Observations of upper tropospheric acetylene on Saturn: No apparent correlation with 2000 km-sized thunderstorms
Planetary and Space Science 65:1 (2012) 21-37
Abstract:
Thunderstorm activity has been observed on Saturn via radio emissions from lightning discharges and optical detections of the lightning flashes on the planets nightside. Thunderstorms provide extreme environments in which specific atmospheric chemistry can be induced - namely through energy release via lightning discharges, and fast vertical transport resulting in rapid advection of tropospheric species. It is thus theorised that certain atmospheric trace species such as C 2H 2, HCN, and CO can be generated in the troposphere by large bursts of energy in the form of lightning, and transported upward towards the upper troposphere by the extreme dynamics of thunderstorms, where they should be observable by satellite instruments. In this work, high-spectral-resolution Cassini/CIRS observations from October 2005 through April 2009 are used to study whether there is an observable increase in upper tropospheric acetylene in regions of known normal thunderstorm activity. Using both individual measurements in which there is known thunderstorm activity, as well as large coadditions of data to study latitudinal-dependencies over the full disc, no systematic enhancement in upper tropospheric (100 mbar) C 2H 2 was detected around regions in which there are known occurrences of normally sized (2000 km) thunderstorms, or in normally sized thunderstorm-prone regions such as 40°S. It is likely that the magnitude of the enhancement theorised is too generous or that enhancements are not advected into the upper troposphere as vertical mixing rates in models would suggest, since Cassini/CIRS can only detect C 2H 2 above the 200 mbar level - although the massive northern hemisphere thunderstorm of 2010/2011 seems able to decrease stratospheric concentrations of C 2H 2. From this, it can be asserted that lightning from normal thunderstorm activity cannot be the key source for upper tropospheric C 2H 2 on Saturn, since the upper-tropospheric concentrations retrieved agree with the concentrations stemming from the photolysis of CH 4 (23 ppbv) from solar radiation penetrating through the Saturnian atmosphere, with an upper limit for lightning-induced C 2H 2 volume mixing ratio of 10 -9. © 2012 Elsevier Ltd. All rights reserved.Isotopic ratios in titan's methane: Measurements and modeling
Astrophysical Journal 749:2 (2012)
Abstract:
The existence of methane in Titan's atmosphere (∼6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of ∼20Myr. In this paper, we examine the clues available from isotopic ratios (12C/13C and D/H) in Titan's methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: 13CH4, 12CH3D, and 13CH3D. From these we compute estimates of 12C/13C= 86.5 ± 8.2 and D/H= (1.59 ± 0.33) × 10-4, in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan's methane: CH4+ C2H→ CH3+ C2H2. Using these new measurements and predictions we proceed to model the time evolution of 12C/13C and D/H in Titan's methane under several prototypical replenishment scenarios. In our Model1 (no resupply of CH4), we find that the present-day 12C/13C implies that the CH4 entered the atmosphere 60-1600Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently - most likely less than 10Myr ago - if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane. © 2012 The American Astronomical Society. All rights reserved.Lunar Net-a proposal in response to an ESA M3 call in 2010 for a medium sized mission
Experimental Astronomy 33:2-3 (2012) 587-644
Abstract:
Emplacement of four or more kinetic penetrators geographically distributed over the lunar surface can enable a broad range of scientific exploration objectives of high priority and provide significant synergy with planned orbital missions. Whilst past landed missions achieved a great deal, they have not included a far-side lander, or investigation of the lunar interior apart from a very small area on the near side. Though the LCROSS mission detected water from a permanently shadowed polar crater, there remains in-situ confirmation, knowledge of concentration levels, and detailed identification of potential organic chemistry of astrobiology interest. The planned investigations will also address issues relating to the origin and evolution of the Earth-Moon system and other Solar System planetary bodies. Manned missions would be enhanced with use of water as a potential in-situ resource; knowledge of potential risks from damaging surface Moonquakes, and exploitation of lunar regolith for radiation shielding. LunarNet is an evolution of the 2007 LunarEX proposal to ESA (European Space Agency) which draws on recent significant advances in mission definition and feasibility. In particular, the successful Pendine full-scale impact trials have proved impact survivability for many of the key technology items, and a penetrator system study has greatly improved the definition of descent systems, detailed penetrator designs, and required resources. LunarNet is hereby proposed as an exciting stand-alone mission, though is also well suited in whole or in-part to contribute to the jigsaw of upcoming lunar missions, including that of a significant element to the ILN (International Lunar Network). © 2011 Springer Science+Business Media B.V.The 2010 European Venus Explorer (EVE) mission proposal
Experimental Astronomy 33:2-3 (2012) 305-335
Abstract:
The European Venus Explorer (EVE) mission described in this paper was proposed in December 2010 to ESA as an 'M-class' mission under the Cosmic Vision programme. It consists of a single balloon platform floating in the middle of the main convective cloud layer of Venus at an altitude of 55 km, where temperatures and pressures are benign (~25°C and ~0. 5 bar). The balloon float lifetime would be at least 10 Earth days, long enough to guarantee at least one full circumnavigation of the planet. This offers an ideal platform for the two main science goals of the mission: study of the current climate through detailed characterization of cloud-level atmosphere, and investigation of the formation and evolution of Venus, through careful measurement of noble gas isotopic abundances. These investigations would provide key data for comparative planetology of terrestrial planets in our solar system and beyond. © 2011 Springer Science+Business Media B.V.Further seasonal changes in Uranus' cloud structure observed by Gemini-North and UKIRT
Icarus 218:1 (2012) 47-55