Characterising Saturn's vertical temperature structure from Cassini/CIRS
Icarus 189:2 (2007) 457-478
Abstract:
Thermal infrared spectra of Saturn from 10-1400 cm-1 at 15 cm-1 spectral resolution and a spatial resolution of 1°-2° latitude have been obtained by the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297]. Many thousands of spectra, acquired over eighteen-months of observations, are analysed using an optimal estimation retrieval code [Irwin, P.G.J., Parrish, P., Fouchet, T., Calcutt, S.B., Taylor, F.W., Simon-Miller, A.A., Nixon, C.A., 2004. Icarus 172, 37-49] to retrieve the temperature structure and para-hydrogen distribution over Saturn's northern (winter) and southern (summer) hemispheres. The vertical temperature structure is analysed in detail to study seasonal asymmetries in the tropopause height (65-90 mbar), the location of the radiative-convective boundary (350-500 mbar), and the variation with latitude of a temperature knee (between 150 and 300 mbar) which was first observed in inversions of Voyager/IRIS spectra [Hanel, R., and 15 colleagues, 1981. Science 212, 192-200; Hanel, R., Conrath, B., Flasar, F.M., Kunde, V., Maguire, W., Pearl, J.C., Pirraglia, J., Samuelson, R., Cruikshank, D.P., Gautier, D., Gierasch, P.J., Horn, L., Ponnamperuma, C., 1982. Science 215, 544-548]. Uncertainties due to both the modelling of spectral absorptions (collision-induced absorption coefficients, tropospheric hazes, helium abundance) and the nature of our retrieval algorithm are quantified. Temperatures in the stratosphere near 1 mbar show a 25-30 K temperature difference between the north pole and south pole. This asymmetry becomes less pronounced with depth as the radiative time constant for the atmospheric response increases at deeper pressure levels. Hemispherically-symmetric small-scale temperature structures associated with zonal winds are superimposed onto the temperature asymmetry for pressures greater than 100 mbar. The para-hydrogen fraction in the 100-400 mbar range is greater than equilibrium predictions for the southern hemisphere and parts of the northern hemisphere, and less than equilibrium predictions polewards of 40° N. The temperature knee between 150-300 mbar is larger in the summer hemisphere than in the winter, smaller and higher at the equator, deeper and larger in the equatorial belts and small at the poles. Solar heating on tropospheric haze is proposed as a possible mechanism for this effect; the increased efficiency of ortho- to para-hydrogen conversion in the southern hemisphere is consistent with the presence of larger aerosols in the summer hemisphere, which we demonstrate to be qualitatively consistent with previous studies of Saturn's tropospheric aerosol distribution. © 2007 Elsevier Inc. All rights reserved.Quantifying the effect of finite field-of-view size on radiative transfer calculations of Titan's limb spectra measured by Cassini-CIRS
Astrophysics and Space Science 310:3-4 (2007) 293-305
Abstract:
The Composite InfraRed Spectrometer (CIRS) on-board the Cassini spacecraft has currently returned around three years worth of data from Saturn's largest moon Titan. One of the unique aspects of CIRS is to take high spatial resolution spectra of the limb of Titan, with sub-scale height (20-40 km) resolutions. This is made possible by the small field-of-view (FOV) of the mid-IR detectors. However, many limb spectra have moderate to large sized FOVs, which introduces bias into retrieved profiles of temperature and abundance unless the finite FOV size is taken into account. The bias can be reduced by calculating a FOV-averaged spectrum comprising a weighted sum of a small number of spectra with infinitesimal FOVs across the FOV. Here we introduce a scheme for incorporating FOV averaging into radiative transfer calculations of CIRS spectra and quantify the errors as a function of number of FOV averaging points, FOV size, tangent altitude, and wavenumber. The optimum number of FOV averaging points for a given observation can then be found by matching the calculated FOV averaging error with the measurement error. This allows for accurate analysis of a vast amount of Cassini-CIRS data. © 2007 Springer Science+Business Media B.V.The composition of Titan's stratosphere from Cassini/CIRS mid-infrared spectra
Icarus 189:1 (2007) 35-62
Abstract:
We have analyzed data recorded by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft during the Titan flybys T0-T10 (July 2004-January 2006). The spectra characterize various regions on Titan from 70° S to 70° N with a variety of emission angles. We study the molecular signatures observed in the mid-infrared CIRS detector arrays (FP3 and FP4, covering roughly the 600-1500 cm-1 spectral range with apodized resolutions of 2.54 or 0.53 cm-1). The composite spectrum shows several molecular signatures: hydrocarbons, nitriles and CO2. A firm detection of benzene (C6H6) is provided by CIRS at levels of about 3.5 × 10-9 around 70° N. We have used temperature profiles retrieved from the inversion of the emission observed in the methane ν4 band at 1304 cm-1 and a line-by-line radiative transfer code to infer the abundances of the trace constituents and some of their isotopes in Titan's stratosphere. No longitudinal variations were found for these gases. Little or no change is observed generally in their abundances from the south to the equator. On the other hand, meridional variations retrieved for these trace constituents from the equator to the North ranged from almost zero (no or very little meridional variations) for C2H2, C2H6, C3H8, C2H4 and CO2 to a significant enhancement at high northern (early winter) latitudes for HCN, HC3N, C4H2, C3H4 and C6H6. For the more important increases in the northern latitudes, the transition occurs roughly between 30 and 50 degrees north latitude, depending on the molecule. Note however that the very high-northern latitude results from tours TB-T10 bear large uncertainties due to few available data and problems with latitude smearing effects. The observed variations are consistent with some, but not all, of the predictions from dynamical-photochemical models. Constraints are set on the vertical distribution of C2H2, found to be compatible with 2-D equatorial predictions by global circulation models. The D/H ratio in the methane on Titan has been determined from the CH3D band at 1156 cm-1 and found to be 1.17-0.28+0.23 × 10-4. Implications of this deuterium enrichment, with respect to the protosolar abundance on the origin of Titan, are discussed. We compare our results with values retrieved by Voyager IRIS observations taken in 1980, as well as with more recent (1997) disk-averaged Infrared Space Observatory (ISO) results and with the latest Cassini-Huygens inferences from other instruments in an attempt to better comprehend the physical phenomena on Titan. © 2007 Elsevier Inc. All rights reserved.Meridional variations of C2 H2 and C2 H6 in Jupiter's atmosphere from Cassini CIRS infrared spectra
Icarus 188:1 (2007) 47-71
Abstract:
Hydrocarbons such as acetylene (C2H2) and ethane (C2H6) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm-1 (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm-1) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν4 band of CH4, and in the troposphere at 150-400 mbar, via the H2 absorption at 600-800 cm-1. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C2H2 and C2H6 by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C2H2ν5 and C2H6ν9 bands, and also emission of the acetylene (ν4 + ν5) - ν4 hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼ 3 × 10-9. Additionally, the abundance gradient of C2H2 between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C2H2 and C2H6 by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C2H6 in the stratosphere (3 × 1010 s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5 - 50 × 108 s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C2H2, the opposite occurs, with the relatively short photochemical lifetime (3 × 107 s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible. © 2006 Elsevier Inc. All rights reserved.The meridional phosphine distribution in Saturn's upper troposphere from Cassini/CIRS observations
Icarus 188:1 (2007) 72-88