Frustration of magnetic and ferroelectric long-range order in Bi(2)Mn(4/3)Ni(2/3)O(6).
J Am Chem Soc 131:39 (2009) 14000-14017
Abstract:
The slight incommensurate modulation of the structure of Bi(2)Mn(4/3)Ni(2/3)O(6) is sufficient to suppress the electrical polarization which arises in commensurate treatments of the structure, due to antiferroelectric coupling of local polar units of over 900 A(3). The incommensurate structure is produced by the competition between ferroelectric Bi lone pair-driven A site displacement, chemical order of Mn and Ni on the B site, and both charge and orbital order at these transition metals. The interplay between the frustrated polar Bi displacements and the frustrated spin order at the B site, induced by positional disorder, produces magnetodielectric coupling between the incommensurately modulated lattice and the spin-glass-like ground state with an unusual relationship between the magnetocapacitance and the applied field.Concepts in Thermal Physics
Oxford University PressOxford, 2009
Abstract:
Proximal magnetometry of monolayers of single molecule magnets on gold using polarized muons
(2009)
Muon-fluorine entanglement in fluoropolymers
Journal of Physics Condensed Matter 21:34 (2009)