Isotopic ratios in titan's methane: Measurements and modeling
Astrophysical Journal 749:2 (2012)
Abstract:
The existence of methane in Titan's atmosphere (∼6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of ∼20Myr. In this paper, we examine the clues available from isotopic ratios (12C/13C and D/H) in Titan's methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: 13CH4, 12CH3D, and 13CH3D. From these we compute estimates of 12C/13C= 86.5 ± 8.2 and D/H= (1.59 ± 0.33) × 10-4, in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan's methane: CH4+ C2H→ CH3+ C2H2. Using these new measurements and predictions we proceed to model the time evolution of 12C/13C and D/H in Titan's methane under several prototypical replenishment scenarios. In our Model1 (no resupply of CH4), we find that the present-day 12C/13C implies that the CH4 entered the atmosphere 60-1600Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently - most likely less than 10Myr ago - if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane. © 2012 The American Astronomical Society. All rights reserved.The 2010 European Venus Explorer (EVE) mission proposal
Experimental Astronomy 33:2-3 (2012) 305-335
Abstract:
The European Venus Explorer (EVE) mission described in this paper was proposed in December 2010 to ESA as an 'M-class' mission under the Cosmic Vision programme. It consists of a single balloon platform floating in the middle of the main convective cloud layer of Venus at an altitude of 55 km, where temperatures and pressures are benign (~25°C and ~0. 5 bar). The balloon float lifetime would be at least 10 Earth days, long enough to guarantee at least one full circumnavigation of the planet. This offers an ideal platform for the two main science goals of the mission: study of the current climate through detailed characterization of cloud-level atmosphere, and investigation of the formation and evolution of Venus, through careful measurement of noble gas isotopic abundances. These investigations would provide key data for comparative planetology of terrestrial planets in our solar system and beyond. © 2011 Springer Science+Business Media B.V.EnVision: taking the pulse of our twin planet
Experimental Astronomy Springer Nature 33:2-3 (2012) 337-363
Lunar Net—a proposal in response to an ESA M3 call in 2010 for a medium sized mission
Experimental Astronomy Springer Nature 33:2-3 (2012) 587-644
Further seasonal changes in Uranus' cloud structure observed by Gemini-North and UKIRT
Icarus 218:1 (2012) 47-55