Prof Ramin Golestanian

Abstract:

Using a generalization of the Poisson-Boltzmann equation, dynamics of counterion condensation is studied. For a single charged plate in the presence of counterions, it is shown that the approach to equilibrium is diffusive. In the far from equilibrium case of a moving charged plate, a dynamical counterion condensation transition occurs at a critical velocity. The complex dynamic behavior of the counterion cloud is shown to lead to a novel nonlinear force-velocity relation for the moving plate.

Abstract:

The effective elasticity of highly charged stiff polyelectrolytes is studied in the presence of counterions, with and without added salt. The rigid polymer conformations may become unstable due to an effective attraction induced by counterion density fluctuations. Instabilities at the longest, or intermediate length scales may signal collapse to globule, or necklace states, respectively. In the presence of added-salt, a generalized electrostatic persistence length is obtained, which has a nontrivial dependence on the Debye screening length.

Abstract:

In a recent Letter, Gurovitch and Sens studied the adsorption of a weakly charged polyelectrolyte chain onto an oppositely charged colloidal particle. By using a variational technique they found that the colloidal particle can adsorb a polymer of higher charge than its own, and thus be ``overcharged.'' I argue that the observed overcharging by a factor of 16/5 is indeed an artifact of the approximations involved in the study. Moreover, I show that the existence of overcharging depends crucially on the choice of the trial wave function, contrary to their claim.

Abstract:

A path integral formulation is developed to study the spectrum of radiation from a perfectly reflecting (conducting) surface. It allows us to study arbitrary deformations in space and time. The spectrum is calculated to second order in the height function. For a harmonic traveling wave on the surface, we find many different regimes in which the radiation is restricted to certain directions. It is shown that high frequency photons are emitted in a beam with relatively low angular dispersion whose direction can be controlled by the mechanical deformations of the plate.

Abstract:

A path integral formulation is developed for the dynamic Casimir effect. It allows us to study arbitrary deformations in space and time of the perfectly reflecting (conducting) boundaries of a cavity. The mechanical response of the intervening vacuum is calculated to linear order in the frequency-wavevector plane, using which a plethora of interesting phenomena can be studied. For a single corrugated plate we find a correction to mass at low frequencies, and an effective shear viscosity at high frequencies that are both anisotropic. The anisotropy is set by the wavevector of the corrugation. For two plates, the mass renormalization is modified by a function of the ratio between the separation of the plates and the wave-length of corrugations. The dissipation rate is not modified for frequencies below the lowest optical mode of the cavity, and there is a resonant dissipation for all frequencies greater than that. In this regime, a divergence in the response function implies that such high frequency deformation modes of the cavity can not be excited by any macroscopic external forces. This phenomenon is intimately related to resonant particle creation. For particular examples of two corrugated plates that are stationary, or moving uniformly in the lateral directions, Josephson-like effects are observed. For capillary waves on the surface of mercury a renormalization to surface tension, and sound velocity is obtained.