systems. We make several conclusions about detecting quantumness in NMR-like systems. © 2012 The Royal Society.

Abstract:

We propose a feasible approach to test quantum nonlocality with two qubits dispersively coupled to a driven cavity. Our proposal is based on spectral joint measurements of two qubits, i.e., their quantum states in the computational basis states {|kl,k,l=0,1} can be measured nondestructively by detecting the steady-state transmission spectra of the driven cavity. With this kind of measurements, the existence of Bell state can be robustly confirmed instead of conventional quantum state tomography. Then this kind of measurements is further utilized to test CHSH-Bell inequality. The advantage and feasibility of our proposal are also discussed. © Copyright EPLA, 2012.

Abstract:

Many intramolecular electron transfer (ET) reactions in biology are mediated by metal centers in proteins. This process is commonly described by a model of diffusive hopping according to the semiclassical theories of Marcus and Hopfield. However, recent studies have raised the possibility that nontrivial quantum mechanical effects play a functioning role in certain biomolecular processes. Here, we investigate the potential effects of quantum coherence in biological ET by extending the semiclassical model to allow for the possibility of quantum coherent phenomena using a quantum master equation based on the Holstein Hamiltonian. We test the model on the structurally defined chain of seven iron-sulfur clusters in nicotinamide adenine dinucleotide plus hydrogen:ubiquinone oxidoreductase (complex I), a crucial respiratory enzyme and one of the longest chains of metal centers in biology. Using experimental parameters where possible, we find that, in limited circumstances, a small quantum mechanical contribution can provide a marked increase in the ET rate above the semiclassical diffusive-hopping rate. Under typical biological conditions, our model reduces to well-known diffusive behavior. © 2012 American Physical Society.