Planetary atmosphere observation analysis

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Quantifying Thin Dust Layer Effects on Thermal-IR Spectra of Bennu-Like Regolith: FTIR Experiments with CI Asteroid Simulant 

(2025)

Authors:

Emma Belhadfa, Neil Bowles, Katherine Shirley

Abstract:

Introduction: The surfaces of airless bodies, such as asteroid (101955) Bennu, are typically composed of a regolith mixture containing both coarse and fine particulates. Observations from NASA’s Origins, Spectral Interpretation, Resource Identification, Security, Regolith Explorer (OSIRIS-REx) mission demonstrated a discontinuity between the remote sensing derived thermophysical properties and thermal spectroscopy results, indicating that a fine layer of dust may be coating the large boulders and coarse regolith surface [1]. To better understand the impact of such a coating on the thermal infrared spectra measured at Bennu, this work developed experimental methods for simulating dust coverings using Space Resource Technology’s CI simulant, based on the bulk composition of the Orgueil meteorite [2].    Figure 1: FTIR Reflectance Spectra of Control Samples of CI simulant. Figure 2: Figure 2: Microscope Camera Images of Sample Surfaces (7%, 10%, 15%, 20%, 25%, 50% Fines wt) of CI simulant Methods: The CI simulant was first sieved into seven size fractions: 1000 mm. An unsieved sample was used as a control. The spectra of the eight samples were measured using a Bruker Vertex 70v Fourier Transform Infrared Reflectance (FTIR) spectrometer, normalized using a gold standard prior to and after measurements, in the range of 1000-650 cm-1 (Figure 1). The dust coating was simulated by placing increasing mass fractions of fine particulates (10% change in the spectral slope).  Implications for OSIRIS-Rex Findings: From the data returned by the OSIRIS-Rex Thermal Emission Spectrometer (OTES) [3],  thermal inertia modelling imply that the surface is porous;, however, the spectral findings indicate that the surface is composed of non-porous? rocks with thin dust coatings [4]. Our experiments find that as little as ~7 wt % of 7% wt) was sufficient to overwhelm and dominate mid-infrared emissivity spectra. The results indicate that the discontinuity in OTES data could be linked back to dust coating on the larger rocks and boulders.   References: [1] Tinker C. et al. (2023) RAS Techniques and Instruments (Vol. 2, Issue 1). [2] Landsman Z. et al. (2020) EPSC 2020. [3] Christensen P. R. et al. (2018) Space Science Reviews (Vol. 214, Issue 5). [4] Rozitis B. et al. (2022) JGR: Planets (Vol. 127, Issue 6). [5] Rivera-Hernandez F. et al. (2015) Icarus (Vol. 262). 
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Saturn’s Local and Seasonal Aerosol Variations Inferred from Cassini Combined UV, Visual, and Near-IR Observations  

(2025)

Authors:

James Sinclair, Emma Dahl, Kevin Baines, Tom Momary, Lawrence Sromovsky, Pat Fry, Patrick Irwin

Abstract:

Clouds are the manifestations of atmospheric dynamics, chemistry, thermal evolution, and orbital characteristics; thus, understanding their physical and spectral properties and their spatial and temporal variability is critical to understanding the planet as a whole.  Observations of Saturn by the Hubble Space Telescope since 1994 and by Cassini from 2004 - 2017 have spanned almost one Saturn year (29.5 Earth years).  Despite the wealth of data, a self-consistent picture of the seasonal variations in Saturn’s haze and cloud structure remain elusive. In this work, we present a radiative transfer analysis of Cassini-VIMS (Visible and Infrared Mapping Spectrometer) spectra in order to derive the vertical structure and color properties of Saturn’s clouds and their latitudinal and seasonal variability.  VIMS records spectra over visible (0.3 to 1.05 micron) and infrared (0.85 to 5.1 micron) channels at spectral resolutions of 7 and 16 nm, respectively.  After a review of the VIMS dataset, we have identified dayside spectra that capture unique cloud features in a given latitude circle at multiple emission angles, allowing for improved vertical discrimination of cloud models. Data are additionally available over multiple epochs, allowing us to analyze any seasonal evolution.  Using the NEMESIS radiative transfer code (Irwin et al., 2008, JQSRT 109, 1136-1150), we invert the VIMS spectra to derive the vertical profiles of phosphine (PH3), ammonia (NH3) and the vertical structure of 4 haze/cloud layers (using the cloud model and cloud/gas parameters shown in Figure 1).  In preliminary findings, in adopting the chromophore optical constants derived by Sromovsky et al., 2021 (Icarus 362, 114409) for a north polar cloud observed in 2016, we find we can adequately fit the spectra for a subset of clouds observed in September 2014.  At other locations/times, the chromophore optical constants derived by Sromovsly et al., 2021, need to be varied in order to fit the spectra within uncertainty, which indicates seasonal evolution of Saturn’s chromophore.  In this work, we present derived cloud properties and the optical constants of the derived chromophore as a function of latitude and season in order to shed light on the complex interplay between cloud structure, color, chemistry, and orbital characteristics.     
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Spectral Variability and Compositional Insights from Asteroid (101955) Bennu’s Sampling Sites Using OTES Data 

(2025)

Authors:

Emma Belhadfa, Katherine Shirley, Neil Bowles

Abstract:

Introduction: During the Reconnaissance phase of NASA’s OSIRIS-REx mission, the Thermal Emission Spectrometer (OTES) acquired high–spatial resolution emissivity spectra over Bennu’s four prospective sampling sites [1, 2]. We analyse the calibrated OTES dataset archived in the Planetary Data System [3] to quantify compositional and mineralogical diversity across the original four candidate sample sites (Nightingale, Kingfisher, Osprey, and Sandpiper) and to explore possible drivers of Bennu’s surface heterogeneity, including implications for Bennu’s mineralogy and space-weathering history.  Figure 1: Site-Averaged Emissivity Spectra with Annotated Band Parameters Methods: Calibrated emissivity spectra (5.7-100 µm) were linked to corresponding OCAMS imagery [5] to place the thermal infrared measurements in geological context, by cross-referencing observation times. For every spectrum we derived four diagnostic band parameters: Christiansen Feature (CF), silicate stretching band, silicate bending band and spectral slope, following the methods outlined in [6]. Each site contains thousands of spectral observations (site-averaged for visualization in Figure 1). The corresponding band parameters were compared using three statistical models: Principal Component Analysis (PCA) [5], k-Nearest Neighbors (KNN) [7], and Analysis of Variance (ANOVA) [8]. The three methods compare the mean and variance of each individual observation per site, considering how the in-group variance (i.e. the spread within all observations of a single site) compares to the out-group variance (i.e. the spread from other sites).  Results: Significant differences in emissivity spectra emerged among the four sites. PCA indicated that the first three components explain 85.5% of spectral variance, distinguishing Kingfisher as notably unique, with Sandpiper and Osprey exhibiting the greatest similarity. The KNN analysis corroborated PCA findings, reaching optimal classification accuracy (47%) at k = 21. ANOVA highlighted significant variability among the sites, especially in the spectral slope parameter (F = 762.8), suggesting differences in particle size distribution and space weathering could be driving factors in the detected heterogeneity [9]. Band ratio analyses provided additional insight into site-specific mineralogical distinctions, notably the relationship between silicate features and aqueous alteration indicators [10].  Figure 2: Distributions of Band Parameters by Site Discussion: Variability in spectral parameters aligns with documented particle size frequency distributions and known space weathering spectral types across Bennu’s surface [9]. Nightingale, the mission’s selected sample site, captures representative global characteristics, contrasting with Kingfisher’s distinct compositional and physical attributes, potentially related to differences in Fe/Mg content and degree of aqueous alteration [10].  Conclusion: Integrative use of multiple statistical approaches confirms the compositional and physical diversity of Bennu's surface, as seen through the four prospective sites. These analyses provide a framework for interpreting returned sample data and offer insights into the connections between mineralogy, particle size, and space weathering processes on small airless body surfaces.  References: [1] Lauretta D. S. et al (2021) Sample Return Missions. [2] Hamilton V. et al. (2021) A&A (Vol. 650). [3] Christensen, P. R. et al. (2019) NASA Planetary Data System [4] Christensen P. R. et al. (2018) Space Science Reviews (Vol. 214, Issue 5). [5] Rizk B. et al (2018) Space Science Reviews (Vol. 214, Issue 1). [6] Xie B. et al (2022) Minerals (Vol. 508, Issue 12). [7] Kramer O. (2013) Intelligent Systems Reference Library (13-23). [8] Sawyer S. (2009) Journal of Manual & Manipulative Therapy. [9] Clark B. E. et al (2023) Icarus (Vol. 400). [10] Bates H. et al (2020) MaPS (Vol. 55, Issue 1). 
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Temperature, Composition, and Cloud structure in Atmosphere of Neptune from MIRI-MRS and NIRSpec-IFU Observations

(2025)

Authors:

Michael Roman, Leigh Fletcher, Heidi Hammel, Oliver King, Glenn Orton, Naomi Rowe-Gurney, Patrick Irwin, Julianne Moses, Imke de Pater, Henrik Melin, Jake Harkett, Simon Toogood, Stefanie Milam

Abstract:

We present observations and analysis of Neptune’s atmosphere from JWST, providing new constraints on hydrocarbon abundances, cloud properties, and temperature structure across the planet’s disk.  JWST observed Neptune in June 2023 (program1249) as part of the Solar System Guaranteed Time Observations (GTO). Integral field spectroscopy (IFS) with the Near-Infrared Spectrograph (NIRSpec) and the Mid-Infrared Instrument/Medium Resolution Spectrometer (MIRI/MRS) were combined to provide nearly simultaneous and continuous spatial and spectral data between 1.66 and 28.70 microns.We show how wavelengths sensitive to the atmospheric temperatures reveal a structure consistent with Voyager [1] and ground-based imaging [2,3], with a sharply defined warm polar vortex. In contrast, wavelengths sensitive to stratospheric hydrocarbons (namely acetylene and ethane) show a marked enhancement in the northern winter hemisphere.Finally, we examine the distribution and vertical structure of clouds in context of the temperature and chemical structure. Scattered light in NIRSpec observations indicate variable discrete clouds extend to pressures of roughly 50 mbar at the northernmost latitudes and south pole. [1] Conrath, B. J., F. M. Flasar, and P. J. Gierasch. "Thermal structure and dynamics of Neptune's atmosphere from Voyager measurements." Journal of Geophysical Research: Space Physics 96, no. S01 (1991): 18931-18939.[2] Fletcher, Leigh N., Imke de Pater, Glenn S. Orton, Heidi B. Hammel, Michael L. Sitko, and Patrick GJ Irwin. "Neptune at summer solstice: zonal mean temperatures from ground-based observations, 2003–2007." Icarus 231 (2014): 146-167.[3] Roman, Michael T., Leigh N. Fletcher, Glenn S. Orton, Thomas K. Greathouse, Julianne I. Moses, Naomi Rowe-Gurney, Patrick GJ Irwin et al. "Subseasonal variation in Neptune’s mid-infrared emission." The Planetary Science Journal 3, no. 4 (2022): 78.
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Temperature, Composition, and Cloud structure in Atmosphere of Uranus from MIRI-MRS and NIRSpec-IFU Spectra

(2025)

Authors:

Michael Roman, Leigh Fletcher, Heidi Hammel, Patrick Irwin, Oliver King, Naomi Rowe-Gurney, Julianne Moses, Glenn Orton, Imke de Pater, Henrik Melin, Jake Harkett, Matthew Hedman, Simon Toogood, Stefanie Milam

Abstract:

Introduction: Due to Uranus’ weak thermal radiance, the thermal and compositional structures of its atmosphere have remained poorly characterised. Here, using the unprecedented sensitivity of JWST's MIRI and NIRSpec instruments, we present an analysis of Uranus' spatially resolved spectrum spanning the near- and mid-infrared, revealing how temperatures, composition, and clouds vary across the planet's northern hemisphere.Observations: JWST observed Uranus on 8--9 January 2023 (program1248) as part of the Solar System Guaranteed Time Observations (GTO). Integral field spectroscopy (IFS) with the Near-Infrared Spectrograph (NIRSpec) and the Mid-Infrared Instrument/Medium Resolution Spectrometer (MIRI/MRS) were combined to provide nearly simultaneous and continuous spatial and spectral data between 1.66 and 28.70 microns.Temperatures: The nearly continuous spectral coverage offered by the combination of NIRSpec and MIRI provide constraints on the temperature structure from the stratosphere down to several bars. The average temperature-pressure vertical profile is largely consistent with that determined from Spitzer [1], but the spatially resolved JWST reveal how these temperatures vary with latitude in the stratosphere and cloud layer for the first time [2]. They also suggest the possibility of a sub-adiabatic cloud layer.Chemistry: Our radiative transfer analysis of MIRI-MRS spectra 1) provide new constraints on minor species in Uranus’ stratosphere and 2) reveals how various hydrocarbons vary as a function of latitude. The observed distributions are indicative of a combination of seasonal photochemistry [3] and dynamical processes, as we will briefly discuss.Clouds and hazes: Finally, we briefly examine the vertical cloud structure and its latitudinal variation as sensed by NIRSpec data. The data reveal the opacity of Uranus clouds and hazes spanning the transition from scattered sunlight to thermal emission for the first time. The overall vertical structure suggested by these new data largely agrees with that of prior work [3,4,5], but a comparison between observed and model spectra reveal interesting discrepancies and possibly a need for additional sources of opacity. [1] Orton, G.S., Fletcher, L.N., Moses, J.I., Mainzer, A.K., Hines, D., Hammel, H.B., Martin-Torres, F.J., Burgdorf, M., Merlet, C., Line, M.R.: Mid-infrared spectroscopy of uranus from the spitzer infrared spectrometer: 1. determination of the mean temperature structure of the upper troposphere and stratosphere. Icarus 243, 494–513 (2014)[2] Roman, M.T., Fletcher, L.N., Orton, G.S., Rowe-Gurney, N., Irwin, P.G.: Uranus in northern midspring: persistent atmospheric temperatures and circulations inferred from thermal imaging. The Astronomical Journal 159(2), 45 (2020)[3] Moses, J.I., Fletcher, L.N., Greathouse, T.K., Orton, G.S., Hue, V.: Seasonal stratospheric photochemistry on uranus and neptune. Icarus 307, 124–145 (2018)[4] Sromovsky, L.A., Karkoschka, E., Fry, P.M., Pater, I., Hammel, H.B.: The methane distribution and polar brightening on uranus based on hst/stis, keck-nirc2, and irtf/spex observations through 2015. Icarus 317, 266–306 (2019)189[5] Irwin, P.G., Teanby, N.A., Fletcher, L.N., Toledo, D., Orton, G.S., Wong, M.H.,Roman, M.T., Perez-Hoyos, S., James, A., Dobinson, J.: Hazy blue worlds:A holistic aerosol model for uranus and neptune, including dark spots[6] Roman, M.T., Banfield, D., Gierasch, P.J.: Aerosols and methane in the ice giant atmospheres inferred from spatially resolved, near-infrared spectra: I. uranus, 2001–2007. Icarus 310, 54–76 (2018)
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