Prof. Patrick Irwin

Abstract:

In this work, we have analyzed images provided by the Hubble Space Telescope's Wide Field Camera 3 (HST/WFC3) in December 2016, with a spectral coverage from the ultraviolet to the near infrared. We have obtained the spectral reflectivity of the GRS and its surroundings, with particular emphasis on selected, dynamically interesting regions. A spectral characterization of the GRS area is performed following two different procedures: (a) in terms of Altitude/Opacity and Color Indices (AOI and CI); (b) by means of automatic spectral classification. We used the NEMESIS radiative transfer suite to retrieve the main atmospheric parameters (e.g., particle vertical and size distributions, refractive indices) that are able to explain the observed spectral reflectivity. The optimal a priori model atmosphere used for the retrievals is obtained from a grid of about 12,000 different atmospheric models, and choosing the one that best fits South Tropical Zone (STrZ) spectra and its observed limb-darkening. We conclude that the spectral reflectivity of the GRS area is well reproduced with the following layout: (a) a stratospheric haze with its base near the 100 mbar level, with optical depths at 900 nm of the order of unity and particles with a size of 0.3 μm; (b) a more vertically extended tropospheric haze, with τ (900 nm) ∼10 down to 500 mbar and micron sized particles. Both haze layers show a stronger short wavelength absorption, and thus both act as chromophores. The altitude difference between clouds tops in the GRS and surrounding areas is ∼10 km.

Abstract:

The Ultraviolet Spectrograph (UVS) instrument on the Juno mission records far-ultraviolet reflected sunlight from Jupiter. These spectra are sensitive to the abundances of chemical species in the upper atmosphere and to the distribution of the stratospheric haze layer. We combine observations from the first 30 perijoves of the mission in order to study the meridional distribution of acetylene (C2H2) in Jupiter's stratosphere. We find that the abundance of C2H2 decreases toward the poles by a factor of 2–4, in agreement with previous analyses of mid-infrared spectra. This result is expected from insolation rates: near the equator, the UV solar flux is higher, allowing more C2H2 to be generated from the UV photolysis of CH4. The decrease in abundance toward the poles suggests that horizontal mixing rates are not rapid enough to homogenize the latitudinal distribution.

Abstract:

The current Martian atmosphere is about five times more enriched in deuterium than Earth’s, providing direct testimony that Mars hosted vastly more water in its early youth than nowadays. Estimates of the total amount of water lost to space from the current mean D/H value depend on a rigorous appraisal of the relative escape between deuterated and non-deuterated water. Isotopic fractionation of D/H between the lower and the upper atmospheres of Mars has been assumed to be controlled by water condensation and photolysis, although their respective roles in influencing the proportions of atomic D and H populations have remained speculative. Here we report HDO and H2O profiles observed by the Atmospheric Chemistry Suite (ExoMars Trace Gas Orbiter) in orbit around Mars that, once combined with expected photolysis rates, reveal the prevalence of the perihelion season for the formation of atomic H and D at altitudes relevant for escape. In addition, while condensation-induced fractionation is the main driver of variations of D/H in water vapour, the differential photolysis of HDO and H2O is a more important factor in determining the isotopic composition of the dissociation products.

Abstract:

The current Martian atmosphere is about five times more enriched in deuterium than Earth’s, providing direct testimony that Mars hosted vastly more water in its early youth than nowadays. Estimates of the total amount of water lost to space from the current mean D/H value depend on a rigorous appraisal of the relative escape between deuterated and non-deuterated water. Isotopic fractionation of D/H between the lower and the upper atmospheres of Mars has been assumed to be controlled by water condensation and photolysis, although their respective roles in influencing the proportions of atomic D and H populations have remained speculative. Here we report HDO and H2O profiles observed by the Atmospheric Chemistry Suite (ExoMars Trace Gas Orbiter) in orbit around Mars that, once combined with expected photolysis rates, reveal the prevalence of the perihelion season for the formation of atomic H and D at altitudes relevant for escape. In addition, while condensation-induced fractionation is the main driver of variations of D/H in water vapour, the differential photolysis of HDO and H2O is a more important factor in determining the isotopic composition of the dissociation products.