JWST reveals cosmic ray dominated chemistry in the local ULIRG IRAS 07251−0248

Monthly Notices of the Royal Astronomical Society: Letters Oxford University Press 542:1 (2025) L117-L125

Authors:

G Speranza, M Pereira-Santaella, M Agúndez, E González-Alfonso, I García-Bernete, JR Goicoechea, M Imanishi, D Rigopoulou, MG Santa-Maria, N Thatte

Abstract:

We analyse the ro-vibrational absorption bands of various molecular cations (HCO, HCNH, and NH) and neutral species (HCN, HNC, and HCN) detected in the James Webb Space Telescope/Mid-Infrared Instrument Medium Resolution Spectrometer spectrum (4.9–27.9 μm) of the local ultraluminous infrared galaxy IRAS 07251-0248. We find that the molecular absorptions are blueshifted by 160 km s relative to the systemic velocity of the target. Using local thermal equilibrium excitation models, we derive rotational temperatures () from 42 to 185 K for these absorption bands. This range of measured can be explained by infrared radiative pumping as a by-product of the strength, effective critical density, and opacity of each molecular band. Thus, these results suggest that these absorptions originate in a warm expanding gas shell (90–330 yr), which might be the base of the larger scale cold molecular outflow detected in this source. Finally, the elevated abundance of molecular cations can be explained by a high cosmic ray ionization rate, with log(/n in the range of -18.2 (from H) to -19.1 (inferred from HCO and NH, which are likely tracing denser gas), consistent with a cosmic ray dominated chemistry as predicted by chemical models.

Measuring the Sun’s radial velocity variability due to supergranulation over a magnetic cycle

Monthly Notices of the Royal Astronomical Society Oxford University Press 541:4 (2025) 3942-3962

Authors:

Niamh K O’Sullivan, Suzanne Aigrain, Michael Cretignier, Ben Lakeland, Baptiste Klein, Xavier Dumusque, Nadège Meunier, Sophia Sulis, Megan Bedell, Annelies Mortier, Andrew Collier Cameron, Heather M Cegla

Abstract:

In recent years, supergranulation has emerged as one of the biggest challenges for the detection of Earth-twins in radial velocity planet searches. We used eight years of Sun-as-a-star radial velocity observations from HARPS-N to measure the quiet-Sun’s granulation and supergranulation properties of most of its 11-yr activity cycle, after correcting for the effects of magnetically active regions using two independent methods. In both cases, we observe a clear, order of magnitude variation in the time-scale of the supergranulation component, which is largest at activity minimum and is strongly anticorrelated with the relative Sunspot number. We also explored a range of observational strategies which could be employed to characterize supergranulation in stars other than the Sun, showing that a comparatively long observing campaign of at least 23 nights is required, but that up to 10 stars can be monitored simultaneously in the process. We conclude by discussing plausible explanations for the ‘supergranulation’ cycle.

A geochemical view on the ubiquity of CO2 on rocky exoplanets with atmospheres

Copernicus Publications (2025)

Authors:

Claire Marie Guimond, Oliver Shorttle, Raymond T Pierrehumbert

Abstract:

To aid the search for atmospheres on rocky exoplanets, we should know what to look for. An unofficial paradigm is to anticipate CO2 present in these atmospheres, through analogy to the solar system and through theoretical modelling. This CO2 would be outgassed from molten silicate rock produced in the planet’s mostly-solid interior—an ongoing self-cooling mechanism that should proceed, in general, so long as the planet has sufficient internal heat to lose.Outgassing of CO2 requires relatively oxidising conditions. Previous work has noted the importance of how oxidising the planet interior is (the oxygen fugacity), which depends strongly on its rock composition. Current models presume that redox reactions between iron species control oxygen fugacity. However, iron alone need not be the sole dictator of how oxidising a planet is. Indeed, carbon itself is a powerful redox element, with great potential to feed back upon the mantle redox state as it melts. Whilst Earth is carbon-poor, even a slightly-higher volatile endowment could trigger carbon-powered geochemistry.We offer a new framework for how carbon is transported from solid planetary interior to atmosphere. The model incorporates realistic carbon geochemistry constrained by recent experiments on CO2 solubility in molten silicate, as well as redox couplings between carbon and iron that have never before been applied to exoplanets. We also incorporate a coupled 1D energy- and mass-balance model to provide first-order predictions of the rate of volcanism.We show that carbon-iron redox coupling maintains interior oxygen fugacity in a narrow range: more reducing than Earth magma, but not reducing enough to destabilise CO2 gas. We predict that most secondary atmospheres, if present, should contain CO2, although the total pressure could be low. An atmospheric non-detection may indicate a planet either born astonishingly dry, or having shut off its internal heat engine.

Photochemistry versus Escape in the Trappist-1 planets.

(2025)

Authors:

Sarah Blumenthal, Richard Chatterjee, Harrison Nicholls, Louis Amard, Shang-Min Tsai, Tad Komacek, Raymond Pierrehumbert

Abstract:

Survive or not survive, that is the question of the 500-hour JWST Rocky Worlds DDT Program. Whether a terrestrial planets’ atmosphere can suffer under the intense XUV of its host, or if it completely escapes, these are the questions we explore. Zahnle & Catling (2017) defined the Cosmic Shoreline, but recent observations from JWST reveal airless worlds around M-stars, calling for a refinement of this “receding” shoreline (Pass et al. 2025). M-stars spend a longer time in pre-main sequence, subjecting their orbiting worlds to some higher intensity XUV activity. This complicates our present understanding of this shoreline. Investigating chemical effects of planet-star interactions could be the key to a more complete picture of this shoreline.  We investigate the interplay between photochemistry, mixing, and escape of carbon dioxide atmospheres under intense and mild XUV fluxes as follow on work to both Johnstone et al. (2018) and Nakayama et al. (2022). We expand on this work by adopting thermal structure models from Nakayama et al. (2022) and apply them to identify key chemical pathways for escape. We create a reduced C-O chemical network including neutral and ionic species to identify these pathways. As photochemistry simulations take into account many reactions, these 1D calculations are too computationally expensive to be done in 3D. Although rudimentary at best, the mixing parameter– eddy diffusion term, K_zz, comprises the dynamical element of 1D photochemical simulations. Here, we consider the mixing of photochemical products in competition with escape to explore the chemical pathways of retention and loss. We compare the photochemical model results for active and inactive cases for the Trappist-1 system planets. Then, using the resulting composition-dependent heating and cooling rates for Trappist-1 planets, we assess their propensity for efficient atomic line cooling versus escape. We follow the work of Chatterjee & Pierrehumbert (2024) in this assessment.  Finally, using our pathway analysis, we find an analytical formula for calculating an energy-limited escape boundary for these planets based on composition.  It is important here to note the limitations of 1D work. First, there exists an exchange of rigor between modelling chemistry and dynamics. Insights from this work are ripe for implementation into 3D GCMs, especially in response to incorporating UV-driven processes for thermospheric modelling mentioned in Ding and Wordsworth (2019). Second, interaction with the interior is important in the early phase of planetary formation, i.e., the magma ocean phase. Due to exchange between atmosphere and magma early in the planet’s formation, incorporation with an interior-atmosphere model would better constrain higher pressure chemical abundances. Although this work focuses on the upper atmosphere, extrapolation to the surface environment is a key goal for understanding a planet.  Considering planet-star interaction is imperative for the selection of targets for observation. However, it is also important when considering anomalous detections of atmospheres around planets predicted to not have an atmosphere. This could be a first step in determining an atmosphere as non-primary and/or distinguishing between an airless planet and one with high altitude haze. 

Super-Earth lava planet from birth to observation: photochemistry, tidal heating, and volatile-rich formation

Copernicus Publications (2025)

Authors:

Harrison Nicholls, Tim Lichtenberg, Richard D Chatterjee, Claire Marie Guimond, Emma Postolec, Raymond T Pierrehumbert

Abstract:

Larger-than-Earth exoplanets are sculpted by strong stellar irradiation, but it is unknown whence they originate. Two propositions are that they formed with rocky interiors and hydrogen-rich envelopes (‘gas-dwarfs’), or with bulk compositions rich in water-ices (‘water-worlds’) . Multiple observations of super-Earth L 98-59 d have revealed its low bulk-density, consistent with substantial volatile content alongside a rocky/metallic interior, and recent JWST spectroscopy evidences a high mean molecular weight atmosphere. Its density and composition make it a waymarker for disentangling the processes which separate super-Earths and sub-Neptunes across geological timescales. We simulate the possible pathways for L 98-59 d from birth up to the present day using a comprehensive evolutionary modelling framework. Emerging from our calculations is a novel self-limiting mechanism between radiative cooling, tidal heating, and mantle rheology, which we term the 'radiation-tide-rheology feedback'. Coupled numerical modelling yields self-limiting tidal heating estimates that are up to two orders of magnitude lower than previous calculations, and yet are still large enough to enable the extension of primordial magma oceans to Gyr timescales. Our analysis indicates that the planet formed with a large amount (>1.8 mass%) of sulfur and hydrogen, and a chemically-reducing mantle; inconsistent with both the canonical gas-dwarf and water-world scenarios. A thick atmosphere and tidal heating sustain a permanent deep magma ocean, allowing the dissolution and retention of volatiles within its mantle. Transmission features can be explained by in-situ photochemical production of SO2 in a high-molecular weight H2-H2S background. These results subvert the emerging gas-dwarf vs. water-world dichotomy of small planet categorisation, inviting a more nuanced classification framework. We show that interactions between planetary interiors and atmospheres shape their observable characteristics over billions of years.