Planetary atmosphere observation analysis

Abstract:

In this paper, we present the first measurements of the vertical distribution of cyanogen (${{\rm{C}}}_{2}{{\rm{N}}}_{2}$) in Titan's lower atmosphere at different latitudes and seasons, using Cassini's Composite Infrared Spectrometer far-infrared data. We also study the vertical distribution of three other minor species detected in our data: methylacetylene (${{\rm{C}}}_{3}{{\rm{H}}}_{4}$), diacetylene (${{\rm{C}}}_{4}{{\rm{H}}}_{2}$), and ${{\rm{H}}}_{2}{\rm{O}}$, in order to compare them to ${{\rm{C}}}_{2}{{\rm{N}}}_{2}$, but also to get an overview of their seasonal and meridional variations in Titan's lower stratosphere from 85 km to 225 km. We measured an average volume mixing ratio of ${{\rm{C}}}_{2}{{\rm{N}}}_{2}$ of $6.2\pm 0.8\times {10}^{-11}$ at 125 km at the equator, but poles exhibit a strong enrichment in ${{\rm{C}}}_{2}{{\rm{N}}}_{2}$ (up to a factor 100 compared to the equator), greater than what was measured for ${{\rm{C}}}_{3}{{\rm{H}}}_{4}$ or ${{\rm{C}}}_{4}{{\rm{H}}}_{2}$. Measuring ${{\rm{C}}}_{2}{{\rm{N}}}_{2}$ profiles provides constraints on the processes controlling its distribution, such as bombardment by Galactic Cosmic Rays which seem to have a smaller influence on ${{\rm{C}}}_{2}{{\rm{N}}}_{2}$ than predicted by photochemical models.

Abstract:

Launched onboard the BepiColombo Mercury Planetary Orbiter (MPO) in October 2018, the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS) is on its way to planet Mercury. MERTIS consists of a push-broom IR-spectrometer (TIS) and a radiometer (TIR), which operate in the wavelength regions of 7-14 μm and 7-40 μm, respectively. This wavelength region is characterized by several diagnostic spectral signatures: the Christiansen feature (CF), Reststrahlen bands (RB), and the Transparency feature (TF), which will allow us to identify and map rock-forming silicates, sulfides as well as other minerals. Thus, the instrument is particularly well-suited to study the mineralogy and composition of the hermean surface at a spatial resolution of about 500 m globally and better than 500 m for approximately 5-10% of the surface. The instrument is fully functional onboard the BepiColombo spacecraft and exceeds all requirements (e.g., mass, power, performance). To prepare for the science phase at Mercury, the team developed an innovative operations plan to maximize the scientific output while at the same time saving spacecraft resources (e.g., data downlink). The upcoming fly-bys will be excellent opportunities to further test and adapt our software and operational procedures. In summary, the team is undertaking action at multiple levels, including performing a comprehensive suite of spectroscopic measurements in our laboratories on relevant analog materials, performing extensive spectral modeling, examining space weathering effects, and modeling the thermal behavior of the hermean surface.

Abstract:

Here we search for hydrogen chloride (HCl) in Neptune’s stratosphere using observations of the 1876.22 GHz J=3–2 transition from the Heterodyne Instrument for the Far-Infrared (HIFI) on Herschel. Observations comprise a 7.2 hr disc-averaged integration, originally designed to investigate stratospheric methane. Significant HCl emission was not detected. Instead, we determine upper limits using step-type abundance profiles, defined by zero deep abundance and uniform volume mixing ratio for pressures less than a transition pressure (assumed to be 0.1 or 1 mbar). These profiles are a reasonable first-order approximation for an externally sourced species; at higher pressures HCl is expected to be removed by aerosol scavenging and reactions with ammonia. The 3 upper limits are 0.70 parts per billion (ppb) for a 0.1 mbar transition pressure and 0.076 ppb for a 1 mbar transition pressure. These upper limits are the most stringent to date and are consistent with current estimates of interplanetary dust particle flux and the hypothesis that Neptune experienced a large comet impact in the past 1000 years.

Abstract:

Aims: The ExoMars Trace Gas Orbiter (TGO) was sent to Mars in March 2016 to search for trace gases diagnostic of active geological or biogenic processes.

Methods: We report the first observation of the spectral features of Martian ozone (O3) in the mid-infrared range using the Atmospheric Chemistry Suite (ACS) Mid-InfaRed (MIR) channel, a cross-dispersion spectrometer operating in solar occultation mode with the finest spectral resolution of any remote sensing mission to Mars.

Results: Observations of ozone were made at high northern latitudes (> 65◦N) prior to the onset of the 2018 global dust storm (Ls = 163–193◦). During this fast transition phase between summer and winter ozone distribution, the O3 volume mixing ratio observed is 100–200 ppbv near 20 km. These amounts are consistent with past observations made at the edge of the southern polar vortex in the ultraviolet range. The observed spectral signature of ozone at 3000–3060 cm−1 directly overlaps with the spectral range of the methane (CH4) ν3 vibration-rotation band, and it, along with a newly discovered CO2 band in the same region, may interfere with measurements of methane abundance.