Solar system

Research group

Research theme

Sub department

About

Related research groups

Using SOFIA’s EXES to improve the upper limits for C6H2 and C4N2 in Titan’s atmosphere

(2025)

Authors:

Zachary McQueen, Curtis DeWitt, Antoine Jolly, Juan Alday, Nicholas Teanby, Véronique Vuitton, Panayotis Lavvas, Joseph Penn, Patrick Irwin, Conor Nixon

Abstract:

IntroductionSaturn’s largest moon, Titan, has a dense atmosphere comprised mostly of nitrogen and methane. The photolysis and ionization of these major componentsleads to complex chemical reactions, which create substantial diversity among Titan’s minor atmospheric constituents. Remote sensing and molecular  pectroscopy historically have been a critical tool for detecting trace gases in Titan’s atmosphere and help corroborate predictions of Titan’s atmospheric composition from photochemical models. Following the Voyager and Cassini missions, which provided a wealth of spectroscopic studies of Titan’s  atmosphere, ground-based measurements have been useful for detecting elusive trace gases. The Echelon-Cross-Echelle Spectrometer (EXES) is a high-resolution (R ∼ 90, 000) mid-infrared spectrometer that was previously operated aboard NASA’s Stratospheric Observatory For Infrared Astronomy (SOFIA)(1 ). EXES benefited from the high altitude flights during the SOFIA mission to make observations above the bulk of the atmosphere to avoid strong telluric absorption lines that inhibit ground based mid-IR spectrometers such as its sister instrument TEXES.Here we present EXES observations of Titan which were made in an attempt to detect two trace gases, triacetylene (C6H2) and dicyanoacetylene (C4N2). C6H2 is an important polyyne and is predicted to form readily from the addition of the ethynyl (C2H) radical with diacetylene (C4H2). It remains yet tobe detected, though, and the previous upper limit study was limited by the lower spectral resolution of Voyager’s IRIS (R ∼ 145)(2 ). Delpech et al. 1994 derived an upper-limit of 6 × 10−11 which would be detectable by EXES.Gas-phase C4N2 formation is primarily completed through C3N addition to HCN or, alternatively, CN addition to HC3N(3 ). The ice-phase C4N2, which is formed through solid-state photochemical reactions on the surface of HC3N ice grains, has been detected in spectra measured by Voyager’s IRIS and CIRSduring the Cassini mission (4, 5 ), yet C4N2 in the gas-phase remains elusive to spectroscopic detections. Again, previous studies of the gas-phase upper limits (3σ = 1.53 × 10−9) were performed using spectra collected by CIRS (R ∼ 1240) which has a resolving power significantly lower than EXES(6 ). The high-resolution of EXES will help improve on the upper limits of both of these species and allow for an updated comparison to photochemical model predictions of their vertical profiles in Titan’s atmosphere.Observations and ModelingMid-infrared observations of Titan were made in June of 2021, using EXES. These observations aim to detect the ν11 out-of-plane bending mode of C6H2 at 621 cm−1 and the perpendicular ν9 stretch of the gasphase C4N2 at 472 cm−1. Figure 1 shows a small portion of the EXES spectrum measured at the 621 cm−1 spectral setting. In this region there are strong emission features from diacetylene (C4H2) and propyne (C3H4) which must be fit before analyzing the C6H2 upper limits. Highlighted in the blue box is the region where the ν11 vibrational mode for C6H2 should be present.To model the collected spectra, we use the arch-NEMESIS radiative transfer package which is a new Python implementation of the NEMESIS radiative transfer code (7, 8 ). The radiative transfer modeling of the measured spectra occurs in two steps. The initial step is to retrieve the atmospheric profiles of the aerosols and known gases using the archNEMESIS optimal estimation algorithm. For the 621 cm−1 spectral setting, the vertical profiles of C4H2, C3H4, and aerosol continuum are retrieved, however, at the 472 cm−1 region, there are no emission features to fit and just the continuum level is retrieved by adjusting the aerosol profile. For both spectral regions, we use a temperature profile and initial gas profiles defined in Vuitton et al. 2019 photochemical model (3 ). The quality of each retrieval is determined by a goodnessof-fit metric (χ2) which compares the residual of the modeled spectrum to the noise of the measurement. Following the retrieval, we derive the upper limits by building forward models of the spectral regions where the abundance of each target species is iteratively increased and a subsequent χ2 is determined. We then take the difference, Δχ2, between the retrieved and updated forward model χ2 to find where the abundance causes significant deviation from the retrieved spectrum. Step-profiles, which have a cutoff altitude and constant abundance above this cutoff, were used to determine the upper-limits for each species. This method has been applied for many different upper limits studies of gases predicted in Titan’s atmosphere (9, 10 ).ResultsBased on these observations, C6H2 and gas-phase C4N2 remain undetected and therefore, we derive the upper limits to their atmospheric abundance. We improve upon the upper limits of C6H2 and C4N2 by an order of magnitude for both species. Figure 2 shows Δχ2 increase sharply with increased abundance for both C6H2 and C4N2. For C6H2 the 3σ upper limit (Δχ2 = 9) is on the order of 10−11 and for C4N2, 10−10. These new upper limits improve on the previously derived upper limits by an order of magnitude for each target species. More work is still being done to precisely determine the upper limits and compare these values to the current photochemical model predictions of their abundance. The values of the 1σ, 2σ, and 3σ upper limits for each species will be reported in the presentation. The upper limits derived improved upon the previous upper limits by an order of magnitude and we are currently working on comparing these upper limits to photochemical models of Titan’s atmospheric composition to build a better understanding of the chemical pathways in Titan’s atmosphere which will also be discussed in the presentation. AcknowledgmentsThe material is based upon work supported by NASA under award number 80GSFC24M0006.References1. Richter et al., 20182. Delpech et al., 19943. Vuitton et al., 20194. Samuelson et al, 19975. Anderson et al, 20166. Jolly et al., 20157. Alday et al, 20258. Irwin et al., 20089. Nixon et al., 201010. Teanby et al., 2013
More details from the publisher

VIVA (Venus' Interior, Volcanism and Atmosphere): a Venus mission to reveal unknown interior structure, thermosphere dynamics and meteoroid flux from atmospheric response to seismic waves, volcanic events and external forcings

(2025)

Authors:

Raphael Garcia, Matthias Grott, Neil Bowles, Jim Cutts, Elizabeth Klioner, Marouchka Froment, Gabriella Gilli, Lauriane Soret, Apostolos Christou

Abstract:

Despite being often described as Earth’s sister planet due to a similar distance to the Sun and comparable size, Venus’s internal structure and geodynamic regime, together with its upper atmosphere dynamics and asteroid entry rates, are poorly constrained. Whereas Venus is a prime candidate for being a tectonically active planet and presents a very dynamic atmosphere, future missions will not constrain high frequency phenomena such as seismic waves, meteoroid impacts, and high frequency gravity waves. These short duration events can be used to infer Venus' seismicity, internal structure, upper atmosphere dynamics and the small Solar System bodies population [1].We present a mission concept that targets high rate observations of upper atmosphere airglow emissions on both the day and night side of Venus, as well as thermal imaging in the visible. These observations will allow us to image the propagation of acoustic waves generated by seismic waves, enabling us to investigate quake locations and magnitudes, as well as to determine the structure of the crust and upper mantle. Volcanic events will also be studied through the associated increase in surface and atmosphere temperature. In addition, variations in airglow emissions will constrain the transfer of mechanical energy from the lower atmosphere to the thermosphere, as well as atmosphere dynamics (winds) and composition, and its response to solar forcing. Finally, the observation of fireballs produced by asteroid entries will constrain the asteroid population that crosses Venus’s orbit.The instruments required to perform these high rate observations are presented. They are based on a strong heritage relying on previous implementations in planetary missions.The mission concept and spacecraft demand new capabilities in terms of on-board attitude determination and data processing capabilities. In particular, a dedicated on-board data processing unit capable of autonomously detecting different event types with advanced algorithms, including machine learning methods, has been identified as a key component of the mission. This unit will also be used to average out phenomena over different temporal and spatial scales. To maximise science return, the mission will adopt an operational concept involving the capability to download high rate event data from a first quicklook information, similar to the one implemented on InSight NASA mission.The feasibility of the mission, already partly demonstrated by VAMOS JPL/NASA mission concept study [2,3], is validated through a dedicated mission analysis study.References[1] Christou A.A., Gritsevich M. 2024. Feasibility of meteor surveying from a Venus orbiter, Icarus, 417, 15 July 2024, 116116, DOI 10.1016/j.icarus.2024.116116[2] Sutin, B.M. et al. In Space Telescopes and Instrumentation 2018: Optical, Infrared, and Millimeter Wave, volume 10698. SPIE, 2018. doi:10.1117/12.2309439.[3] Didion, A. et al. In 2018 IEEE aerospace conference. IEEE, 2018.
More details from the publisher

What are subNeptunes made of?

(2025)

Abstract:

This talk will cover the state of the art in whole-planet subNeptune modelling, and needs for the future.  Inferences about the composition of the deep envelope can be made on the basis of the way chemical transformations in the deep envelope may be evidenced in the observable atmosphere, such as has been attempted, for example, regarding the presence or absence of NH3 in the observable atmospheres of subNeptunes.  Such inferences require an understanding not only of deep envelope chemistry, but also of vertical mixing processes. The mixing process engages a number of poorly understood phenomena, such as mixing rates through stably stratified (nonconvective) internal radiative layers.  The occurrence of such radiative layers can be induced by compositional suppression of convection (e.g. due to high molecular weight H2O in an H2-rich atmosphere). We will review our modelling studies regarding this phenomenon.  Typically, the envelope-silicate interface is hot enough that the interface takes the form of a magma ocean, so compositional interchange with the magma ocean becomes crucial. This exchange includes rock vapours as well as lower molecular weight volatiles.  Our work on magma ocean exchanges will be reviewed. We highlight the importance of mineral physics experiments and molecular dynamics to provide crucially needed (and largely absent) thermodynamic parameters, particularly at high pressure.  At sufficiently high temperatures, silicate itself can become supercritical so that the distinction between silicate melt and silicate vapour disappears and the silicate substance becomes completely miscible with the lower molecular weight envelope.  Modeling and experiment regarding this novel and largely unexplored regime is particularly needed.
More details from the publisher

What goes on inside the Mars north polar vortex?

(2025)

Authors:

Kevin Olsen, Bethan Gregory, Franck Montmessin, Lucio Baggio, Franck Lefèvre, Oleg Korablev, Alexander Trokhimovsky, Anna Fedorova, Denis Belyaev, Juan Alday, Armin Kleinböhl

Abstract:

Mars has an axial tilt of 25.2°, comparable to that on Earth of 23.4°. This gives rise to very similar seasons, and even leads to our definition of Martian time, aligning the solar longitudes (Ls) such that Ls 0° and 180° occur at the equinoxes. In the northern hemisphere, between the equinoxes, the north polar region experiences polar days without darkness in spring and summer, and days of total darkness in the fall and winter. The dark polar winters give rise to a polar vortex that encircles the polar region and encircles an atmosphere of very cold and dry air bound within (1-3).The Atmospheric Chemistry Suite (ACS) mid-infrared channel (MIR) on the ExoMars Trace Gas Orbiter (TGO; 4) operates in solar occultation mode in which the Sun is used as a light source when the atmosphere lies between the Sun and TGO. The tangent point locations of ACS MIR observation necessarily lie on the solar terminator on Mars. At the poles when either polar night or polar day are experienced, there is no terminator, and solar occultations are restricted to outside such a region. The latitudinal distribution of ACS MIR solar occultations during the north polar fall and winter over four Mars years (MYs) is shown in Fig. 1. The furthest northern extent of observations occurs at the equinoxes, and falling northern boundary is seen between, as the north pole points further away from the Sun (similarly in the south, where it is polar day).While direct observations of the north polar vortex are forbidden with solar occultations, the polar vortex is not perfectly circular (1-3) and occasionally, descends into the illuminated region where we are making observations. The characteristic signs that we are sampling the polar vortex are a sudden drop in temperature below 20 km, the almost complete reduction in water vapour volume mixing ratio (VMR) and an enhancement in ozone VMR, the latter of which is extremely rare (5).To measure the extent of the polar vortex, we use temperature measurements from the Mars Climate Sounder (MCS; 6, 7) on Mars Reconnaissance Orbiter (MRO). We define the polar vortex as the average temperature over 10-20 km being within a boundary of 170 K (30). We introduce a novel technique to determine this boundary during a 1° Ls period using an alpha hull. We show that we can accurately measure the area of the polar vortex and achieve similar results to (3). The impact of the southern summer and dust activity is clearly visible in the time series of the northern polar vortex extent, leading to maxima occurring at the equinoxes, and shrinking toward perihelion. The impact of global dust storms and the late season dust storms are also pronounced.We will show the vertical structure of water vapour and ozone VMRs inside and outside the north polar vortex, the results of a search for polar vortex temperatures from the near-infrared channel (NIR) of ACS (along the dark blue dots in Fig. 1), and show whether these results agree with the polar vortex extent measurements using MCS.       Figure 1: The latitudes of ACS MIR solar occultation as a function of time (solar longitude Ls) during northern fall (Ls 180-270°) and winter (Ls 270-360°). Data from Mars years (MYs) 34-37 are indicated with colours. The region of interest in searching for polar vortex excursions is highlighted in blue.References:(1) Streeter, P. M. et al. J. Geophys. Res. 126, e2020JE006774 (2021).(2) Streeter, P. M., Lewis, S. R., Patel, M. R., Holmes, J. A., & Rajendran, K. Icarus 409, 115864 (2024).(3) Alsaeed, N.R., Hayne, P. O. & Concepcion, V. J. Geophys. Res. 129, e2024JE008397 (2024).(4) Korablev, O. et al. Space Sci. Rev. 214, 7 (2018).(5) Olsen, K. S., et al. J. Geophys. Res. 127, e2022JE007213 (2022).(6) Kleinböhl, A., et al. J. Geophys. Res., 114, E10006 (2009).(7) Kleinböhl, A., Friedson, A. J., & Schofield, J. T. J. Quant. Spectrosc. Radiat. Transfer. 187, 511-522 (2017).
More details from the publisher

 MIRMIS – The Modular Infrared Molecules and Ices Sensor for ESA’s Comet Interceptor.

(2025)

Authors:

Neil Bowles, Antti Näsilä, Tomas Kohout, Geronimo Villanueva, Chris Howe, Patrick Irwin, Antti Penttila, Alexander Kokka, Richard Cole, Sara Faggi, Aurelie Guilbert-Lepoutre, Silvia Protopapa, Aria Vitkova

Abstract:

Introduction: This presentation will describe the Modular Infrared Molecules and Ices Sensor currently in final assembly and test at the University of Oxford, UK and VTT Finland for ESA’s upcoming Comet interceptor mission.The Comet Interceptor mission: The Comet Interceptor mission [1] was selected by ESA as the first of its new “F” class of missions in June 2019 and adopted in June 2022.  Comet Interceptor (CI) aims to be the first mission to visit a long period comet, preferably, a Dynamically New Comet (DNC), a subset of long-period comets that originate in the Oort cloud and may preserve some of the most primitive material from early in our Solar System’s history. CI is scheduled to launch to the Earth-Sun L2 point with ESA’s ARIEL [2] mission in ~2029 where it will wait for a suitable DNC target.The CI mission is comprised of three spacecraft.  Spacecraft A will pass by the target nucleus at ~1000 km to mitigate against hazards caused by dust due to the wide range of possible encounter velocities (e.g. 10 – 70 km/s).  As well as acting as a science platform, Spacecraft A will deploy and provide a communications hub for two smaller spacecrafts, B1 (supplied by the Japanese space agency JAXA) and B2 that will perform closer approaches to the nucleus.  Spacecrafts B1 and B2 will make higher risk/higher return measurements but with the increased probability that they will not survive the whole encounter.The MIRMIS Instrument: The Modular InfraRed Molecules and Ices sensor (MIRMIS, Figure 1) instrument is part of the CI Spacecraft A scientific payload.  The MIRMIS consortium includes hardware contributions from Finland (VTT Finland) and the UK (University of Oxford) with members of the instrument team from the Universities of Helsinki, Lyon, NASA’s Goddard Space Flight Center, and Southwest Research Institute.MIRMIS will map the spatial distribution of temperatures, ices, minerals and gases in the nucleus and coma of the comet using covering a spectral range of 0.9 to 25 microns.  An imaging Fabry-Perot interferometer will provide maps of composition at a scale of ~180 m at closest approach from 0.9 to 1.7 microns.  A Fabry-Perot point spectrometer will make observations of the coma and nucleus at wavelengths from 2.5 to 5 microns and finally a thermal imager will map the temperature and composition of the nucleus at a spatial resolution of 260 m using a series of multi-spectral filters from 6 to 25 microns.  Figure 1: (Top) The MIRMIS instrument for ESA’s Comet Interceptor mission. (Bottom) The MIRMIS Structural Thermal model under test at University of Oxford.The MIRMIS instrument is compact (548.5 x 282.0 x 126.8 mm) and low mass (
More details from the publisher