Solar system

Abstract:

Titan, Saturn’s largest satellite, maintains an atmosphere composed primarily of nitrogen (N2) and methane (CH4) that leads to complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced 15N abundances compared to Earth and Titan’s dominant nitrogen (N2) reservoir. The 14N/15N isotopic ratio in Titan’s nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan’s large nitrogen abundance. Using high signal-to-noise ratio (>13), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array Band 6 receiver (211–275 GHz), we measure the 14N/15N and 12C/13C isotopic ratios of acetonitrile (CH3CN) in Titan’s stratosphere. Using the NEMESIS, we derived the CH3CN/13CH3CN ratio to be 89.2 ± 7.0 and the CH3CN/CH313CN ratio to be 91.2 ± 6.0, in agreement with the 12C/13C ratio in Titan’s methane and other solar system species. We found the 14N/15N isotopic ratio to be 68.9 ± 4.2, consistent with previously derived values for HCN and HC3N, confirming an enhanced 15N abundance in Titan’s nitriles compared with the bulk atmospheric N2 value of 14N/15N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N2 at high altitudes.

Abstract:

Whether or not there is a particulate layer in the lowest 10 km of the Venusian atmosphere is still an open question. Some of the past in situ experiments showed the presence of a detached particulate layer, and a few suggested the existence of finely dispersed aerosols, while other instruments supported the idea of no particulate matter in the deep atmosphere. In this work, we investigate the presence of a near‐surface particulate layer (NSPL) using in situ data from the Venera 13 mission. While the original spectrophotometric data from Venera 13 were lost, we have reconstructed a part of this data by digitizing the old graphic material and selected the eight most reliable Venera 13 downward radiance profiles from 0.48 to 0.8 μ ${\upmu }$ m for our retrievals. The retrievals suggest the existence of the particulate layer with a peak in the altitude range of 3.5–5 km. They further indicate a log‐normal particle size distribution with a mean radius between 0.6 and 0.85 μ ${\upmu }$ m. The retrievals constrain the real refractive index of the particles to lie around the range of 1.4–1.6, with the imaginary refractive index of a magnitude of 10 − 3 ${10}^{-3}$ . Based on refractive index retrievals, uplifted basalt particles or volcanic ash could be responsible for near‐surface particulates. In comparison, volatile condensates appear less likely to be behind the formation of NSPL.