Solar system

Abstract:

Heterogeneous electrochemistry induced by Martian dust activity is an important type of atmosphere-surface interaction that affects geochemical processes at the Martian surface and in the Martian atmosphere. We have experimentally demonstrated that heterogeneous electrochemistry stimulated by mid-strength dust events can decompose common chloride salts, which is accompanied by the release of chlorine atoms into the atmosphere and the generation of (per)chlorates (chlorates and perchlorates) and carbonates. In this study, we present quantitative analyses on the above products from 26 heterogeneous electrochemical experiments on chloride salts. Based on these quantifications, our calculation indicates that such atmosphere-surface interaction during a portion of Amazonian period could accumulate the observed abundance of (per)chlorates, carbonates, and HCl by landed and orbital missions, and thus can be considered as a major driving force of the global chlorine-cycle on Mars. This study emphasizes the importance of measuring the electrical properties of dust activity on Mars.

Abstract:

<jats:title>Abstract</jats:title> <jats:p>The implications of the water vapor runaway greenhouse phenomenon for water-rich sub-Neptunes are developed. In particular, the nature of the postrunaway equilibration process for planets that have an extremely high water inventory is addressed. Crossing the threshold from subrunaway to superrunaway conditions leads to a transition from equilibrated states with cold, deep liquid oceans and deep interior ice-X phases to states with hot supercritical fluid interiors. There is a corresponding marked inflation of radius for a given mass, similar to the runaway greenhouse radius inflation effect noted earlier for terrestrial planets, but in the present case the inflation involves the entire interior of the planet. The calculation employs the AQUA equation-of-state database to simplify the internal structure calculation. Some speculations concerning the effect of H<jats:sub>2</jats:sub> admixture, silicate cores, and hot- versus cold-start evolution trajectories are offered. Observational implications are discussed though the search for the mass–radius signature of the phenomena considered is limited by degeneracies and by lack of data.</jats:p>

Abstract:

<jats:title>Abstract</jats:title> <jats:p>The gas giant HD 80606 b has a highly eccentric orbit (e ∼ 0.93). The variation due to the rapid shift of stellar irradiation provides a unique opportunity to probe the physical and chemical timescales and to study the interplay between climate dynamics and atmospheric chemistry. In this work, we present integrated models to study the atmospheric responses and the underlying physical and chemical mechanisms of HD 80606 b. We first run three-dimensional general circulation models (GCMs) to establish the atmospheric thermal and dynamical structures for different atmospheric metallicities and internal heat. Based on the GCM output, we then adopted a 1D time-dependent photochemical model to investigate the compositional variation along the eccentric orbit. The transition of the circulation patterns of HD 80606 b matched the dynamics regimes in previous works. Our photochemical models show that efficient vertical mixing leads to deep quench levels of the major carbon and nitrogen species and the quenching behavior does not change throughout the eccentric orbit. Instead, photolysis is the main driver of the time-dependent chemistry. While CH4 dominates over CO through most of the orbits, a transient state of [CO]/[CH4] &amp;gt; 1 after periastron is confirmed for all metallicity and internal heat cases. The upcoming JWST Cycle 1 GO program will be able to track this real-time CH4–CO conversion and infer the chemical timescale. Furthermore, sulfur species initiated by sudden heating and photochemical forcing exhibit both short-term and long-term cycles, opening an interesting avenue for detecting sulfur on exoplanets.</jats:p>

Abstract:

The study of isotopic ratios in planetary atmospheres gives an insight into the formation history and evolution of these objects. The more we can constrain these ratios, the better we can understand the history and future of our solar system. To help in this endeavour, we used Infrared Space Observatory Short Wavelength Spectrometer (ISO/SWS) Jupiter observations in the 793–1500 cm (Formula presented.) region together with the Nonlinear Optimal Estimator for MultivariatE Spectral analySIS (NEMESIS) radiative transfer suite to retrieve the temperature–pressure profile and the chemical abundances for various chemical species. We also used the 1500–2499 cm (Formula presented.) region to determine the cloud and aerosol structure of the upper troposphere. We obtained a best-fit simulated spectrum with (Formula presented.) for the 793–1500 cm (Formula presented.) region and (Formula presented.) for the 1500–2499 cm (Formula presented.) region. From the retrieved methane abundances, we obtained, within a 1 (Formula presented.) uncertainty, a (Formula presented.) C/ (Formula presented.) C ratio of 84 ± 27 and a D/H ratio of (3.5 ± 0.6) × 10 (Formula presented.), and these ratios are consistent with other published results from the literature.