Cadmium Bis(phenyldithiocarbamate) as a Nanocrystal Shell-Growth Precursor.
Inorganic chemistry 56:21 (2017) 12920-12929
Abstract:
Cadmium bis(phenyldithiocarbamate) [Cd(PTC)2] is prepared and structurally characterized. The compound crystallizes in the monoclinic space group P21/n. A one-dimensional polymeric structure is adopted in the solid state, having bridging PTC ligands and 6-coordinate pseudo-octahedral Cd atoms. The compound is soluble in DMSO, THF, and DMF and insoluble in EtOH, MeOH, CHCl3, CH2Cl2, and toluene. {CdSe[n-octylamine]0.53} quantum belts and Cd(PTC)2 react to deposit epitaxial CdS shells on the nanocrystals. With an excess of Cd(PTC)2, the resulting thick shells contain spiny CdS nodules grown in the Stranski-Krastanov mode. Stoichiometric control affords smooth, monolayer CdS shells. A base-catalyzed reaction pathway is elucidated for the conversion of Cd(PTC)2 to CdS, which includes phenylisothiocyanate and aniline as intermediates, and 1,3-diphenylthiourea as a final product.Highly Efficient Perovskite Solar Cells Using Non‐Toxic Industry Compatible Solvent System
Solar RRL Wiley 1:11 (2017)
Improving energy and visual performance in offices using building integrated perovskite-based solar cells: A case study in Southern Italy
Applied Energy Elsevier 205 (2017) 834-846
Room temperature atomic layer deposited Al2O3 on CH3NH3PbI3 characterized by synchrotron-based X-ray photoelectron spectroscopy
Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms Elsevier 411 (2017) 49-52
Crystallization kinetics and morphology control of formamidinium-cesium mixed-cation lead mixed-halide perovskite via tunability of the colloidal precursor solution
Fundacio Scito (2017)