Andrea Cavalleri

Abstract:

Interlayer transport in high-TC cuprates is mediated by superconducting tunneling across the CuO2 planes. For this reason, the terahertz frequency optical response is dominated by one or more Josephson plasma resonances and becomes highly nonlinear at fields for which the tunneling supercurrents approach their critical value IC. These large terahertz nonlinearities are in fact a hallmark of superconducting transport. Surprisingly, however, they have been documented in La2-xBaxCuO4 (LBCO) also above TC for doping values near x=1/8 and interpreted as an indication of superfluidity in the stripe phase. Here, electric-field-induced second harmonic is used to study the dynamics of time-dependent interlayer voltages when LBCO is driven with large-amplitude terahertz pulses, in search of other characteristic signatures of Josephson tunneling in the normal state. We show that this method is sensitive to the voltage anomalies associated with 2πJosephson phase slips, which near x=1/8 are observed both below and above TC. These results document a regime of nonlinear transport that shares features of fluctuating stripes and superconducting phase dynamics.

Abstract:

Resonant optical excitation of certain molecular vibrations in κ−(BEDT−TTF)2Cu[N(CN)2]Br has been shown to induce transient superconductinglike optical properties at temperatures far above equilibrium Tc. Here, we report experiments across the bandwidth-tuned phase diagram of this class of materials, and study the Mott insulator κ−(BEDT−TTF)2Cu[N(CN)2]Cl and the metallic compound κ−(BEDT−TTF)2Cu(NCS)2. We find nonequilibrium photoinduced superconductivity only in κ−(BEDT−TTF)2Cu[N(CN)2]Br, indicating that the proximity to the Mott insulating phase and possibly the presence of preexisting superconducting fluctuations are prerequisites for this effect.

Abstract:

The crystal structure of a solid largely dictates its electronic, optical and mechanical properties. Indeed, much of the exploration of quantum materials in recent years including the discovery of new phases and phenomena in correlated, topological and two-dimensional materials—has been based on the ability to rationally control crystal structures through materials synthesis, strain engineering or heterostructuring of van der Waals bonded materials. These static approaches, while enormously powerful, are limited by thermodynamic and elastic constraints. An emerging avenue of study has focused on extending such structural control to the dynamical regime by using resonant laser pulses to drive vibrational modes in a crystal. This paradigm of ‘nonlinear phononics’ provides a basis for rationally designing the structure and symmetry of crystals with light, allowing for the manipulation of functional properties at high speed and, in many instances, beyond what may be possible in equilibrium. Here we provide an overview of the developments in this field, discussing the theory, applications and future prospects of optical crystal structure engineering.

Abstract:

This Perspective addresses the design, creation, characterization and control of synthetic quantum materials with strong electronic correlations. We show how emerging synergies between theoretical/computational approaches and materials design/experimental probes are driving recent advances in the discovery, understanding and control of new electronic behaviour in materials systems with interesting and potentially technologically important properties. The focus here is on transition metal oxides, where electronic correlations lead to a myriad of functional properties including superconductivity, magnetism, Mott transitions, multiferroicity and emergent behaviour at picoscale-designed interfaces. Current opportunities and challenges are also addressed, including possible new discoveries of non-equilibrium phenomena and optical control of correlated quantum phases of transition metal oxides.

Abstract:

High power mid-infrared light pulses of tunable pulse length were generated to stabilize light-induced superconductivity in K3C60 for nanoseconds. This metastable state showed a vanishing electrical resistance at five times the material's equilibrium critical temperature.