Prof. Patrick Irwin

Abstract:

The current Martian atmosphere is about five times more enriched in deuterium than Earth’s, providing direct testimony that Mars hosted vastly more water in its early youth than nowadays. Estimates of the total amount of water lost to space from the current mean D/H value depend on a rigorous appraisal of the relative escape between deuterated and non-deuterated water. Isotopic fractionation of D/H between the lower and the upper atmospheres of Mars has been assumed to be controlled by water condensation and photolysis, although their respective roles in influencing the proportions of atomic D and H populations have remained speculative. Here we report HDO and H2O profiles observed by the Atmospheric Chemistry Suite (ExoMars Trace Gas Orbiter) in orbit around Mars that, once combined with expected photolysis rates, reveal the prevalence of the perihelion season for the formation of atomic H and D at altitudes relevant for escape. In addition, while condensation-induced fractionation is the main driver of variations of D/H in water vapour, the differential photolysis of HDO and H2O is a more important factor in determining the isotopic composition of the dissociation products.

Abstract:

NASA's Spitzer Infrared Spectrometer (IRS) acquired mid-infrared (5–37 μm) disc-averaged spectra of Uranus very near to its equinox in December 2007. A mean spectrum was constructed from observations of multiple central meridian longitudes, spaced equally around the planet, which has provided the opportunity for the most comprehensive globally-averaged characterisation of Uranus' temperature and composition ever obtained (Orton et al., 2014a,b). In this work we analyse the disc-averaged spectra at four separate central meridian longitudes to reveal significant longitudinal variability in thermal emission occurring in Uranus' stratosphere during the 2007 equinox. We detect a variability of up to 15% at wavelengths sensitive to stratospheric methane, ethane and acetylene at the ~0.1-mbar level. The tropospheric hydrogen‑helium continuum and deuterated methane absorption exhibit a negligible variation (less than 2%), constraining the phenomenon to the stratosphere. Building on the forward-modelling analysis of the global average study, we present full optimal estimation inversions (using the NEMESIS retrieval algorithm, Irwin et al., 2008) of the Uranus-2007 spectra at each longitude to distinguish between thermal and compositional variability. We found that the variations can be explained by a temperature change of less than 3 K in the stratosphere. Near-infrared observations from Keck II NIRC2 in December 2007 (Sromovsky et al., 2009; de Pater et al., 2011), and mid-infrared observations from VLT/VISIR in 2009 (Roman et al., 2020), help to localise the potential sources to either large scale uplift or stratospheric wave phenomena.

Abstract:

Phosphine (PH3) is proposed to be a possible biomarker in planetary atmospheres and has been claimed to have been observed in the atmosphere of Venus, sparking interest in the habitability of Venus’s atmosphere. Observations of another biomarker, methane (CH4), have been reported several times in the atmosphere of Mars, hinting at the possibility of a past or present biosphere. The Atmospheric Chemistry Suite on the ExoMars Trace Gas Orbiter has a spectral range that includes several absorption lines of PH3 with line strengths comparable to previously observed CH4 lines. The signature of PH3 was not observed in the 192 observations made over a full Martian year of observations, and here we report upper limits of 0.1–0.6 ppbv.

Abstract:

HCl was discovered in the atmosphere of Mars for the first time during the global dust storm in Mars year (MY) 34 (July 2018) using the Atmospheric Chemistry Suite mid-infrared channel (ACS MIR) on the ExoMars Trace Gas Orbiter. The simultaneity of variations in dust and HCl, and a correlation between water vapour and HCl, led to the proposal of a novel surface-atmosphere coupling analogous to terrestrial HCl production in the troposphere from salt aerosols. After seasonal dust activity restarted in MY 35 (August 2020), we have been monitoring HCl activity to determine whether such a coupling was validated. Here we present a new technique for analyzing the absorption features of trace gases close to the ACS MIR noise level and report that HCl mixing ratios are observed to rapidly increase in both hemispheres coincidentally with the onset of the MY 35 perihelion dust season. We present the temporal evolution of the vertical distribution of HCl (0.1–6 ppbv) and of dust activity in both hemispheres. We also report two observations of > 2 ppbv HCl below 10 km in the northern hemisphere during the aphelion period.