A 3D model simulation of hydrogen chloride photochemistry on Mars: Comparison with satellite data
Astronomy & Astrophysics EDP Sciences 699 (2025) a362
Abstract:
Context. Hydrogen chloride (HCl) was independently detected in the Martian atmosphere by the Nadir and Occultation for MArs Discovery (NOMAD) and Atmospheric Chemistry Suite (ACS) spectrometers aboard the ExoMars Trace Gas Orbiter (TGO). Photochemical models show that using gas-phase chemistry alone is insufficient to reproduce these data. Recent work has developed a heterogeneous chemical network within a 1D photochemistry model, guided by the seasonal variability in HCl. This variability includes detection almost exclusively during the dust season, a positive correlation with water vapour, and an anticorrelation with water ice. Aims. The aim of this work is to show that incorporating heterogeneous chlorine chemistry into a global 3D model of Martian photochemistry with conventional gas-phase chemistry can reproduce spatial and temporal changes in hydrogen chloride on Mars, as observed by instruments aboard the TGO. Methods. We incorporated this heterogeneous chlorine scheme into the Mars Planetary Climate Model (MPCM). After some refinements to the scheme, mainly associated with it being employed in a 3D model, we used it to model chlorine photochemistry during Mars Years (MYs) 34 and 35. These two years provide contrasting dust scenarios, with MY 34 featuring a global dust storm. We also examined correlations in the model results between HCl and other key atmospheric quantities, as well as production and loss processes, to understand the impact of different factors driving changes in HCl. Results. We find that the 3D model of Martian photochemistry using the proposed heterogeneous chemistry is consistent with the changes in HCl observed by ACS in MY 34 and MY 35, including detections and 70% of non-detections. For the remaining 30% of non-detections, model HCl is higher than the ACS detection limit due to biases associated with water vapour, dust, or water ice content at these locations. As with previous 1D model calculations, we find that heterogeneous chemistry is required to describe the loss of HCl, resulting in a lifetime of a few sols that is consistent with the observed seasonal variation in HCl. As a result of this proposed chemistry, modelled HCl is correlated with water vapour, airborne dust, and temperature, and anticorrelated with water ice. Our work shows that this chemical scheme enables the reproduction of aphelion detections in MY 35.Ionospheric Analysis With Martian Mutual Radio Occultation
Journal of Geophysical Research Planets 130:6 (2025)
Abstract:
This study presents a comprehensive analysis of the Martian ionosphere using Mutual Radio Occultation (RO) observations between Mars Express and Trace Gas Orbiter, featuring 71 full vertical profiles out of a total of 124 measurements. Among these, 35 measurements were taken from regions with Solar Zenith Angles lower than 40°. The profiles also represent the largest data set for the lower M1 ionospheric layer during the midday ever measured. This paper has also been submitted with a comprehensive data set, which marks the first time MEX-TGO RO data has been made available to the community. Additionally, neutral temperature profiles have been extracted from the measurements. We find unexpected features in the lower thermosphere temperature behavior which we conclude is likely due to the effects of local circulation and associated dynamical heating rather than solar-controlled.Mars Express: From the Launch Pad to a 20-Year Success Record at Mars
Space Science Reviews 221:4 (2025)
Abstract:
Mars Express was conceived and built by ESA as a successor of the unsuccessful Russian Mars-96 mission. It was planned from the onset as an orbiter and lander mission to be able to carry out long-term, remote sensing and in-situ scientific investigations of the planet Mars and its environment. As an exceptionally successful workhorse and a backbone of the Agency’s Science Programme in operation at Mars since end December 2003, Mars Express has proven to be a highly productive mission returning excellent scientific value for the investments made by ESA and its Member States. This paper is intended as the introduction to the series of papers that make this special collection. It briefly reviews the history of the mission, its science goals, its uniqueness while establishing its complementarity with other Mars missions in a collaborative context. It also lists the teams and operational aspects and innovations that made this mission a success. Then the paper highlights Mars Express’s scientific achievements throughout its 20-year lifetime. Mars Express results and discoveries continue playing an essential role in understanding the geological, atmospheric and climate evolution of the Red Planet and determining its potential past habitability. To conclude, a preview of the science and other topics covered by this collection is given. Mars Express, a pioneering mission for Europe at Mars, is currently continuing on its long scientific journey around the Red Planet.Context images for Venus Express radio occultation measurements: A search for a correlation between temperature structure and UV contrasts in the clouds of Venus
Astronomy & Astrophysics EDP Sciences 698 (2025) a198
Abstract:
Context . Venus exhibits strong and changing contrasts at ultraviolet wavelengths. They appear to be related to the clouds and the dynamics in the cloud layer, but to date their origin continues to be unknown. Aims . We investigate the nature of the UV contrasts exhibited by Venus’ clouds by examining possible correlations between the thermal structure inferred from radio occultation data and UV brightness from imagery data, both observed with Venus Express. Methods . We analysed Venus Express images obtained from 11 hours before to a few hours after the time of radio occultation measurements of the same area. We accounted for the advection of clouds by zonal and meridional winds and applied a phase angle correction to compensate for the changing viewing geometry. Results . We find a possible anti-correlation between UV brightness and atmospheric temperature around an altitude of 67 km for low latitudes, with a one percent probability of this finding being due to chance (p value = 0.01). Heating in this altitude and latitude region due to an increase in the UV absorber has been predicted by radiative forcing studies. The predictions roughly match our observed temperature amplitude between UV-dark and UV-bright regions. Conclusions . This could be the first observational evidence of a direct link between UV brightness and atmospheric temperature in the 65–70 km altitude region in the clouds of Venus.Seasonal Evolution of Titan’s Stratospheric Tilt and Temperature Field at High Resolution from Cassini/CIRS
The Planetary Science Journal IOP Publishing 6:5 (2025) 114