Methane precipitation in ice giant atmospheres

Astronomy & Astrophysics EDP Sciences (2025)

Authors:

D Toledo, Pascal Rannou, Patrick Irwin, Bruno de Batz de Trenquelléon, Michael Roman, Victor Apestigue, Ignacio Arruego, Margarita Yela

Abstract:

<jats:p>Voyager-2 radio occultation measurements have revealed changes in the atmospheric refractivity within a 2-4 km layer near the 1.2-bar level in Uranus and the 1.6-bar level in Neptune. These changes were attributed to the presence of a methane cloud, consistent with the observation that methane concentration decreases with altitude above these levels, closely following the saturation vapor pressure. However, no clear spectral signatures of such a cloud have been detected thus far in the spectra acquired from both planets. We examine methane cloud properties in the atmospheres of the ice giants, including vertical ice distribution, droplet radius, precipitation rates, timescales, and total opacity, employing microphysical simulations under different scenarios. We used a one-dimensional (1D) cloud microphysical model to simulate the formation of methane clouds in the ice giants. The simulations include the processes of nucleation, condensation, coagulation, evaporation, and precipitation, with vertical mixing simulated using an eddy-diffusion profile (K_eddy). Our simulations show cloud bases close to 1.24 bars in Uranus and 1.64 bars in Neptune, with droplets up to 100 μm causing high settling velocities and precipitation rates (∼370 mm per Earth year). The high settling velocities limit the total cloud opacity, yielding values at 0.8 μm of ∼0.19 for Uranus and ∼0.35 for Neptune, using K_ eddy = 0.5 m^2 s^-1 and a deep methane mole fraction (μ_CH_4) of 0.04. In addition, lower K_ eddy or μ_CH_4 values result in smaller opacities. Methane supersaturation is promptly removed by condensation, controlling the decline in μ_CH_4 with altitude in the troposphere. However, the high settling velocities prevent the formation of a permanent thick cloud. Stratospheric hazes made of ethane or acetylene ice are expected to evaporate completely before reaching the methane condensation level. Since hazes are required for methane heterogeneous nucleation, this suggests either a change in the solid phase properties of the haze particles, inhibiting evaporation, or the presence of photochemical hazes.</jats:p>

Clouds and Ammonia in the Atmospheres of Jupiter and Saturn Determined From a Band‐Depth Analysis of VLT/MUSE Observations

Journal of Geophysical Research E: Planets American Geophysical Union 130:1 (2025)

Authors:

Patrick GJ Irwin, Steven M Hill, Leigh N Fletcher, Charlotte Alexander, John H Rogers

The Peregrine Ion Trap Mass Spectrometer (PITMS): Results from a CLPS-delivered Mass Spectrometer

The Planetary Science Journal American Astronomical Society 6:1 (2025) 14

Authors:

Barbara A Cohen, Simeon J Barber, Aleksandra J Gawronska, Feargus AJ Abernethy, Natalie M Curran, Phillip A Driggers, William M Farrell, David J Heather, Christopher Howe, Peter F Landsberg, Veneranda López-Días, Andrew D Morse, Thomas Morse, Michael J Poston, Parvathy Prem, Roland Trautner, Orenthal J Tucker, Tristram J Warren, Stefano Boccelli

archNEMESIS: An Open-Source Python Package for Analysis of Planetary Atmospheric Spectra

Journal of Open Research Software Ubiquity Press 13:1 (2025)

Authors:

Juan Alday, Joseph Penn, Patrick Irwin, Jonathon Mason, Jingxuan Yang, Jack Dobinson

Abstract:

ArchNEMESIS is an open-source Python package developed for the analysis of remote sensing spectroscopic observations of planetary atmospheres. It is based on the widely used NEMESIS radiative transfer and retrieval tool, which has been extensively used for the investigation of a wide variety of planetary environments. The main goal of archNEMESIS is to provide the capabilities of its Fortran-based predecessor, keeping or exceeding the efficiency in the calculations, and benefitting from the advantages Python tools provide in terms of usability and portability. ArchNEMESIS enables users to compute synthetic spectra for a wide variety of planetary atmospheres, supporting multiple spectral ranges, viewing geometries (e.g., nadir, limb, and solar occultation), and radiative transfer scenarios, including multiple scattering. Furthermore, it provides tools to fit observed spectra and retrieve atmospheric and surface parameters using both optimal estimation and nested sampling retrieval schemes. The code, stored in a public GitHub repository under a GPL-v3.0 license, is accompanied by detailed documentation available at https://archnemesis.readthedocs.io/.

Magma Ocean Evolution at Arbitrary Redox State

Journal of Geophysical Research: Planets American Geophysical Union 129:12 (2024) e2024JE008576

Authors:

Harrison Nicholls, Tim Lichtenberg, Dan J Bower, Raymond Pierrehumbert

Abstract:

Interactions between magma oceans and overlying atmospheres on young rocky planets leads to an evolving feedback of outgassing, greenhouse forcing, and mantle melt fraction. Previous studies have predominantly focused on the solidification of oxidized Earth‐similar planets, but the diversity in mean density and irradiation observed in the low‐mass exoplanet census motivate exploration of strongly varying geochemical scenarios. We aim to explore how variable redox properties alter the duration of magma ocean solidification, the equilibrium thermodynamic state, melt fraction of the mantle, and atmospheric composition. We develop a 1D coupled interior‐atmosphere model that can simulate the time‐evolution of lava planets. This is applied across a grid of fixed redox states, orbital separations, hydrogen endowments, and C/H ratios around a Sun‐like star. The composition of these atmospheres is highly variable before and during solidification. The evolutionary path of an Earth‐like planet at 1 AU ranges between permanent magma ocean states and solidification within 1 Myr. Recently solidified planets typically host H 2 O ${\mathrm{H}}_{2}\mathrm{O}$ ‐ or H 2 ${\mathrm{H}}_{2}$ ‐dominated atmospheres in the absence of escape. Orbital separation is the primary factor determining magma ocean evolution, followed by the total hydrogen endowment, mantle oxygen fugacity, and finally the planet's C/H ratio. Collisional absorption by H 2 ${\mathrm{H}}_{2}$ induces a greenhouse effect which can prevent or stall magma ocean solidification. Through this effect, as well as the outgassing of other volatiles, geochemical properties exert significant control over the fate of magma oceans on rocky planets.