Exploring the atmosphere of Neoproterozoic Earth: The effect of O2 on haze formation and composition
Astrophysical Journal American Astronomical Society 858:2 (2018) 119
Abstract:
Previous studies of haze formation in the atmosphere of the early Earth have focused on N2/CO2/CH4 atmospheres. Here, we experimentally investigate the effect of O2 on the formation and composition of aerosols to improve our understanding of haze formation on the Neoproterozoic Earth. We obtained in situ size, particle density, and composition measurements of aerosol particles produced from N2/CO2/CH4/O2 gas mixtures subjected to FUV radiation (115–400 nm) for a range of initial CO2/CH4/O2 mixing ratios (O2 ranging from 2 ppm to 0.2%). At the lowest O2 concentration (2 ppm), the addition increased particle production for all but one gas mixture. At higher oxygen concentrations (20 ppm and greater), particles are still produced, but the addition of O2 decreases the production rate. Both the particle size and number density decrease with increasing O2, indicating that O2 affects particle nucleation and growth. The particle density increases with increasing O2. The addition of CO2 and O2 not only increases the amount of oxygen in the aerosol, but it also increases the degree of nitrogen incorporation. In particular, the addition of O2 results in the formation of nitrate-bearing molecules. The fact that the presence of oxygen-bearing molecules increases the efficiency of nitrogen fixation has implications for the role of haze as a source of molecules required for the origin and evolution of life. The composition changes also likely affect the absorption and scattering behavior of these particles but optical property measurements are required to fully understand the implications for the effect on the planetary radiative energy balance and climate.Descent rate models of the synchronization of the Quasi-Biennial Oscillation by the annual cycle in tropical upwelling
Journal of the Atmospheric Sciences American Meteorological Society 75:7 (2018) 2281-2297
Abstract:
The response of the Quasi-Biennial Oscillation (QBO) to an imposed mean upwelling with a periodic modulation is studied, by modelling the dynamics of the zero wind line at the equator using a class of equations known as ‘descent rate’ models. These are simple mathematical models that capture the essence of QBO synchronization by focusing on the dynamics of the height of the zero wind line. A heuristic descent rate model for the zero wind line is described, and is shown to capture many of the synchronization features seen in previous studies of the QBO. Using a simple transformation, it is then demonstrated that the standard Holton-Lindzen model of the QBO can itself be put into the form of a descent rate model if a quadratic velocity profile is assumed below the zero wind line. The resulting non-autonomous ordinary differential equation captures much of the synchronization behaviour observed in the full Holton-Lindzen partial differential equation. The new class of models provides a novel framework within which to understand synchronization of the QBO, and we demonstrate a close relationship between these models and the circle map well-known in the mathematics literature. Finally, we analyse reanalysis datasets to validate some of the predictions of our descent rate models, and find statistically significant evidence for synchronization of the QBO that is consistent with model behaviour.The roles of static stability and tropical-extratropical interactions in the summer interannual variability of the North Atlantic sector
Climate Dynamics Springer Verlag 52:3-4 (2018) 1299-1315
Abstract:
Summer seasonal forecast skill in the North Atlantic sector is lower than winter skill. To identify potential controls on predictability, the sensitivity of North Atlantic baroclinicity to atmospheric drivers is quantified. Using ERA-INTERIM reanalysis data, North Atlantic storm-track baroclinicity is shown to be less sensitive to meridional temperature-gradient variability in summer. Static stability shapes the sector’s interannual variability by modulating the sensitivity of baroclinicity to variations in meridional temperature gradients and tropopause height and by modifying the baroclinicity itself. High static stability anomalies at upper levels result in more zonal extratropical cyclone tracks and higher eddy kinetic energy over the British Isles in the summertime. These static stability anomalies are not strongly related to the summer NAO; but they are correlated with the suppression of convection over the tropical Atlantic and with a poleward-shifted subtropical jet. These results suggest a non-local driver of North Atlantic variability. Furthermore, they imply that improved representations of convection over the south-eastern part of North America and the tropical Atlantic might improve summer seasonal forecast skill.Overview of experiment design and comparison of models participating in phase 1 of the SPARC Quasi-Biennial Oscillation initiative (QBOi)
Geoscientific Model Development Copernicus Publications 11:3 (2018) 1009-1032
Abstract:
The Stratosphere–troposphere Processes And their Role in Climate (SPARC) Quasi-Biennial Oscillation initiative (QBOi) aims to improve the fidelity of tropical stratospheric variability in general circulation and Earth system models by conducting coordinated numerical experiments and analysis. In the equatorial stratosphere, the QBO is the most conspicuous mode of variability. Five coordinated experiments have therefore been designed to (i) evaluate and compare the verisimilitude of modelled QBOs under present-day conditions, (ii) identify robustness (or alternatively the spread and uncertainty) in the simulated QBO response to commonly imposed changes in model climate forcings (e.g. a doubling of CO2 amounts), and (iii) examine model dependence of QBO predictability. This paper documents these experiments and the recommended output diagnostics. The rationale behind the experimental design and choice of diagnostics is presented. To facilitate scientific interpretation of the results in other planned QBOi studies, consistent descriptions of the models performing each experiment set are given, with those aspects particularly relevant for simulating the QBO tabulated for easy comparison.Seasonal sensitivity of the Hadley cell and cross-hemispheric responses to diabatic heating in an idealized GCM
Geophysical Research Letters American Geophysical Union 45:5 (2018) 2533-2541