Solar system

Abstract:

Heterogeneous electrochemistry induced by Martian dust activity is an important type of atmosphere-surface interaction that affects geochemical processes at the Martian surface and in the Martian atmosphere. We have experimentally demonstrated that heterogeneous electrochemistry stimulated by mid-strength dust events can decompose common chloride salts, which is accompanied by the release of chlorine atoms into the atmosphere and the generation of (per)chlorates (chlorates and perchlorates) and carbonates. In this study, we present quantitative analyses on the above products from 26 heterogeneous electrochemical experiments on chloride salts. Based on these quantifications, our calculation indicates that such atmosphere-surface interaction during a portion of Amazonian period could accumulate the observed abundance of (per)chlorates, carbonates, and HCl by landed and orbital missions, and thus can be considered as a major driving force of the global chlorine-cycle on Mars. This study emphasizes the importance of measuring the electrical properties of dust activity on Mars.

Abstract:

<jats:title>Abstract</jats:title> <jats:p>The implications of the water vapor runaway greenhouse phenomenon for water-rich sub-Neptunes are developed. In particular, the nature of the postrunaway equilibration process for planets that have an extremely high water inventory is addressed. Crossing the threshold from subrunaway to superrunaway conditions leads to a transition from equilibrated states with cold, deep liquid oceans and deep interior ice-X phases to states with hot supercritical fluid interiors. There is a corresponding marked inflation of radius for a given mass, similar to the runaway greenhouse radius inflation effect noted earlier for terrestrial planets, but in the present case the inflation involves the entire interior of the planet. The calculation employs the AQUA equation-of-state database to simplify the internal structure calculation. Some speculations concerning the effect of H<jats:sub>2</jats:sub> admixture, silicate cores, and hot- versus cold-start evolution trajectories are offered. Observational implications are discussed though the search for the mass–radius signature of the phenomena considered is limited by degeneracies and by lack of data.</jats:p>