Snaith group

Abstract:

Molecular piezoelectrics are a potentially disruptive technology, enabling a new generation of self-powered electronics that are flexible, high performing, and inherently low in toxicity. Although significant efforts have been made toward understanding their structural design by targeted manipulation of phase transition behavior, the resulting achievable piezoresponse has remained limited. In this work, we use a low-symmetry, zero-dimensional (0D) inorganic framework alongside a carefully selected 'quasi-spherical' organic cation to manipulate organic-inorganic interactions and thus form the hybrid, piezoelectric material [(CH₃)₃NCH₂I]₃Bi₂I₉. Using variable-temperature single crystal X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy, we demonstrate that this material simultaneously exhibits an order-disorder and displacive symmetry-breaking phase transition. This phase transition is mediated by halogen bonding between the organic and inorganic frameworks and results in a large piezoelectric response, d₃₃ = 161.5 pm/V. This value represents a 4-fold improvement on previously reported halobismuthate piezoelectrics and is comparable to those of commercial inorganic piezoelectrics, thus offering a new pathway toward low-cost, low-toxicity mechanical energy harvesting and actuating devices.

Abstract:

<jats:p>This study pioneers a solvent-additive cascade strategy to achieve crystallographically homogenous perovskite films, breaking the efficiency–stability trade-off by harnessing facet-dependent properties for record performance.</jats:p>

Abstract:

Semi-transparent perovskite solar cells (ST-PSCs) have shown great potential in building-integrated photovoltaics. However, the performance of ST-PSCs is still far from achieving their true potential. Herein, a functional additive, [4-(trifluoromethyl)phenyl] sulfonyl chloride (TFBSC), is incorporated into the perovskite precursor solution to regulate the crystallization process and reduce defects in the perovskite films. The addition of TFBSC improves the perovskite film morphology and increases the charge carrier lifetime and photoluminescence quantum efficiency, compared with the control perovskite films. As a result, the champion device modified with TFBSC shows a power conversion efficiency (PCE) of 14.75% with a light utilization efficiency (LUE) of 3.92%, whereas the control device shows PCE and LUE values of 10.71% and 2.96%, respectively. Moreover, the unencapsulated TFBSC-modified device retains ∼90% of its initial PCE after 1500 h of storage under ambient conditions (relative humidity of ∼30%–40%). These findings could provide new avenues to develop high performance ST-PSCs for smart building applications.

Abstract:

Monolithic perovskite–organic tandem solar cells (POTSCs) have attracted considerable attention in recent years due to their compatible fabrication routes and advances in single-cell efficiencies. To further boost the performance of POTSCs, reducing the voltage losses that mainly arise from wide bandgap (WBG, >1.7 eV) perovskite subcells and interconnecting layers (ICLs) is critical. Here, a new ICL with a configuration of C60/YbO x /Au/MoO x is demonstrated for constructing the monolithic POTSC. The YbO x -based ICL benefits from an ohmic contact and high transparency, resulting in improved POSTC performance. The champion device presents a PCE of 23.2% owing to a high V OC of 2.11 V (approximately equal to the sum of individual V OC’s of the subcells) without compromising the short-circuit current density and fill factors. This work opens an avenue for developing efficient ICLs in POTSCs.