Prof. Patrick Irwin

Abstract:

<jats:title>Abstract</jats:title> <jats:p>We present an analysis of all currently available ground-based imaging of Neptune in the mid-infrared. Dating between 2003 and 2020, the images reveal changes in Neptune’s mid-infrared (∼8–25 <jats:italic>μ</jats:italic>m) emission over time in the years surrounding Neptune’s 2005 southern summer solstice. Images sensitive to stratospheric ethane (∼12 <jats:italic>μ</jats:italic>m), methane (∼8 <jats:italic>μ</jats:italic>m), and CH<jats:sub>3</jats:sub>D (∼9 <jats:italic>μ</jats:italic>m) display significant subseasonal temporal variation on regional and global scales. Comparison with H<jats:sub>2</jats:sub> S(1) hydrogen quadrupole (∼17.035 <jats:italic>μ</jats:italic>m) spectra suggests that these changes are primarily related to stratospheric temperature changes. The stratosphere appears to have cooled between 2003 and 2009 across multiple filtered wavelengths, followed by a dramatic warming of the south pole between 2018 and 2020. Conversely, upper-tropospheric temperatures—inferred from ∼17 to 25 <jats:italic>μ</jats:italic>m imaging—appear invariant during this period, except for the south pole, which appeared warmest between 2003 and 2006. We discuss the observed variability in the context of seasonal forcing, tropospheric meteorology, and the solar cycle. Collectively, these data provide the strongest evidence to date that processes produce subseasonal variation on both global and regional scales in Neptune’s stratosphere.</jats:p>

Abstract:

Abstract Curiously, n-butane has yet to be detected at Titan, though it is predicted to be present in a wide range of abundances that span over 2.5 orders of magnitude. We have searched infrared spectroscopic observations of Titan for signals from n-butane (n-C4H10) in Titan’s stratosphere. Three sets of Cassini Composite Infrared Spectrometer Focal Plane 4 (1050–1500 cm−1) observations were selected for modeling, having been collected from different flybys and pointing latitudes. We modeled the observations with the Nonlinear Optimal Estimator for MultivariatE Spectral AnalySIS radiative transfer tool. Temperature profiles were retrieved for each of the data sets by modeling the ν 4 emission from methane near 1305 cm−1. Then, incorporating the temperature profiles, we retrieved abundances of all of Titan’s known trace gases that are active in this spectral region, reliably reproducing the observations. We then systematically tested a set of models with varying abundances of n-butane, investigating how the addition of this gas affected the fits. We did this for several different photochemically predicted abundance profiles from the literature, as well as for a constant-with-altitude profile. Ultimately, though we did not produce any firm detection of n-butane, we derived new upper limits on its abundance specific to the use of each profile and to multiple different ranges of stratospheric altitudes. These results will tightly constrain the C4 chemistry of future photochemical modeling of Titan’s atmosphere and also motivate the continued search for n-butane and its isomer, isobutane.