Quantum systems engineering

Abstract:

Stark many-body localized (SMBL) systems have been shown both numerically and experimentally to have Bloch many-body oscillations, quantum many-body scars, and fragmentation in the large field tilt limit, but these observations have not been fundamentally understood. We explain and analytically prove all these observations by rigorously perturbatively showing the existence of novel algebraic structures that are exponentially stable in time, which we call dynamical l-bits. In particular, we show that many-body Bloch oscillations persist even at infinite temperature for exponentially long-times using a new type of dynamical algebra and provide a bound on the tilt strength for this non-ergodic transition. We numerically confirm our results by studying the prototypical Stark MBL model of a tilted XXZ spin chain. Our work explains why thermalization was observed in a recent 2D tilted experiment. As dynamical l-bits represent stable, localized, and quantum coherent excitations, our work opens new possibilities for quantum information processing in Stark MBL systems even at high temperature.

Abstract:

Many complex systems can spontaneously oscillate under nonperiodic forcing. Such self-oscillators are commonplace in biological and technological assemblies where temporal periodicity is needed, such as the beating of a human heart or the vibration of a cello string. While self-oscillation is well understood in classical nonlinear systems and their quantized counterparts, the spontaneous emergence of periodicity in quantum systems is more elusive. Here, we show that this behavior can emerge within the repeated-interaction description of open quantum systems. Specifically, we consider a many-body quantum system that undergoes dissipation due to sequential coupling with auxiliary systems at random times. We develop dynamical symmetry conditions that guarantee an oscillatory long-time state in this setting. Our rigorous results are illustrated with specific spin models, which could be implemented in trapped-ion quantum simulators.

Abstract:

Variational quantum algorithms (VQAs) are increasingly being applied in simulations of strongly bound (covalently bonded) systems using full molecular orbital basis representations. The application of quantum computers to the weakly bound intermolecular and noncovalently bonded regime, however, has remained largely unexplored. In this work, we develop a coarse-grained representation of the electronic response that is ideally suited for determining the ground state of weakly interacting molecules using a VQA. We require qubit numbers that grow linearly with the number of molecules and derive scaling behavior for the number of circuits and measurements required, which compare favorably to traditional variational quantum eigensolver methods. We demonstrate our method on IBM superconducting quantum processors and show its capability to resolve the dispersion energy as a function of separation for a pair of nonpolar molecules—thereby establishing a means by which quantum computers can model Van der Waals interactions directly from zero-point quantum fluctuations. Within this coarse-grained approximation, we conclude that current-generation quantum hardware is capable of probing energies in this weakly bound but nevertheless chemically ubiquitous and biologically important regime. Finally, we perform experiments on simulated and real quantum computers for systems of three, four, and five oscillators as well as oscillators with anharmonic onsite binding potentials; the consequences of the latter are unexamined in large systems using classical computational methods but can be incorporated here with low computational overhead.