Quantum spin dynamics

Abstract:

Coupling between a crystal of di(phenyl)-(2,4,6-trinitrophenyl)iminoazanium (DPPH) radicals and a superconducting microwave resonator is investigated in a circuit quantum electrodynamics (cQED) architecture. The crystal exhibits paramagnetic behavior above 4 K, with antiferromagnetic correlations appearing below this temperature, and we demonstrate strong coupling at base temperature. The magnetic resonance acquires a field angle dependence as the crystal is cooled down, indicating anisotropy of the exchange interactions. These results show that multi-spin modes in organic crystals are suitable for cQED, offering a platform for their coherent manipulation. They also utilize the cQED architecture as a way to probe spin correlations at low temperature.

Abstract:

The endohedral fullerene $^{15}\mathrm{N@C}_{60}$ has narrow electron paramagnetic resonance lines which have been proposed as the basis for a condensed-matter portable atomic clock. We measure the low-frequency spectrum of this molecule, identifying and characterizing a clock transition at which the frequency becomes insensitive to magnetic field. We infer a linewidth at the clock field of 100 kHz. Using experimental data, we are able to place a bound on the clock's projected frequency stability. We discuss ways to improve the frequency stability to be competitive with existing miniature clocks.