Thin film quantum materials

Abstract:

Metallic nanoparticles containing 3d elements are generally susceptible to oxidation leading to a deterioration of desired properties. Here, the oxidation behavior of differently sized FePt nanoparticles is experimentally studied by x-ray photoelectron spectroscopy (XPS) and compared to a FePt reference film. For all as-prepared metallic samples the common features are the formation of Fe(3+), becoming detectable for exposures to pure oxygen above 10(6) langmuir whereas under identical conditions the Pt(0) signal is conserved. Most notably, these features are independent of particle size. Annealing at 650 degrees C, however, affects small and large FePt particles differently. While large particles as well as the reference film show a 100-1000 times enhanced resistance against oxidation, small FePt particles (diameter 5 nm) exhibit no such enhancement due to the thermal treatment. Additional XPS intensity analysis in combination with model calculations leads to an explanation of this observation in terms of Pt segregating to the surface. In large particles and films the thickness of the resulting Pt layer is sufficient to strongly impede oxidation, while in small particles this layer is incomplete and no longer provides protection against oxidation.

Abstract:

The magnetic domain structure of MnAs stripes exhibits a number of domain transitions that are inclined with respect to the system's easy axis. Among them are laterally confined slanted and V-shaped domain walls, as well as extended zigzag shaped transitions that are running along the stripe axis. The nature of these unusual domain transitions was investigated with the help of micromagnetic simulations and compared with experimental magnetic force microscopy (MFM) images. All types of inclined walls result from the underlying three-dimensional domain structure of the wires. In the domain transition region, the underlying flux closure pattern gets asymmetrically distorted in the cross-sectional wire plane as the system changes its domain types. The results of the simulations are in excellent qualitative agreement with the stray field patterns observed with MFM. © 2009 American Institute of Physics.

Abstract:

We investigate the temperature-dependent hysteresis of the stripe state of MnAs thin films on GaAs(001) in the phase coexistence regime. The underlying magnetic domain structure is described employing an analytic model for stripe arrays with perpendicular anisotropy. In the framework of this model the magnetic properties of the MnAs stripe array can be unraveled as a combined effect of magnetostatic coupling of neighboring ferromagnetic stripes and the tendency to form antiparallel magnetic domains within the individual ferromagnetic stripes. The detailed analysis reveals the balance of demagnetization energy and domain-wall energy for the domain structure. It is capable to quantitatively predict the temperature dependency of the coercive field of MnAs thin films on GaAs(001) in the phase coexistence regime. Further, the analytic model allows for an understanding of the unusual magnetic reversal properties as a consequence of the temperature-driven geometrical variations in the stripe array. Here, it is the energy difference of the single and the multidomain states associated with the geometrical variations, which is the driving factor, rather than the temperature dependence of the magnetic properties themselves. Although the stripe array of MnAs thin films can be in an interstripe as well as in an intrastripe coupling state, the magnetization reversal is entirely determined by interstripe coupling. © 2008 The American Physical Society.

Abstract:

The catalytic growth by chemical vapor deposition is a well-established route to single-wall carbon nanotubes (SWNTs). In this process, the choice and preparation of the metal catalyst determines the nanotube growth. The system Fe/Mo is known to yield a large percentage of SWNTs. In order to make use of SWNTs in electronic or electromechanical devices, the patterned growth relies on lithography techniques like photolithography or electron beam lithography. Many standard lithographic processes, i.e. the combination of photoresist and lift-off procedure, are not compatible with Fe/Mo catalyst solutions, resulting in low SWNT yield. We present a systematic study of the influence of the catalyst solvent on the patterned SWNT growth. Most remarkably, the use of water as a solvent is the basis for integrating SWNT with the established processing techniques due to its compatibility with any lithographic process and the simultaneous high SWNT yield. © 2007 Elsevier B.V. All rights reserved.

Abstract:

At the basis of future applications of spin electronics are ferromagnetic films that have a Curie temperature above room temperature, a crystal structure that allows for epitaxial growth on common semiconductor surfaces, and a high degree of spin polarization at the Fermi level. A class of ternary compounds, the so‐called Heusler alloys, combine these requirements as they are lattice‐matched to many compound semiconductors, have a compatible crystal structure (face‐centered cubic), and show high Curie temperatures. Moreover, calculations suggested that some Heusler alloys may belong to the magnetic class of half‐metals that is characterized by a 100% spin polarization at the Fermi level. We review the work on epitaxial‐Heusler alloy films on semiconductor surfaces. Special emphasis is laid on molecular‐beam epitaxy (MBE), as this growth method allows for an in situ control of the growth and structure of the material. Taking Co2FeSi on GaAs as an example, the structural and magnetic properties of MBE‐grown samples will be discussed.