Water vapor in Titan's stratosphere from Cassini CIRS far-infrared spectra
Icarus 220:2 (2012) 855-862
Abstract:
Here we report the measurement of water vapor in Titan's stratosphere using the Cassini Composite Infrared Spectrometer (CIRS, Flasar, F.M. et al. [2004]. Space Sci. Rev. 115, 169-297). CIRS senses water emissions in the far infrared spectral region near 50μm, which we have modeled using two independent radiative transfer codes (NEMESIS (Irwin, P.G.J. et al. [2008]. J. Quant. Spectrosc. Radiat. Trans. 109, 1136-1150) and ART (Coustenis, A. et al. [2007]. Icarus 189, 35-62; Coustenis, A. et al. [2010]. Icarus 207, 461-476). From the analysis of nadir spectra we have derived a mixing ratio of 0.14±0.05ppb at an altitude of 97km, which corresponds to an integrated (from 0 to 600km) surface normalized column abundance of 3.7±1.3×10 14molecules/cm 2. In the latitude range 80°S to 30°N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of 0.13±0.04ppb at an altitude of 115km and 0.45±0.15ppb at an altitude of 230km, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models (e.g. Lara, L.M., Lellouch, F., Lopez-Moreno, J.J., Rodrigo, R. [1996]. J. Geophys. Res. 101(23), 261; Wilson, E.H., Atreya, S.K. [2004]. J. Geophys. Res. 109, E6; Hörst, S.M., Vuitton, V., Yelle, R.V. [2008]. J. Geophys. Res., 113, E10). We have also fitted our data using scaling factors of ~0.1-0.6 to these photochemical model profiles, indicating that the models over-predict the water abundance in Titan's lower stratosphere. © 2012 Elsevier Inc..Seasonal disappearance of far-infrared haze in Titan's stratosphere
Astrophysical Journal Letters 754:1 (2012)
Abstract:
A far-infrared emission band attributed to volatile or refractory haze in Titan's stratosphere has been decreasing in intensity since Cassini's arrival in 2004. The 220cm-1 feature, first seen by the Voyager Infrared Interferometer Spectrometer, has only been found in Titan's winter polar region. The emission peaks at about 140km altitude near the winter stratospheric temperature minimum. Observations recorded over the period 2004-2012 by the Composite Infrared Spectrometer on Cassini show a decrease in the intensity of this feature by about a factor of four. Possible seasonal causes of this decline are an increase in photolytic destruction of source chemicals at high altitude, a lessening of condensation as solar heating increased, or a weakening of downwelling of vapors. As of early 2012, the 220cm-1 haze has not yet been detected in the south. The haze composition is unknown, but its decrease is similar to that of HC3N gas in Titan's polar stratosphere, pointing to a nitrile origin. © 2012. The American Astronomical Society. All rights reserved.Investigation of new band parameters with temperature dependence for self-broadened methane gas in the range 9000 to 14,000cm -1 (0.71 to 1.1μm)
Journal of Quantitative Spectroscopy and Radiative Transfer 113:10 (2012) 763-782
Abstract:
This paper describes new measurements and modelling of the absorption of methane gas, one of the most important gases observed in the atmospheres of the outer planets and Titan, between 9000 and 14,000cm -1 (0.7 to 1.1μm) and compares them with current best available spectral models.A series of methane spectra were measured at the UK's Natural Environment Research Council (NERC) Molecular Spectroscopy Facility (based at the Rutherford Appleton Laboratory, Oxfordshire, UK) using a Brüker 125HR Fourier transform spectrometer. To approximate the conditions found in outer planet atmospheres, the spectra were measured over a wide range of pressures (5bar to 38mbar) and temperatures (290-100K) with path lengths of 19.3, 17.6, 16.0 and 14.4m. The spectra were recorded at a moderate resolution of 0.12cm -1 and then averaged to 10cm -1 resolution prior to fitting a series of increasingly complex band-models including temperature dependence. Using the most complex model, a Goody line distribution with a Voigt line shape and two lower energy state levels, the typical rms residual error in the fit is between 0.01 and 0.02 in the wings of the main absorption bands.The new spectral parameters were then compared with the measured spectra and spectra calculated using existing data and shown to be able to accurately reproduce the measured absorption. The improvement in the temperature dependence included in the model is demonstrated by comparison with existing cold methane spectral data for a typical Jovian path. © 2012 Elsevier Ltd.Investigation of new band parameters with temperature dependence for self-broadened methane gas in the range 9000 to 14,000cm−1 (0.71 to 1.1μm)
Journal of Quantitative Spectroscopy and Radiative Transfer Elsevier 113:10 (2012) 763-782
Characterizing atmospheric waves on Venus, Earth, and Mars
Eos 93:23 (2012) 220