Band Tail States in FAPbI3: Characterization and Simulation

Fundacio Scito (2017)

Authors:

Adam Wright, Rebecca Milot, Giles Eperon, Henry Snaith, Michael Johnston, Laura Herz

Large-area, highly uniform evaporated formamidinium lead triiodide thin-films for solar cells

ACS Energy Letters American Chemical Society 2 (2017) 2799-2804

Authors:

Juliane Borchert, Rebecca Milot, Jay B Patel, Christopher L Davies, Adam Wright, Laura Martinez Maestro, Henry J Snaith, Laura M Hertz, Michael Johnston

Abstract:

Perovskite thin-film solar cells are one of the most promising emerging renewable energy technologies because of their potential for low-cost, large-area fabrication combined with high energy conversion efficiencies. Recently, formamidinium lead triiodide (FAPbI3) and other formamidinium (CH(NH2)2) based perovskites have been explored as interesting alternatives to methylammonium lead triiodide (MAPbI3) because they exhibit better thermal stability. However, at present a major challenge is the scale-up of perovskite solar cells from small test-cells to full solar modules. We show that coevaporation is a scalable method for the deposition of homogeneous FAPbI3 thin films over large areas. The method allows precise control over film thickness and results in highly uniform, pinhole-free layers. Our films exhibited a high charge-carrier mobility of 26 cm2 V–1s–1, excellent optical properties, and a bimolecular recombination constant of 7 × 10–11 cm3 s–1. Solar cells fabricated using these vapor-deposited layers within a regular device architecture produced stabilized power conversion efficiencies of up to 14.2%. Thus, we demonstrate that efficient FAPbI3 solar cells can be vapor-deposited, which opens up a pathway toward large-area stable perovskite photovoltaics.

The Importance of Interface Morphology for Hysteresis-Free Perovskite Solar Cells

Fundacio Scito (2017)

Authors:

Jay Patel, Jennifer Wong-Leung, Stephan Van Reenen, Nobuya Sakai, Jacob Wang, Elizabeth Parrott, Mingzhen Liu, Henry Snaith, Laura Herz, Michael Johnston

Modulation of terahertz polarization on picosecond timescales using polymer-encapsulated semiconductor nanowires

Conference on Lasers and Electro-Optics (CLEO 2017) Optical Society of America 2017-January (2017) 1-2

Authors:

Jessica Boland, Djamshid Damry, HH Tan, C Jagadish, HJ Joyce, Michael Johnston

Abstract:

We exploit the photoconductivity of semiconductor nanowires to achieve ultrafast broad-bandwidth modulation of THz pulses. A modulation depth of -8 dB was exhibited by a polarizer consisting of 14 layers of nanowires encapsulated in polymer.

Modulation of terahertz polarization on picosecond timescales using polymer-encapsulated semiconductor nanowires

2017 Conference on Lasers and Electro-Optics, CLEO 2017 - Proceedings 2017-January (2017) 1-2

Authors:

SA Baig, JL Boland, DA Damry, H Hoe Tan, C Jagadish, HJ Joyce, MB Johnston

Abstract:

We exploit the photoconductivity of semiconductor nanowires to achieve ultrafast broad-bandwidth modulation of THz pulses. A modulation depth of -8 dB was exhibited by a polarizer consisting of 14 layers of nanowires encapsulated in polymer.