Planetary atmosphere observation analysis

Abstract:

We have analyzed data recorded by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft during the Titan flybys T0-T10 (July 2004-January 2006). The spectra characterize various regions on Titan from 70° S to 70° N with a variety of emission angles. We study the molecular signatures observed in the mid-infrared CIRS detector arrays (FP3 and FP4, covering roughly the 600-1500 cm-1 spectral range with apodized resolutions of 2.54 or 0.53 cm-1). The composite spectrum shows several molecular signatures: hydrocarbons, nitriles and CO2. A firm detection of benzene (C6H6) is provided by CIRS at levels of about 3.5 × 10-9 around 70° N. We have used temperature profiles retrieved from the inversion of the emission observed in the methane ν4 band at 1304 cm-1 and a line-by-line radiative transfer code to infer the abundances of the trace constituents and some of their isotopes in Titan's stratosphere. No longitudinal variations were found for these gases. Little or no change is observed generally in their abundances from the south to the equator. On the other hand, meridional variations retrieved for these trace constituents from the equator to the North ranged from almost zero (no or very little meridional variations) for C2H2, C2H6, C3H8, C2H4 and CO2 to a significant enhancement at high northern (early winter) latitudes for HCN, HC3N, C4H2, C3H4 and C6H6. For the more important increases in the northern latitudes, the transition occurs roughly between 30 and 50 degrees north latitude, depending on the molecule. Note however that the very high-northern latitude results from tours TB-T10 bear large uncertainties due to few available data and problems with latitude smearing effects. The observed variations are consistent with some, but not all, of the predictions from dynamical-photochemical models. Constraints are set on the vertical distribution of C2H2, found to be compatible with 2-D equatorial predictions by global circulation models. The D/H ratio in the methane on Titan has been determined from the CH3D band at 1156 cm-1 and found to be 1.17-0.28+0.23 × 10-4. Implications of this deuterium enrichment, with respect to the protosolar abundance on the origin of Titan, are discussed. We compare our results with values retrieved by Voyager IRIS observations taken in 1980, as well as with more recent (1997) disk-averaged Infrared Space Observatory (ISO) results and with the latest Cassini-Huygens inferences from other instruments in an attempt to better comprehend the physical phenomena on Titan. © 2007 Elsevier Inc. All rights reserved.

Abstract:

Against a backdrop of intensive exploration of the Martian surface environment, intehded to lead to human exploration, some aspects of the modern climate and the meteorology of Mars remain relatively unexplored. In particular, there is a need for detailed measurements of the vertical profiles of atmospheric temperature, water vapor, dust, and condensates to understand the intricately related processes upon which the surface conditions, and those encountered during descent by landers, depend. The most important of these missing data are accurate and extensive temperature measurements with high vertical resolution. The Mars Climate Sounder experiment on the 2005 Mars Reconnaissance Orbiter, described here, is the latest attempt to characterize the Martian atmosphere with the sort of coverage and precision achieved by terrestrial weather satellites. If successful, it is expected to lead to corresponding improvements in our understanding of meteorological phenomena and to enable improved general circulation models of the Martian atmosphere for climate studies on a range of timescales. Copyright 2007 by the American Geophysical Union.

Abstract:

Hydrocarbons such as acetylene (C2H2) and ethane (C2H6) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm-1 (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm-1) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν4 band of CH4, and in the troposphere at 150-400 mbar, via the H2 absorption at 600-800 cm-1. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C2H2 and C2H6 by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C2H2ν5 and C2H6ν9 bands, and also emission of the acetylene (ν4 + ν5) - ν4 hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼ 3 × 10-9. Additionally, the abundance gradient of C2H2 between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C2H2 and C2H6 by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C2H6 in the stratosphere (3 × 1010   s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5 - 50 × 108   s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C2H2, the opposite occurs, with the relatively short photochemical lifetime (3 × 107   s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible. © 2006 Elsevier Inc. All rights reserved.

Abstract:

The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH3) abundance in Saturn's upper troposphere. PH3 has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10-600 cm-1) and mid (600-1400 cm-1) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm-1) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm-1), and lower resolution (2.5 cm-1) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250-500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The PH3 abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH3 abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60-65° S, with depleted PH3 at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH3 photolysis in the polar region. © 2006 Elsevier Inc. All rights reserved.

Abstract:

Limb spectra recorded by the Composite InfraRed Spectrometer (CIRS) on Cassini provide information on abundance vertical profiles of C2H2, C2H4, C2H6, CH3C2H, C3H8, C4H2, C6H6 and HCN, along with the temperature profiles in Titan's atmosphere. We analyzed two sets of spectra, one at 15° S (Tb flyby) and the other one at 80° N (T3 flyby). The spectral range 600-1400 cm-1, recorded at a resolution of 0.5 cm-1, was used to determine molecular abundances and temperatures in the stratosphere in the altitude range 100-460 km for Tb and 170-495 km for T3. Both temperature profiles show a well defined stratopause, at around 310 km (0.07 mbar) and 183 K at 13° S, and 380 km (0.01 mbar) with 207 K at 80° N. Near the north pole, stratospheric temperatures are colder and mesospheric temperatures are warmer than near the equator. C2H2, C2H6, C3H8 and HCN display vertical mixing ratio profiles that increase with height at 15° S and 80° N, consistent with their formation in the upper atmosphere, diffusion downwards and condensation in the lower stratosphere, as expected from photochemical models. The CH3C2H and C4H2 mixing ratios also increase with height at 15° S. But near the north pole, their profiles present an unexpected minimum around 300 km, observed for the first time thanks to the high vertical resolution of the CIRS limb data. C2H4 is the only molecule having a vertical abundance profile that decreases with height at 15° S. At 80° N, it also displays a minimum of its mixing ratio around the 0.1-mbar level. For C6H6, an upper limit of 1.1 ppb (in the 0.3-10 mbar range) is derived at 15° S, whereas a constant mixing ratio profile of 3-1.5+3   ppb is inferred near the north pole. At 15° S, the vertical profile of HCN exhibits a steeper gradient than other molecules, which suggests that a sink for this molecule exists in the stratosphere, possibly due to haze formation. All molecules display a more or less pronounced enrichment towards the north pole, probably due, in part, to subsidence of air at the north (winter) pole that brings air enriched in photochemical compounds from the upper atmosphere to lower levels. © 2006 Elsevier Inc. All rights reserved.