Thin film quantum materials

Abstract:

The origin of high-temperature superconductivity in iron-based superconductors is still not understood; determination of the pairing symmetry is essential for understanding the superconductivity mechanism. In the iron-based superconductors that have hole pockets around the Brillouin zone centre and electron pockets around the zone corners, the pairing symmetry is generally considered to be s±, which indicates a sign change in the superconducting gap between the hole and electron pockets. For the iron-based superconductors with only hole pockets, however, a couple of pairing scenarios have been proposed, but the exact symmetry is still controversial. Here we determine that the pairing symmetry in KFe2As2—which is a prototypical iron-based superconductor with hole pockets both around the zone centre and around the zone corners—is also of the s± type. Our laser-based angle-resolved photoemission measurements have determined the superconducting gap distribution and identified the locations of the gap nodes on all the Fermi surfaces around the zone centres and the zone corners. These results unify the pairing symmetry in hole-doped iron-based superconductors and point to spin fluctuation as the pairing glue in generating superconductivity.

Abstract:

In half-metallic systems, electronic conduction is mediated by a single spin species, offering enormous potential for spintronic devices. Here, using microscopic-area angle-resolved photoemission, we show that a spin-polarised two-dimensional hole gas is naturally realised in the polar magnetic semiconductor AgCrSe₂ by an intrinsic self-doping at its CrSe₂-terminated surface. Through comparison with first-principles calculations, we unveil a striking role of spin-orbit coupling for the surface hole gas, unlocked by both bulk and surface inversion symmetry breaking, suggesting routes for stabilising complex magnetic textures in the surface layer of AgCrSe₂.

Abstract:

Magnetic exchange springs (ESs) are composed of exchange-coupled hard and soft magnetic layers, i.e., layers with high and low anisotropy, respectively. The moments in the soft layer can be wound up by applying an external field, which has to be smaller than the anisotropy field of the hard layer. Alternatively, an ES can be realized by biasing the soft magnetic layer by two adjacent hard magnetic layers with different magnetic anisotropy directions. We have fabricated an ES layer stack by magnetron sputter deposition. As the hard magnetic bottom layer, we used epitaxial FePt L10, and as the top layer Co with both layers having different in-plane easy axes. These hard layers pin the moments of a soft permalloy (Ni81Fe19) layer sandwiched between them, winding up an ES at remanence. The anisotropy of the polycrystalline top Co layer was engineered by glancing-angle deposition to have in-plane easy axis anisotropy perpendicular to the easy direction of the bottom layer. Using soft x-ray spectroscopy and magneto-optical measurements, we found the in-plane ES to extend from the soft layer into the top layer of our FePt/permalloy/Co trilayer structure.

Abstract:

To harness the intriguing properties of 2D van der Waals (vdW) ferromagnets (FMs) for versatile applications, the key challenge lies in the reliable material synthesis for scalable device production. Here, the epitaxial growth of single-crystalline 1T-CrTe2 thin films on 2-inch sapphire substrates are demonstrated. Benefiting from the uniform surface energy of the dangling bond-free Al2O3(0001) surface, the layer-by-layer vdW growth mode is observed right from the initial growth stage, which warrants precise control of the sample thickness beyond three monolayer and homogeneous surface morphology across the entire wafer. Moreover, the presence of the Coulomb interaction at the CrTe2/Al2O3 interface plays an important role in tailoring the anomalous Hall response, and the structural optimization of the CrTe2-based spin-orbit torque device leads to a substantial switching power reduction by 54%. The results may lay out a general framework for the design of energy-efficient spintronics based on configurable vdW FMs.