Seasonal disappearance of far-infrared haze in Titan's stratosphere

Astrophysical Journal Letters 754:1 (2012)

Authors:

DE Jennings, CM Anderson, RE Samuelson, FM Flasar, CA Nixon, VG Kunde, RK Achterberg, V Cottini, R De Kok, A Coustenis, S Vinatier, SB Calcutt

Abstract:

A far-infrared emission band attributed to volatile or refractory haze in Titan's stratosphere has been decreasing in intensity since Cassini's arrival in 2004. The 220cm-1 feature, first seen by the Voyager Infrared Interferometer Spectrometer, has only been found in Titan's winter polar region. The emission peaks at about 140km altitude near the winter stratospheric temperature minimum. Observations recorded over the period 2004-2012 by the Composite Infrared Spectrometer on Cassini show a decrease in the intensity of this feature by about a factor of four. Possible seasonal causes of this decline are an increase in photolytic destruction of source chemicals at high altitude, a lessening of condensation as solar heating increased, or a weakening of downwelling of vapors. As of early 2012, the 220cm-1 haze has not yet been detected in the south. The haze composition is unknown, but its decrease is similar to that of HC3N gas in Titan's polar stratosphere, pointing to a nitrile origin. © 2012. The American Astronomical Society. All rights reserved.

Investigation of new band parameters with temperature dependence for self-broadened methane gas in the range 9000 to 14,000cm -1 (0.71 to 1.1μm)

Journal of Quantitative Spectroscopy and Radiative Transfer 113:10 (2012) 763-782

Authors:

N Bowles, R Passmore, K Smith, G Williams, S Calcutt, PGJ Irwin

Abstract:

This paper describes new measurements and modelling of the absorption of methane gas, one of the most important gases observed in the atmospheres of the outer planets and Titan, between 9000 and 14,000cm -1 (0.7 to 1.1μm) and compares them with current best available spectral models.A series of methane spectra were measured at the UK's Natural Environment Research Council (NERC) Molecular Spectroscopy Facility (based at the Rutherford Appleton Laboratory, Oxfordshire, UK) using a Brüker 125HR Fourier transform spectrometer. To approximate the conditions found in outer planet atmospheres, the spectra were measured over a wide range of pressures (5bar to 38mbar) and temperatures (290-100K) with path lengths of 19.3, 17.6, 16.0 and 14.4m. The spectra were recorded at a moderate resolution of 0.12cm -1 and then averaged to 10cm -1 resolution prior to fitting a series of increasingly complex band-models including temperature dependence. Using the most complex model, a Goody line distribution with a Voigt line shape and two lower energy state levels, the typical rms residual error in the fit is between 0.01 and 0.02 in the wings of the main absorption bands.The new spectral parameters were then compared with the measured spectra and spectra calculated using existing data and shown to be able to accurately reproduce the measured absorption. The improvement in the temperature dependence included in the model is demonstrated by comparison with existing cold methane spectral data for a typical Jovian path. © 2012 Elsevier Ltd.

Investigation of new band parameters with temperature dependence for self-broadened methane gas in the range 9000 to 14,000cm−1 (0.71 to 1.1μm)

Journal of Quantitative Spectroscopy and Radiative Transfer Elsevier 113:10 (2012) 763-782

Authors:

Neil Bowles, R Passmore, K Smith, G Williams, S Calcutt, PGJ Irwin

Characterizing atmospheric waves on Venus, Earth, and Mars

Eos 93:23 (2012) 220

Authors:

CF Wilson, A Piccialli

Abstract:

Atmospheric Waves Workshop; Noordwijk, Netherlands, 9-10 November 2011 Experts in observations and modeling of atmospheric waves from the Earth and planetary atmospheric science communities came together at a November 2011 workshop held at the European Space Agency's (ESA) European Space Research and Technology Centre (ESTEC) site in the Netherlands to discuss the nature of waves observed in Venus's atmosphere and their comparison to those on Earth and Mars. ESA's Venus Express (VEx) satellite and ground-based observers find atmospheric waves at many scales. Migrating solar tides and other planetary-scale waves are observed in cloud-tracking wind vectors and temperature fields. Mesoscale gravity waves (GWs) can also be seen at a variety of levels from the cloud base up to the thermosphere, evident in imagery and in vertical profiles of temperature, density, and aerosol abundance. This workshop focused particularly on GWs, as their role in the atmospheric circulation is still poorly understood. © 2012 American Geophysical Union. All Rights Reserved.

Observations of upper tropospheric acetylene on Saturn: No apparent correlation with 2000 km-sized thunderstorms

Planetary and Space Science 65:1 (2012) 21-37

Authors:

J Hurley, PGJ Irwin, LN Fletcher, JI Moses, B Hesman, J Sinclair, C Merlet

Abstract:

Thunderstorm activity has been observed on Saturn via radio emissions from lightning discharges and optical detections of the lightning flashes on the planets nightside. Thunderstorms provide extreme environments in which specific atmospheric chemistry can be induced - namely through energy release via lightning discharges, and fast vertical transport resulting in rapid advection of tropospheric species. It is thus theorised that certain atmospheric trace species such as C 2H 2, HCN, and CO can be generated in the troposphere by large bursts of energy in the form of lightning, and transported upward towards the upper troposphere by the extreme dynamics of thunderstorms, where they should be observable by satellite instruments. In this work, high-spectral-resolution Cassini/CIRS observations from October 2005 through April 2009 are used to study whether there is an observable increase in upper tropospheric acetylene in regions of known normal thunderstorm activity. Using both individual measurements in which there is known thunderstorm activity, as well as large coadditions of data to study latitudinal-dependencies over the full disc, no systematic enhancement in upper tropospheric (100 mbar) C 2H 2 was detected around regions in which there are known occurrences of normally sized (2000 km) thunderstorms, or in normally sized thunderstorm-prone regions such as 40°S. It is likely that the magnitude of the enhancement theorised is too generous or that enhancements are not advected into the upper troposphere as vertical mixing rates in models would suggest, since Cassini/CIRS can only detect C 2H 2 above the 200 mbar level - although the massive northern hemisphere thunderstorm of 2010/2011 seems able to decrease stratospheric concentrations of C 2H 2. From this, it can be asserted that lightning from normal thunderstorm activity cannot be the key source for upper tropospheric C 2H 2 on Saturn, since the upper-tropospheric concentrations retrieved agree with the concentrations stemming from the photolysis of CH 4 (23 ppbv) from solar radiation penetrating through the Saturnian atmosphere, with an upper limit for lightning-induced C 2H 2 volume mixing ratio of 10 -9. © 2012 Elsevier Ltd. All rights reserved.