Prof. Patrick Irwin

Abstract:

The global distribution of phosphine (PH3) on Jupiter and Saturn is derived using 2.5 cm-1 spectral resolution Cassini/CIRS observations. We extend the preliminary PH3 analyses on the gas giants [Irwin, P.G.J., and 6 colleagues, 2004. Icarus 172, 37-49; Fletcher, L.N., and 9 colleagues, 2007a. Icarus 188, 72-88] by (a) incorporating a wider range of Cassini/CIRS datasets and by considering a broader spectral range; (b) direct incorporation of thermal infrared opacities due to tropospheric aerosols and (c) using a common retrieval algorithm and spectroscopic line database to allow direct comparison between these two gas giants. The results suggest striking similarities between the tropospheric dynamics in the 100-1000 mbar regions of the giant planets: both demonstrate enhanced PH3 at the equator, depletion over neighbouring equatorial belts and mid-latitude belt/zone structures. Saturn's polar PH3 shows depletion within the hot cyclonic polar vortices. Jovian aerosol distributions are consistent with previous independent studies, and on Saturn we demonstrate that CIRS spectra are most consistent with a haze in the 100-400 mbar range with a mean optical depth of 0.1 at 10 μm. Unlike Jupiter, Saturn's tropospheric haze shows a hemispherical asymmetry, being more opaque in the southern summer hemisphere than in the north. Thermal-IR haze opacity is not enhanced at Saturn's equator as it is on Jupiter. Small-scale perturbations to the mean PH3 abundance are discussed both in terms of a model of meridional overturning and parameterisation as eddy mixing. The large-scale structure of the PH3 distributions is likely to be related to changes in the photochemical lifetimes and the shielding due to aerosol opacities. On Saturn, the enhanced summer opacity results in shielding and extended photochemical lifetimes for PH3, permitting elevated PH3 levels over Saturn's summer hemisphere. © 2009 Elsevier Inc.

Abstract:

Far-IR (25-50 μm, 200-400 cm-1) nadir and limb spectra measured during Cassini's four year prime mission by the Composite InfraRed Spectrometer (CIRS) instrument have been used to determine the abundances of cyanogen (C2N2), methylacetylene (C3H4), and diacetylene (C4H2) in Titan's stratosphere as a function of latitude. All three gases are enriched at northern latitudes, consistent with north polar subsidence. C4H2 abundances agree with those derived previously from mid-IR data, but C3H4 abundances are about 2 times lower, suggesting a vertical gradient or incorrect band intensities in the C3H4 spectroscopic data. For the first time C2N2 was detected at southern and equatorial latitudes with an average volume mixing ratio of 5.5 ± 1.4 × 10- 11 derived from limb data (> 3 - σ significance). This limb result is also corroborated by nadir data, which give a C2N2 volume mixing ratio of 6 ± 3 × 10- 11 (2-σ significance) or alternatively a 3-σ upper limit of 17 × 10- 11. Comparing these figures with photochemical models suggests that galactic cosmic rays may be an important source of N2 dissociation in Titan's stratosphere. Like other nitriles (HCN, HC3N), C2N2 displays greater north polar relative enrichment than hydrocarbons with similar photochemical lifetimes, suggesting an additional loss mechanism for all three of Titan's main nitrile species. Previous studies have suggested that HCN requires an additional sink process such as incorporation into hazes. This study suggests that such a sink may also be required for Titan's other nitrile species. © 2009 Elsevier Inc. All rights reserved.

Abstract:

We present radiative transfer modelling of thermal emission from the nightside of Venus in two 'spectral window' regions at 1.51 and 1.55 μm. The first discovery of these windows, reported by Erard et al. [Erard, S., Drossart, P., Piccioni, G., 2009. J. Geophys. Res. Planets 114, doi:10.1029/2008JE003116. E00B27], was achieved using a principal component analysis of data from the VIRTIS instrument on Venus Express. These windows are spectrally narrow, with a full-width at half-maximum of ∼20 nm, and less bright than the well-known 1.7 and 2.3 μm spectral windows by two orders of magnitude. In this note we present the first radiative transfer analysis of these windows. We conclude that the radiation in these windows originates at an altitude of 20-35 km. As is the case for the other infrared window regions, the brightness of the windows is affected primarily by the optical depth of the overlying clouds; in addition, the 1.51 μm radiance shows a very weak sensitivity to water vapour abundance. © 2009 Elsevier Inc.

Abstract:

A fast method is presented for deriving the tropospheric CO concentrations in the Venus atmosphere from near-infrared spectra using the night side 2.3 μm window. This is validated using the spectral fitting techniques of Tsang et al. [Tsang, C.C.C., Irwin, P.G.J., Taylor, F.W., Wilson, C.F., Drossart, P., Piccioni, G., de Kok, R., Lee, C., Calcutt, S.B., and the Venus Express/VIRTIS Team, 2008a. Tropospheric carbon monoxide concentrations and variability on Venus with Venus Express/VIRTIS-M observations. J. Geophys. Res. 113, doi: 10.1029/2008JE003089. E00B08] to show that monitoring CO in the deep atmosphere can be done quickly using large numbers of observations, with minimal effect from cloud and temperature variations. The new method is applied to produce some 1450 zonal mean CO profiles using data from the first eighteen months of operation from the Visible and Infrared Thermal Imaging Spectrometer infrared mapping subsystem (VIRTIS-M-IR) on Venus Express. These results show many significant long- and short-term variations from the mean equator-to-pole increasing trend previously found from earlier Earth- and space-based observations, including a possible North-South dichotomy, with interesting implications for the dynamics and chemistry of the lower atmosphere of Venus. © 2009 Elsevier Inc. All rights reserved.

Abstract:

The composite infrared spectrometer (CIRS) instrument on board the Cassini Saturn orbiter employs two 1x10 HgCdTe detector arrays for mid-infrared remote sensing of Titan's and Saturn's atmospheres. In this paper we show that the real detector spatial response functions, as measured in ground testing before launch, differ significantly from idealized "boxcar" responses. We further show that neglecting this true spatial response function when modeling CIRS spectra can have a significant effect on interpretation of the data, especially in limb-sounding mode, which is frequently used for Titan science. This result has implications not just for CIRS data analysis but for other similar instrumental applications.