Charge order, enhanced orbital moment, and absence of magnetic frustration in layered multiferroic LuFe2 O4
Physical Review B - Condensed Matter and Materials Physics 80:22 (2009)
Abstract:
Electronic and magnetic properties of the charge ordered phase of LuFe2 O4 are investigated by means of x-ray spectroscopic and theoretical electronic structure approaches. LuFe2 O4 is a compound showing fascinating magnetoelectric coupling via charge ordering. Here, we identify the spin ground state of LuFe2 O4 in the charge ordered phase to be a 2:1 ferrimagnetic configuration, ruling out a frustrated magnetic state. An enhanced orbital moment may enhance the magnetoelectric coupling. Furthermore, we determine the densities of states and the corresponding correlation potentials by means of x-ray photoelectron and emission spectroscopies, as well as electronic structure calculations. © 2009 The American Physical Society.Frustration of magnetic and ferroelectric long-range order in Bi(2)Mn(4/3)Ni(2/3)O(6).
J Am Chem Soc 131:39 (2009) 14000-14017
Abstract:
The slight incommensurate modulation of the structure of Bi(2)Mn(4/3)Ni(2/3)O(6) is sufficient to suppress the electrical polarization which arises in commensurate treatments of the structure, due to antiferroelectric coupling of local polar units of over 900 A(3). The incommensurate structure is produced by the competition between ferroelectric Bi lone pair-driven A site displacement, chemical order of Mn and Ni on the B site, and both charge and orbital order at these transition metals. The interplay between the frustrated polar Bi displacements and the frustrated spin order at the B site, induced by positional disorder, produces magnetodielectric coupling between the incommensurately modulated lattice and the spin-glass-like ground state with an unusual relationship between the magnetocapacitance and the applied field.Concepts in Thermal Physics
Oxford University PressOxford, 2009
Abstract:
Proximal magnetometry of monolayers of single molecule magnets on gold using polarized muons
(2009)