Planetary atmosphere observation analysis

Abstract:

Whether or not there is a particulate layer in the lowest 10 km of the Venusian atmosphere is still an open question. Some of the past in situ experiments showed the presence of a detached particulate layer, and a few suggested the existence of finely dispersed aerosols, while other instruments supported the idea of no particulate matter in the deep atmosphere. In this work, we investigate the presence of a near‐surface particulate layer (NSPL) using in situ data from the Venera 13 mission. While the original spectrophotometric data from Venera 13 were lost, we have reconstructed a part of this data by digitizing the old graphic material and selected the eight most reliable Venera 13 downward radiance profiles from 0.48 to 0.8 μ ${\upmu }$ m for our retrievals. The retrievals suggest the existence of the particulate layer with a peak in the altitude range of 3.5–5 km. They further indicate a log‐normal particle size distribution with a mean radius between 0.6 and 0.85 μ ${\upmu }$ m. The retrievals constrain the real refractive index of the particles to lie around the range of 1.4–1.6, with the imaginary refractive index of a magnitude of 10 − 3 ${10}^{-3}$ . Based on refractive index retrievals, uplifted basalt particles or volcanic ash could be responsible for near‐surface particulates. In comparison, volatile condensates appear less likely to be behind the formation of NSPL.

Abstract:

Recent observations from the ExoMars Trace Gas Orbiter (TGO) have revealed the presence of hydrogen chloride (HCl) in the martian atmosphere. HCl shows strong seasonality, primarily appearing during Mars' perihelion period before decreasing faster than projected from photolysis and gas‐phase chemistry. HCl profiles also display local anti‐correlation with water ice aerosol. One candidate explanation is heterogeneous chemistry. We present the first results from a heterogeneous chlorine chemistry scheme incorporated into a Mars global climate model (GCM), with atmospheric dust/water ice parameterized as an HCl source/sink respectively. Results were compared against a Mars GCM with gas‐phase only chlorine chemistry and observations from TGO's Atmospheric Chemistry Suite. We found that the heterogeneous scheme significantly improved the modeled HCl seasonal, latitudinal, and vertical distribution, supporting a crucial role for heterogeneous chemistry in Mars' chlorine cycle. Remaining discrepancies show that further work is needed to characterize the exact aerosol reactions involved.

Abstract:

Recent observations by instruments aboard the ExoMars Trace Gas Orbiter (TGO) have revealed the seasonal presence of hydrogen chloride ( HCl $\text{HCl}$ ) in the Martian atmosphere. This discovery may have important implications for Martian photochemistry as chlorine species are chemically active, and it may provide a link between the atmosphere and known surface reservoirs of chlorine. However, the global distribution of atmospheric HCl $\text{HCl}$ is unknown beyond the very sparse TGO observations, and the source and sink processes driving the observed variability of HCl $\text{HCl}$ are not currently understood. We used a Martian global climate model to investigate, for the first time, the spatial distribution of chlorine species in the Martian atmosphere, and the resulting distribution of surface perchlorates formed via adsorption of atmospheric chlorine species. We adapted an existing Martian photochemical scheme to include gas‐phase chlorine chemistry with HCl as the source species, and the resulting atmospheric perchloric acid was allowed to deposit onto the Martian surface via a heterogeneous adsorption scheme. We found that odd‐oxygen ( O , O 3 $\mathrm{O},{\mathrm{O}}_{3}$ ) and odd‐hydrogen ( H , OH , HO 2 $\mathrm{H},\text{OH},{\text{HO}}_{2}$ ) species play a major role in controlling the distribution of atmospheric chorine species. Surface perchlorate deposition was found to occur preferentially at high latitudes; in the tropics, the perchlorate distribution was anti‐correlated with surface thermal inertia and agreed qualitatively with observations of surface chlorine. Our model predicted a relative enhancement of HCl in polar regions, but it did not reproduce the observed strong seasonality of HCl, suggesting that heterogeneous chemistry may be required to explain the observed chlorine cycle.