Supramolecular Self‐Assembly as a Tool To Preserve the Electronic Purity of Perylene Diimide Chromophores**
Angewandte Chemie Wiley 135:12 (2023)
Titelbild: Supramolecular Self‐Assembly as a Tool To Preserve the Electronic Purity of Perylene Diimide Chromophores (Angew. Chem. 12/2023)
Angewandte Chemie Wiley 135:12 (2023)
Supramolecular self-assembly as a tool to preserve the electronic purity of perylene diimide chromophores
Angewandte Chemie International Edition Wiley 62:12 (2023) e202216729
Abstract:
Organic semiconductors are promising for efficient, printable optoelectronics. However, strong excited-state quenching due to uncontrolled aggregation limits their use in devices. We report on the self-assembly of a supramolecular pseudo-cube formed from six perylene diimides (PDIs). The rigid, shape-persistent cage sets the distance and orientation of the PDIs and suppresses intramolecular rotations and vibrations, leading to non-aggregated, monomer-like properties in solution and the solid state, in contrast to the fast fluorescence quenching in the free ligand. The stabilized excited state and electronic purity in the cage enables the observation of delayed fluorescence due to a bright excited multimer, acting as excited-state reservoir in a rare case of benign inter-chromophore interactions in the cage. We show that self-assembly provides a powerful tool for retaining and controlling the electronic properties of chromophores, and to bring molecular electronics devices within reach.Dataset: Resurgence of superconductivity and the role of the dxy hole band in FeSe1−xTex
University of Oxford (2023)
Abstract:
This dataset is related to the publication entitled: "Resurgence of superconductivity and the role of the dxy hole band in FeSe1−xTex" to appear in Communication Physics. The data files are either ARPES data collected to the Diamond Light Source (.nxs files), ASCII files with the extracted paramaters (.dat) or structural files used as input in DFT calculations (.struct). The PDF files of each figures are provided.Multi-band description of the upper critical field of bulk FeSe
University of Oxford (2023)