Irradiated Atmospheres. IV. Effect of Mixing Heat Flux on Chemistry

Astrophysical Journal 995:2 (2025)

Authors:

ZT Zhang, W Zhong, W Wang, J Guo, X Tan, B Ma, R Wei, C Yu

Abstract:

Vertical mixing disrupts the thermochemical equilibrium and introduces additional heat flux that alters exoplanetary atmospheric temperatures. We investigate how this mixing-induced heat flux affects atmospheric chemistry. Temperature increase in the lower atmosphere by the mixing-induced heat flux alters species abundances there and modifies those in the upper atmosphere through vertical transport. In the lower atmosphere, most species follow thermodynamic equilibrium with temperature changes. In the upper layers, species mixing ratios depend on the positions of quenching levels relative to the regions exhibiting significant mixing-induced temperature variations. When the quenching level resides within such a region (e.g., CO, CH4, and H2O with strong mixing), the mixing ratios in the upper atmosphere are modified due to changes in the quenched ratios affected by the temperature variation in the lower atmosphere. This alters the mixing ratio of other species (e.g., NO and CO2) through the chemical reaction network, whose quenching occurs in the region without much temperature change. The mixing ratios of CH4, H2O, and NH3 decrease in the lower atmosphere with increasing mixing heat flux, similarly reducing these ratios in the upper atmosphere. Conversely, the mixing ratios of CO, CO2, and NO rise in the lower atmosphere, with CO and CO2 also increasing in the upper levels, although NO decreases. Weaker host star irradiation lowers the overall temperature of the planet, allowing a smaller mixing to have a similar effect. We conclude that understanding the vertical mixing heat flux is essential for accurate atmospheric chemistry modeling and retrieval.

JWST NIRSpec finds no clear signs of an atmosphere on TOI-1685 b

(2025)

Authors:

Chloe E Fisher, Matthew J Hooton, Amà lie Gressier, Merlin Zgraggen, Meng Tian, Kevin Heng, Natalie H Allen, Richard D Chatterjee, Brett M Morris, Nicholas W Borsato, Nà stor Espinoza, Daniel Kitzmann, Tobias G Meier, Lars A Buchhave, Adam J Burgasser, Brice-Olivier Demory, Mark Fortune, H Jens Hoeijmakers, Raphael Luque, Erik A Meier Valdés, Joà OM Mendonça, Bibiana Prinoth, Alexander D Rathcke, Jake Taylor

Diversity in the haziness and chemistry of temperate sub-Neptunes

Nature Astronomy Springer Nature (2025) 1-14

Authors:

Pierre-Alexis Roy, Björn Benneke, Marylou Fournier-Tondreau, Louis-Philippe Coulombe, Caroline Piaulet-Ghorayeb, David Lafrenière, Romain Allart, Nicolas B Cowan, Lisa Dang, Doug Johnstone, Adam B Langeveld, Stefan Pelletier, Michael Radica, Jake Taylor, Loïc Albert, René Doyon, Laura Flagg, Ray Jayawardhana, Ryan J MacDonald, Jake D Turner

Abstract:

Recent transit observations of K2-18 b and TOI-270 d revealed strong molecular absorption signatures, lending credence to the idea that temperate sub-Neptunes (equilibrium temperature Teq = 250–400 K) have upper atmospheres mostly free of aerosols. These observations also indicated higher-than-expected CO2 abundances on both planets, implying bulk compositions with high water mass fractions. However, it remains unclear whether these findings hold true for all temperate sub-Neptunes. Here we present the JWST NIRSpec/PRISM 0.7–5.4-μm transmission spectrum of a third temperate sub-Neptune, the 2.4 R⊕ planet LP 791-18 c (Teq = 355 K), which is even more favourable for atmospheric characterization thanks to its small M6 host star. Intriguingly, despite the radius, mass and equilibrium temperature of LP 791-18 c being between those of K2-18 b and TOI-270 d, we find a drastically different transmission spectrum. Although we also detect methane on LP 791-18 c, its transit spectrum is dominated by strong haze scattering and there is no discernible CO2 absorption. Overall, we infer a deep metal-enriched atmosphere (246–415 times solar) for LP 791-18 c, with a CO2-to-CH4 ratio smaller than 0.07 (at 2σ), indicating less H2O in the deep envelope of LP 791-18 c and implying a relatively dry formation inside the water-ice line. These results show that sub-Neptunes that are near analogues in density and temperature can show drastically different aerosols and envelope chemistry and are intrinsically diverse beyond a simple temperature dependence.

JWST NIRSpec finds no clear signs of an atmosphere on TOI-1685 b

Monthly Notices of the Royal Astronomical Society Oxford University Press 545:4 (2025) staf2187

Authors:

Chloe E Fisher, Matthew J Hooton, Amélie Gressier, Merlin Zgraggen, Meng Tian, Kevin Heng, Natalie H Allen, Richard D Chatterjee, Brett M Morris, Nicholas W Borsato, Néstor Espinoza, Daniel Kitzmann, Tobias G Meier, Lars A Buchhave, Adam J Burgasser, Brice-Olivier Demory, Mark Fortune, H Jens Hoeijmakers, Raphael Luque, Erik A Meier Valdés, João M Mendonça, Bibiana Prinoth, Alexander D Rathcke, Jake Taylor

Abstract:

Determining the prevalence of atmospheres on terrestrial planets is a core objective in exoplanetary science. While M dwarf systems offer a promising opportunity, conclusive observations of terrestrial atmospheres have remained elusive, with many yielding flat transmission spectra. We observe four transits of the hot terrestrial planet TOI-1685 b using James Webb Space Telescope (JWST)’s Near Infrared Spectrograph (NIRSpec) G395H instrument. Combining this with the transit from the previously observed phase curve of the planet with the same instrument, we perform a detailed analysis to determine the possibility of an atmosphere on TOI-1685 b. From our retrievals, the Bayesian evidence favours a simple flat line model, indicating no evidence for an atmosphere on TOI-1685 b, in line with results from the phase curve analysis. Our results show that hydrogen-dominated atmospheres can be confidently ruled out. For heavier, secondary atmospheres we find a lower limit on the mean molecular weight of , at a significance of ~5σ. Pure , , , and atmospheres, or a mixed secondary atmosphere () could explain the data (). However, pure atmospheres may be physically unlikely, and the pure and cases require a high-altitude cloud, which could also be interpreted as a thin cloud-free atmosphere. We discuss the theoretical possibility for different types of atmosphere on this planet, and consider the effects of atmospheric escape and stellar activity on the system. Though we find that TOI-1685 b is likely a bare rock, this study also highlights the challenges of detecting secondary atmospheres on rocky planets with JWST.

A Thick Volatile Atmosphere on the Ultrahot Super-Earth TOI-561 b

The Astrophysical Journal Letters American Astronomical Society 995:2 (2025) L39

Authors:

Johanna K Teske, Nicole L Wallack, Anjali AA Piette, Lisa Dang, Tim Lichtenberg, Mykhaylo Plotnykov, Raymond Pierrehumbert, Emma Postolec, Samuel Boucher, Alex McGinty, Bo Peng, Diana Valencia, Mark Hammond

Abstract:

Ultrashort-period (USP) exoplanets—with Rp ≤ 2R⊕ and periods ≤1 day—are expected to be stripped of volatile atmospheres by intense host star irradiation, which is corroborated by their nominal bulk densities and previous eclipse observations, consistent with bare-rock surfaces. However, a few USP planets appear anomalously underdense relative to an Earth-like composition, suggesting an exotic interior structure (e.g., coreless) or a volatile-rich secondary atmosphere increasing their apparent radius. Here, we present the first dayside emission spectrum of the low-density (4.3 ± 0.4 g cm−3) USP planet TOI-561 b, which orbits an iron-poor, alpha-rich, ∼10 Gyr old thick-disk star. Our 3–5 μm JWST/NIRSpec observations demonstrate the dayside of TOI-561 b is inconsistent with a bare-rock surface at high statistical significance, suggesting instead a thick volatile envelope that is cooling the dayside to well below the ∼3000 K expected in the bare-rock or thin-atmosphere case. These results reject the popular hypothesis of complete atmospheric desiccation for highly irradiated exoplanets and support predictions that planetary-scale magma oceans can retain substantial reservoirs of volatiles, opening up the geophysical study of ultrahot super-Earths through the lenses of their atmospheres.