Advanced Functional Materials and Devices (AFMD) Group

Abstract:

Organic solar cells have the potential to become the cheapest form of electricity, beating even silicon photovoltaics. This article summarizes the state of the art in the field, highlighting research challenges, mainly the need for an efficiency increase as well as an improvement in long‐term stability. It discusses possible current and future applications, such as building integrated photovoltaics or portable electronics. Finally, the environmental footprint of this renewable energy technology is evaluated, highlighting the potential to be the energy generation technology with the lowest carbon footprint of all.

Abstract:

Vacuum-based deposition is a scalable, solvent-free industrial method ideal for uniform coatings on complex substrates. However, all vacuum-deposited perovskite solar cells fabricated by thermal evaporation trail solution-processed counterparts in efficiency and stability due to film quality challenges, necessitating advancement and improved understanding. Here, we report a co-evaporation route for 1.67-eV wide-bandgap perovskites by introducing a PbCl2 co-source to optimize film quality. We promote perovskite formation with pronounced (100) “face-up” orientation and deliver a certified all vacuum-deposited solar cell with 18.35% efficiency (19.3% in the lab) for 0.25-cm2 devices (18.5% for 1-cm2 cells). These cells retain 80% of peak efficiency after 1,080 hours under the ISOS-L-2 protocol. Leveraging operando hyperspectral imaging, we provide spatiotemporal spectral insight into halide segregation and trap-mediated recombination, correlating microscopic luminescence features with macroscopic device performance while distinguishing radiative from non-ideal recombination channels. We further demonstrate 27.2%-efficient 1-cm2 evaporated perovskite-on-silicon tandems and outdoor stability of all vacuum-deposited tandems in Italy, retaining ~80% initial performance after 8 months.

Abstract:

This paper presents the development and implementation of a high-sensitivity external quantum efficiency (sEQE) measurement system designed to characterize optoelectronic de- vices, particularly solar cells and photodetectors. Our setup enables precise measurement of the conversion efficiency of photons into free charge carriers, providing crucial insights into device performance and underlying physical mechanisms. The measurement setup is based on a white-light source coupled to a monochromator for wavelength selection, with the diffracted beam focused onto either a calibrated photodiode or the device under test. Mea- surements can be performed at room temperature using a custom sample holder or across a range of temperatures using a cryostat. Signal detection is achieved through Lock-In amplifi- cation, enabling high sensitivity in noisy environments. The incorporation of spectral filters and multiple photodiodes with extended calibration ranges enables a dynamic range span- ning six orders of magnitude, allowing detection of sub-bandgap signals. Beyond describing component modularity and hardware specifications, we provide open-source Python-based control and analysis software to control the sEQE setup and analyze the resulting data. This comprehensive documentation of both hardware and software components contributes to an ongoing effort to increase transparency, standardization, and reproducibility in experimental research and aims to ease access to an important characterization technique for solar cells and photodetectors.

Abstract:

Monolithic perovskite–organic tandem solar cells (POTSCs) have attracted considerable attention in recent years due to their compatible fabrication routes and advances in single-cell efficiencies. To further boost the performance of POTSCs, reducing the voltage losses that mainly arise from wide bandgap (WBG, >1.7 eV) perovskite subcells and interconnecting layers (ICLs) is critical. Here, a new ICL with a configuration of C60/YbO x /Au/MoO x is demonstrated for constructing the monolithic POTSC. The YbO x -based ICL benefits from an ohmic contact and high transparency, resulting in improved POSTC performance. The champion device presents a PCE of 23.2% owing to a high V OC of 2.11 V (approximately equal to the sum of individual V OC’s of the subcells) without compromising the short-circuit current density and fill factors. This work opens an avenue for developing efficient ICLs in POTSCs.

Abstract:

Monolithic perovskite–organic tandem solar cells (POTSCs) have attracted considerable attention in recent years due to their compatible fabrication routes and advances in single-cell efficiencies. To further boost the performance of POTSCs, reducing the voltage losses that mainly arise from wide bandgap (WBG, >1.7 eV) perovskite subcells and interconnecting layers (ICLs) is critical. Here, a new ICL with a configuration of C60/YbO x /Au/MoO x is demonstrated for constructing the monolithic POTSC. The YbO x -based ICL benefits from an ohmic contact and high transparency, resulting in improved POSTC performance. The champion device presents a PCE of 23.2% owing to a high V OC of 2.11 V (approximately equal to the sum of individual V OC’s of the subcells) without compromising the short-circuit current density and fill factors. This work opens an avenue for developing efficient ICLs in POTSCs.