Planetary atmosphere observation analysis

Abstract:

Directional emissivity (DE) describes how the emissivity of an isothermal surface changes with viewing angle across thermal infrared wavelengths. The Oxford Space Environment Goniometer (OSEG) is a novel instrument that has been specifically designed to measure the DE of regolith materials derived from planetary surfaces. The DE of Nextel high emissivity black paint was previously measured by the OSEG and showed that the measured emissivity decreases with increasing emission angle, from an emissivity of 0.97 ± 0.01 at 0° emission angle to an emissivity of 0.89± 0.01 at 71° emission angle. The Nextel target measured was isothermal (<0.1 K surface temperature variation) and the observed change in emissivity was due to Fresnel related effects and was not due to non-isothermal effects. Here we apply several increasingly complex modelling techniques to model the measured DE of Nextel black paint. The modelling techniques used here include the Hapke DE model, the Fresnel equations, a multiple slope Fresnel model and a Monte Carlo ray-tracing model. It was found that only the Monte Carlo raytracing model could accurately fit the OSEG measured Nextel data. We show that this is because the Monte Carlo ray-tracing model is the only model that fully accounts for the surface roughness of the Nextel surface by including multiple scattering effects.

Abstract:

© 2018 Of the C3Hxhydrocarbons, propane (C3H8) and propyne (methylacetylene, CH3C2H) were first detected in Titan's atmosphere during the Voyager 1 flyby in 1980. Propene (propylene, C3H6) was first detected in 2013 with data from the Composite InfraRed Spectrometer (CIRS) instrument on Cassini. We present the first measured abundance profiles of propene on Titan from radiative transfer modeling, and compare our measurements to predictions derived from several photochemical models. Near the equator, propene is observed to have a peak abundance of 10 ppbv at a pressure of 0.2 mbar. Several photochemical models predict the amount at this pressure to be in the range 0.3–1 ppbv and also show a local minimum near 0.2 mbar which we do not see in our measurements. We also see that propene follows a different latitudinal trend than the other C3molecules. While propane and propyne concentrate near the winter pole, transported via a global convective cell, propene is most abundant above the equator. We retrieve vertical abundances profiles between 125 km and 375 km for these gases for latitude averages between 60°S–20°S, 20°S–20°N, and 20°N–60°N over two time periods, 2004 through 2009 representing Titan's atmosphere before the 2009 equinox, and 2012 through 2015 representing time after the equinox. Additionally, using newly corrected line data, we determined an updated upper limit for allene (propadiene, CH2CCH2, the isomer of propyne). We claim a 3-σ upper limit mixing ratio of 2.5 × 10−9 within 30° of the equator. The measurements we present will further constrain photochemical models by refining reaction rates and the transport of these gases throughout Titan's atmosphere.