What relaxes muon spins in molecular nanomagnets?

(2009)

Authors:

T Lancaster, SJ Blundell, FL Pratt, I Franke, AJ Steele, PJ Baker, Z Salman, C Baines, I Watanabe, S Carretta, GA Timco, REP Winpenny

Frustration of magnetic and ferroelectric long-range order in Bi(2)Mn(4/3)Ni(2/3)O(6).

J Am Chem Soc 131:39 (2009) 14000-14017

Authors:

John B Claridge, Helen Hughes, Craig A Bridges, Mathieu Allix, Matthew R Suchomel, Hongjun Niu, Xiaojun Kuang, Matthew J Rosseinsky, Natalia Bellido, Dominique Grebille, Olivier Perez, Charles Simon, Denis Pelloquin, Stephen J Blundell, Tom Lancaster, Peter J Baker, Francis L Pratt, P Shiv Halasyamani

Abstract:

The slight incommensurate modulation of the structure of Bi(2)Mn(4/3)Ni(2/3)O(6) is sufficient to suppress the electrical polarization which arises in commensurate treatments of the structure, due to antiferroelectric coupling of local polar units of over 900 A(3). The incommensurate structure is produced by the competition between ferroelectric Bi lone pair-driven A site displacement, chemical order of Mn and Ni on the B site, and both charge and orbital order at these transition metals. The interplay between the frustrated polar Bi displacements and the frustrated spin order at the B site, induced by positional disorder, produces magnetodielectric coupling between the incommensurately modulated lattice and the spin-glass-like ground state with an unusual relationship between the magnetocapacitance and the applied field.

Concepts in Thermal Physics

Oxford University PressOxford, 2009

Authors:

Stephen J Blundell, Katherine M Blundell

Abstract:

Abstract An understanding of thermal physics is crucial to much of modern physics, chemistry, and engineering. This book provides a modern introduction to the main principles that are foundational to thermal physics, thermodynamics, and statistical mechanics. The key concepts are carefully presented in a clear way, and new ideas are illustrated with worked examples as well as a description of the historical background to their discovery. Applications are presented to subjects as diverse as stellar astrophysics, information and communication theory, condensed matter physics, and climate change. Each chapter concludes with detailed exercises. This second edition of the text maintains the structure and style of the first edition but extends its coverage of thermodynamics and statistical mechanics to include several new topics, including osmosis, diffusion problems, Bayes theorem, radiative transfer, the Ising model, and Monte Carlo methods. New examples and exercises have been added throughout.

Proximal magnetometry of monolayers of single molecule magnets on gold using polarized muons

(2009)

Authors:

Z Salman, SJ Blundell, SR Giblin, M Mannini, L Margheriti, E Morenzoni, T Prokscha, A Suter, A Cornia, R Sessoli

Muon-fluorine entanglement in fluoropolymers

Journal of Physics Condensed Matter 21:34 (2009)

Authors:

T Lancaster, FL Pratt, SJ Blundell, I McKenzie, HE Assender

Abstract:

We present the results of muon spin relaxation measurements on the fluoropolymers polytetrafluoroethylene (PTFE), poly(vinylidene fluoride) (PVDF) and poly(vinyl fluoride) (PVF). Entanglement between the muon spin and the spins of the fluorine nuclei in the polymers allows us to identify the different muon stopping states that occur in each of these materials and provides a method of probing the local environment of the muon and the dynamics of the polymer chains. © 2009 IOP Publishing Ltd.