Prof. Patrick Irwin

Abstract:

New line data describing the absorption of CH 4 and CH 3D from 1.26 to 1.71μm (Campargue, A., Wang, L., Mondelain, D., Kassi, S., Bézard, B., Lellouch, E., Coustenis, A., de Bergh, C., Hirtzig, M., Drossart, P. [2012]. Icarus 219, 110-128), building upon previous papers by Campargue et al. (Campargue, A., Wang, L., Kassi, S., Masat, M., Votava, O. [2010]. J. Quant. Spectrosc. Radiat. Transfer 111, 1141-1151; Wang, L., Kassi, S., Campargue, A. [2010]. J. Quant. Spectrosc. Radiat. Transfer 111, 1130-1140; Wang, L., Kassi, S., Liu, A.W., Hu, S.M., Campargue, A. [2011]. J. Quant. Spectrosc. Radiat. Transfer 112, 937-951)) have been applied to the analysis of Gemini-N/NIFS observations of Uranus made in 2010 and compared with earlier disc-averaged observations made by KPNO/FTS in 1982. The new line data are found to improve greatly the fit to the observed spectra and present a huge advance over previous methane absorption tables by allowing us to determine the CH 3D/CH 4 ratio and also start to break the degeneracy between methane abundance and cloud top height. The best fits are obtained if the cloud particles in the main cloud deck at the 2-3bar level become less scattering with wavelength across the 1.4-1.6μm region and we have modelled this variation here by varying the extinction cross-section and single-scattering albedo of the particles.Applying the new line data to the NIFS spectra of Uranus, we determine a new estimate of the CH 3D/CH 4 ratio of 2.9-0.5+0.9×10-4, which is consistent with the estimate of de Bergh et al. (de Bergh, C., Lutz, B.L., Owen, T., Brault, J., Chauville, J. [1986]. Astrophys. J. 311, 501-510) of 3.6-2.8+3.6×10-4, made by fitting a disc-averaged KPNO/FTS spectrum measured in 1982, but much better constrained. The NIFS observations made in 2010 have been disc-averaged and compared with the 1982 KPNO/FTS spectrum and found to be in excellent agreement.Using k-tables fitted to the new line data, the central meridian observations of Uranus' H-band spectrum (1.49-1.64μm) made by Gemini-N/NIFS in 2010 have been reanalyzed. The use of the new methane absorption coefficients and the modified scattering properties of the cloud particles in the main cloud deck appears to break the degeneracy between cloud height and methane abundance immediately above it in this spectral region and we find that both vary with latitude across Uranus' disc. Overall, we find that the main cloud deck becomes higher, but thinner from equator to poles, with a local maximum in cloud top height in the circumpolar zones at 45°N and 45°S. At the same time, using the 'D' temperature pressure profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987-15001) and a deep methane abundance of 1.6% (Baines, K.H., Mickelson, M.E., Larson, L.E., Ferguson, D.W. [1995]. Icarus 144, 328-340) we find that the relative humidity of methane is high near the equator (~60%) and decreases sharply towards the poles, except near the circumpolar zone at 45°N, which has brightened steadily since 2007, and where there is a local maximum in methane relative humidity. In tests conducted with the warmer 'F1' profile of Sromovsky et al. (2011) we find a similar variation of methane abundance above the main cloud, although for this warmer temperature profile this abundance is dependent mostly on the fitted deep methane mole fraction. © 2012 Elsevier Inc.

Abstract:

Here we report the measurement of water vapor in Titan's stratosphere using the Cassini Composite Infrared Spectrometer (CIRS, Flasar, F.M. et al. [2004]. Space Sci. Rev. 115, 169-297). CIRS senses water emissions in the far infrared spectral region near 50μm, which we have modeled using two independent radiative transfer codes (NEMESIS (Irwin, P.G.J. et al. [2008]. J. Quant. Spectrosc. Radiat. Trans. 109, 1136-1150) and ART (Coustenis, A. et al. [2007]. Icarus 189, 35-62; Coustenis, A. et al. [2010]. Icarus 207, 461-476). From the analysis of nadir spectra we have derived a mixing ratio of 0.14±0.05ppb at an altitude of 97km, which corresponds to an integrated (from 0 to 600km) surface normalized column abundance of 3.7±1.3×10 14molecules/cm 2. In the latitude range 80°S to 30°N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of 0.13±0.04ppb at an altitude of 115km and 0.45±0.15ppb at an altitude of 230km, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models (e.g. Lara, L.M., Lellouch, F., Lopez-Moreno, J.J., Rodrigo, R. [1996]. J. Geophys. Res. 101(23), 261; Wilson, E.H., Atreya, S.K. [2004]. J. Geophys. Res. 109, E6; Hörst, S.M., Vuitton, V., Yelle, R.V. [2008]. J. Geophys. Res., 113, E10). We have also fitted our data using scaling factors of ~0.1-0.6 to these photochemical model profiles, indicating that the models over-predict the water abundance in Titan's lower stratosphere. © 2012 Elsevier Inc..

Abstract:

This paper describes new measurements and modelling of the absorption of methane gas, one of the most important gases observed in the atmospheres of the outer planets and Titan, between 9000 and 14,000cm -1 (0.7 to 1.1μm) and compares them with current best available spectral models.A series of methane spectra were measured at the UK's Natural Environment Research Council (NERC) Molecular Spectroscopy Facility (based at the Rutherford Appleton Laboratory, Oxfordshire, UK) using a Brüker 125HR Fourier transform spectrometer. To approximate the conditions found in outer planet atmospheres, the spectra were measured over a wide range of pressures (5bar to 38mbar) and temperatures (290-100K) with path lengths of 19.3, 17.6, 16.0 and 14.4m. The spectra were recorded at a moderate resolution of 0.12cm -1 and then averaged to 10cm -1 resolution prior to fitting a series of increasingly complex band-models including temperature dependence. Using the most complex model, a Goody line distribution with a Voigt line shape and two lower energy state levels, the typical rms residual error in the fit is between 0.01 and 0.02 in the wings of the main absorption bands.The new spectral parameters were then compared with the measured spectra and spectra calculated using existing data and shown to be able to accurately reproduce the measured absorption. The improvement in the temperature dependence included in the model is demonstrated by comparison with existing cold methane spectral data for a typical Jovian path. © 2012 Elsevier Ltd.

Abstract:

Thunderstorm activity has been observed on Saturn via radio emissions from lightning discharges and optical detections of the lightning flashes on the planets nightside. Thunderstorms provide extreme environments in which specific atmospheric chemistry can be induced - namely through energy release via lightning discharges, and fast vertical transport resulting in rapid advection of tropospheric species. It is thus theorised that certain atmospheric trace species such as C 2H 2, HCN, and CO can be generated in the troposphere by large bursts of energy in the form of lightning, and transported upward towards the upper troposphere by the extreme dynamics of thunderstorms, where they should be observable by satellite instruments. In this work, high-spectral-resolution Cassini/CIRS observations from October 2005 through April 2009 are used to study whether there is an observable increase in upper tropospheric acetylene in regions of known normal thunderstorm activity. Using both individual measurements in which there is known thunderstorm activity, as well as large coadditions of data to study latitudinal-dependencies over the full disc, no systematic enhancement in upper tropospheric (100 mbar) C 2H 2 was detected around regions in which there are known occurrences of normally sized (2000 km) thunderstorms, or in normally sized thunderstorm-prone regions such as 40°S. It is likely that the magnitude of the enhancement theorised is too generous or that enhancements are not advected into the upper troposphere as vertical mixing rates in models would suggest, since Cassini/CIRS can only detect C 2H 2 above the 200 mbar level - although the massive northern hemisphere thunderstorm of 2010/2011 seems able to decrease stratospheric concentrations of C 2H 2. From this, it can be asserted that lightning from normal thunderstorm activity cannot be the key source for upper tropospheric C 2H 2 on Saturn, since the upper-tropospheric concentrations retrieved agree with the concentrations stemming from the photolysis of CH 4 (23 ppbv) from solar radiation penetrating through the Saturnian atmosphere, with an upper limit for lightning-induced C 2H 2 volume mixing ratio of 10 -9. © 2012 Elsevier Ltd. All rights reserved.