Prof. Patrick Irwin

Abstract:

Saturn’s moon Titan undergoes a long annual cycle of 29.45 Earth years. Titan’s northern winter and spring were investigated in detail by the Cassini–Huygens spacecraft (2004–2017), but the northern summer season remains sparsely studied. Here we present new observations from the James Webb Space Telescope (JWST) and Keck II telescope made in 2022 and 2023 during Titan’s late northern summer. Using JWST’s mid-infrared instrument, we spectroscopically detected the methyl radical, the primary product of methane break-up and key to the formation of ethane and heavier molecules. Using the near-infrared spectrograph onboard JWST, we detected several non-local thermodynamic equilibrium CO and CO2 emission bands, which allowed us to measure these species over a wide altitude range. Lastly, using the near-infrared camera onboard JWST and Keck II, we imaged northern hemisphere tropospheric clouds evolving in altitude, which provided new insights and constraints on seasonal convection patterns. These observations pave the way for new observations and modelling of Titan’s climate and meteorology as it progresses through the northern fall equinox, when its atmosphere is expected to show notable seasonal changes.

Abstract:

Titan, Saturn’s largest satellite, maintains an atmosphere composed primarily of nitrogen (N2) and methane (CH4) that leads to complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced 15N abundances compared to Earth and Titan’s dominant nitrogen (N2) reservoir. The 14N/15N isotopic ratio in Titan’s nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan’s large nitrogen abundance. Using high signal-to-noise ratio (>13), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array Band 6 receiver (211–275 GHz), we measure the 14N/15N and 12C/13C isotopic ratios of acetonitrile (CH3CN) in Titan’s stratosphere. Using the NEMESIS, we derived the CH3CN/13CH3CN ratio to be 89.2 ± 7.0 and the CH3CN/CH313CN ratio to be 91.2 ± 6.0, in agreement with the 12C/13C ratio in Titan’s methane and other solar system species. We found the 14N/15N isotopic ratio to be 68.9 ± 4.2, consistent with previously derived values for HCN and HC3N, confirming an enhanced 15N abundance in Titan’s nitriles compared with the bulk atmospheric N2 value of 14N/15N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N2 at high altitudes.

Abstract:

Whether or not there is a particulate layer in the lowest 10 km of the Venusian atmosphere is still an open question. Some of the past in situ experiments showed the presence of a detached particulate layer, and a few suggested the existence of finely dispersed aerosols, while other instruments supported the idea of no particulate matter in the deep atmosphere. In this work, we investigate the presence of a near‐surface particulate layer (NSPL) using in situ data from the Venera 13 mission. While the original spectrophotometric data from Venera 13 were lost, we have reconstructed a part of this data by digitizing the old graphic material and selected the eight most reliable Venera 13 downward radiance profiles from 0.48 to 0.8 μ ${\upmu }$ m for our retrievals. The retrievals suggest the existence of the particulate layer with a peak in the altitude range of 3.5–5 km. They further indicate a log‐normal particle size distribution with a mean radius between 0.6 and 0.85 μ ${\upmu }$ m. The retrievals constrain the real refractive index of the particles to lie around the range of 1.4–1.6, with the imaginary refractive index of a magnitude of 10 − 3 ${10}^{-3}$ . Based on refractive index retrievals, uplifted basalt particles or volcanic ash could be responsible for near‐surface particulates. In comparison, volatile condensates appear less likely to be behind the formation of NSPL.

Abstract:

A range of concepts for long duration aerial missions, using high altitude balloons operating in the clouds of Venus, have been studied by NASA and JPL for the Planetary Science and Astrobiology Decadal Survey and for NASA's competitive New Frontiers and Discovery programs. These concepts offer a rich set of scientific opportunities in atmospheric chemistry, astrobiology, atmospheric dynamics, seismology and sub-cloud surface imaging. The Venus aerobot would be sustained in flight by a variable-altitude balloon and carry a payload of instruments at altitudes between 52 and 62 km. The aerobot would fly in the cloud layer containing sulfuric acid aerosols and be subject to large temperature extremes as it traverses a range of altitudes and latitudes at different times of day. To achieve the desired lifetime on the order of one Venus day we have defined a solar power system that would supply power over the full altitude range while the aerobot is circumnavigating the planet. We have initiated development of the requisite technology, including rechargeable batteries, solar arrays, and a peak power tracker for this challenging mission. Specifically, we have fabricated triple-junction inverted metamorphic (IMM) solar cells optimized for power generation in the unique spectrum of light expected at 51.5 km altitude and measured 34.0 mW/cm2 power output at room temperature in initial testing. We developed a coating to protect aerobot solar panels from corrosion in sulfuric acid and demonstrated survival without performance degradation after 96 hours in 96% aqueous sulfuric acid at room temperature. Initial performance data were obtained on a peak power tracker showing 96% power conversion efficiency. In addition, we have developed specialized lithium-ion cells intended to operate between -30 and 100°C and demonstrated 80% capacity retention after 90 cycles at 100% depth of discharge at 100 deg C. These cells were incorporated into a 4s1p battery module and successfully tested under expected flight-like random vibration and thermal vacuum conditions. These results represent key steps in the process of developing the power system technology needed to bring the Venus aerobot mission to fruition.