The composition of Titan's stratosphere from Cassini/CIRS mid-infrared spectra
Icarus 189:1 (2007) 35-62
Abstract:
We have analyzed data recorded by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft during the Titan flybys T0-T10 (July 2004-January 2006). The spectra characterize various regions on Titan from 70° S to 70° N with a variety of emission angles. We study the molecular signatures observed in the mid-infrared CIRS detector arrays (FP3 and FP4, covering roughly the 600-1500 cm-1 spectral range with apodized resolutions of 2.54 or 0.53 cm-1). The composite spectrum shows several molecular signatures: hydrocarbons, nitriles and CO2. A firm detection of benzene (C6H6) is provided by CIRS at levels of about 3.5 × 10-9 around 70° N. We have used temperature profiles retrieved from the inversion of the emission observed in the methane ν4 band at 1304 cm-1 and a line-by-line radiative transfer code to infer the abundances of the trace constituents and some of their isotopes in Titan's stratosphere. No longitudinal variations were found for these gases. Little or no change is observed generally in their abundances from the south to the equator. On the other hand, meridional variations retrieved for these trace constituents from the equator to the North ranged from almost zero (no or very little meridional variations) for C2H2, C2H6, C3H8, C2H4 and CO2 to a significant enhancement at high northern (early winter) latitudes for HCN, HC3N, C4H2, C3H4 and C6H6. For the more important increases in the northern latitudes, the transition occurs roughly between 30 and 50 degrees north latitude, depending on the molecule. Note however that the very high-northern latitude results from tours TB-T10 bear large uncertainties due to few available data and problems with latitude smearing effects. The observed variations are consistent with some, but not all, of the predictions from dynamical-photochemical models. Constraints are set on the vertical distribution of C2H2, found to be compatible with 2-D equatorial predictions by global circulation models. The D/H ratio in the methane on Titan has been determined from the CH3D band at 1156 cm-1 and found to be 1.17-0.28+0.23 × 10-4. Implications of this deuterium enrichment, with respect to the protosolar abundance on the origin of Titan, are discussed. We compare our results with values retrieved by Voyager IRIS observations taken in 1980, as well as with more recent (1997) disk-averaged Infrared Space Observatory (ISO) results and with the latest Cassini-Huygens inferences from other instruments in an attempt to better comprehend the physical phenomena on Titan. © 2007 Elsevier Inc. All rights reserved.A golden circle in the sky
Nature Springer Nature 447:7147 (2007) 911-911
Mars Climate Sounder: An investigation of thermal and water vapor structure, dust and condensate distributions in the atmosphere, and energy balance of the polar regions
Journal of Geophysical Research: Planets 112:5 (2007)
Abstract:
Against a backdrop of intensive exploration of the Martian surface environment, intehded to lead to human exploration, some aspects of the modern climate and the meteorology of Mars remain relatively unexplored. In particular, there is a need for detailed measurements of the vertical profiles of atmospheric temperature, water vapor, dust, and condensates to understand the intricately related processes upon which the surface conditions, and those encountered during descent by landers, depend. The most important of these missing data are accurate and extensive temperature measurements with high vertical resolution. The Mars Climate Sounder experiment on the 2005 Mars Reconnaissance Orbiter, described here, is the latest attempt to characterize the Martian atmosphere with the sort of coverage and precision achieved by terrestrial weather satellites. If successful, it is expected to lead to corresponding improvements in our understanding of meteorological phenomena and to enable improved general circulation models of the Martian atmosphere for climate studies on a range of timescales. Copyright 2007 by the American Geophysical Union.Meridional variations of C2 H2 and C2 H6 in Jupiter's atmosphere from Cassini CIRS infrared spectra
Icarus 188:1 (2007) 47-71
Abstract:
Hydrocarbons such as acetylene (C2H2) and ethane (C2H6) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm-1 (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm-1) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν4 band of CH4, and in the troposphere at 150-400 mbar, via the H2 absorption at 600-800 cm-1. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C2H2 and C2H6 by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C2H2ν5 and C2H6ν9 bands, and also emission of the acetylene (ν4 + ν5) - ν4 hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼ 3 × 10-9. Additionally, the abundance gradient of C2H2 between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C2H2 and C2H6 by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C2H6 in the stratosphere (3 × 1010 s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5 - 50 × 108 s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C2H2, the opposite occurs, with the relatively short photochemical lifetime (3 × 107 s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible. © 2006 Elsevier Inc. All rights reserved.The meridional phosphine distribution in Saturn's upper troposphere from Cassini/CIRS observations
Icarus 188:1 (2007) 72-88