Solar system

Abstract:

Previous analysis of Neptune’s atmosphere using near-infrared Gemini/NIFS observations found the strongest spectral signature of hydrogen sulphide (HS) to be at the planet’s south pole. Conversely, analysis of microwave observations with the Atacama Large Millimeter/submillimeter Array in 2019 suggested a distribution of HS that peaks in the mid-latitudes and is strongly depleted towards the pole. We analyse near-infrared observations from VLT-SINFONI in 2018 and fit a parametrized cloud model to the data using nested sampling. By prescribing a latitudinally varying methane (CH) profile previously derived from visible light observations, we find general agreement with the microwave analysis, with an enhancement of HS by a factor of 4 at the southern mid-latitudes compared to polar latitudes. The stronger spectral signature at the pole is explained with a deeper cloud top, resulting in a higher cloud-top HS column abundance in this region. Our results are indicative of deep upwelling at the mid-latitudes, with downwelling at the pole and possibly near the equator.

Abstract:

Carbonaceous chondrite meteorites, which include the sulfide-rich “Yamato-type” chondrites (CYs), have undergone a complex history of aqueous and thermal alteration and offer crucial insights into early outer solar system conditions. In this study, we evaluate thermal infrared (TIR) reflectance spectra of three CY chondrites. We observe a broad spectral plateau near 10 μm, a spectral signature that has been observed in remote observations of some primitive, low-albedo asteroids, including Jupiter Trojans. We compare our data to CY emissivity spectra, spectra of Fe-sulfide and olivine mixtures, and remote Jupiter Trojan observations and establish the plateau and low albedo are a result of a high content of fine-particulate Fe-sulfide of these meteorites. We therefore suggest that D- and P-type asteroids, like Jupiter’s Trojan asteroids, could have a high abundance of Fe sulfide on their surfaces as a potential result of aqueous alteration followed by dehydration, shedding light on the processes shaping the outer solar system.

Abstract:

The extreme conditions in Venus’s lower atmosphere make robust calibration of in situ observations challenging. Consequently, measurements from past entry probes provided mixed evidence regarding the existence of a near-surface particulate layer (NSPL). Although the Venera 11 (1978) and Venera 13 and 14 (1982) landers performed in situ spectrophotometric observations during descent, the original datasets were later lost. However, a subset has been reconstructed by digitising graphical outputs produced during the missions’ initial data-processing phase [1]. Following careful analysis to identify and mitigate errors and other artefacts, the reconstructed dataset retains the reliable downward-looking spectra acquired by the three landers from ~62 km altitude to the surface.Previous retrievals from the reconstructed Venera 13 indicated an NSPL centred at ~3.5–5 km, with particulate optical properties consistent with a basaltic composition [2]. Following the methodology of [2], we use NEMESIS, a radiative transfer and retrieval code [3], to perform near-surface retrievals from the reconstructed Venera 11 and Venera 14 datasets. The results from Venera 11, 13, and 14 retrievals are compared with reported detections and non-detections from other instruments on earlier in situ missions, to explore potential formation pathways for the NSPL in light of the combined observational record.References:[1] Ignatiev, N. I., Moroz, V. I., Moshkin, B. E., Ekonomov, A. P., Gnedykh, V. I., Grigor’ev, A. V., and Khatuntsev, I. V. Cosmic Research 35(1), 1–14 (1997).[2] Kulkarni, S. V., Irwin, P. G. J., Wilson, C. F., & Ignatiev, N. I. Journal of Geophysical Research: Planets, 130, e2024JE008728, (2025).[3] Irwin, P. G., Teanby, N. A., de Kok, R., Fletcher, L. N., Howett, C. J., Tsang, C. C., Wilson, C. F., Calcutt, S. B., Nixon, C. A., and Parrish, P. D. Journal of Quantitative Spectroscopy and Radiative Transfer 109(6), 1136–1150 (2008). 

Abstract:

The ExoMars Trace Gas Orbiter (TGO) has characterised trace gases in the Martian atmosphere over several Mars years, improving the accuracy of species concentration measurements and observing temporal, vertical and spatial variations. Hydrogen chloride—detected for the first time with TGO [1,2]—has been investigated recently using the mid-infrared channel on the Atmospheric Chemistry Suite (ACS MIR). HCl observations show a strong seasonal variation, with almost all of the detections occurring during the latter half of the year (solar longitudes 180-360°) in the dusty season, when water vapour is present in the Martian atmosphere and ozone concentrations are low. Chlorine-bearing species such as HCl are important to understand in Mars’ atmosphere because on Earth they are involved in numerous processes throughout the planetary system, including volcanism, and they play a key role in atmospheric chemistry, e.g., by influencing concentrations of oxidative species such as oxygen (O2) and ozone (O3).Here, we use the Mars Planetary Climate Model—a 3-D global climate model that includes a photochemical network—to explore the atmospheric HCl observations. We build on existing chlorine photochemical networks [3,4] to investigate potential source and sink mechanisms, focusing in particular on heterogeneous chemistry involving ice aerosols, and exploring the possibility of its role in direct release of HCl to the atmosphere. We also explore how chlorine species are affected indirectly by changes in the abundances of oxidative species (e.g., OH and HO2,and by extension, O and O3),driven by heterogeneous chemistry. Understanding the role of oxidative chemistry on HCl and other trace gases is key to achieving a more complete picture of processes occurring in the present-day Mars atmosphere, as well as processes that have shaped its evolution and habitability.[1] Korablev O. I. et al. (2021). Sci. Adv., 7, eabe4386. [2] Olsen K. S. et al. (2021). Astron. Astrophys., 647, A161. [3] Rajendran, K. et al. (2025). JGR: Planets 130(3), p.e2024JE008537. [4] Streeter, P. M. et al. (2025). GRL 52(6), p.e2024GL111059.