Solar system

Abstract:

Temperature data derived from ACS NIR observations of Mars used in the paper: Seasonal changes in the vertical structure of ozone in the Martian lower atmosphere and its relationship to water vapour. LMD GCM data interpolated to the terminator (T/P/density/H2O/O3) used in the paper: Seasonal changes in the vertical structure of ozone in the Martian lower atmosphere and its relationship to water vapour.

Abstract:

Isotopic ratios in atmospheric CO2 are shaped by various processes throughout Mars' history, and can help understand what the atmosphere of early Mars was like to sustain liquid water on its surface. In this study, we monitor the O and C isotopic composition of CO2 between 70 and 130 km for more than half a Martian year using solar occultation observations by the Atmospheric Chemistry Suite onboard the ExoMars Trace Gas Orbiter. We find the vertical trends of the isotopic ratios to be consistent with the expectations from diffusive separation above the homopause, with average values below this altitude being consistent with Earth-like fractionation (δ13C = −3 ± 37‰; δ18O = −29 ± 38‰; and δ17O = −11 ± 41‰). Using these measurements, we estimate that at least 20%–40% of primordial C on Mars has escaped to space throughout history. The total amount of C lost from the atmosphere is likely to be well in excess of this lower limit, due to carbonate formation and further sink processes. In addition, we propose a photochemical transfer of light O from H2O to CO2 to explain the larger enrichment in the 18O/16O ratio in H2O than in CO2.

Abstract:

Condensable species are crucial to shaping planetary climate. A wide range of planetary climate systems involve understanding nondilute condensable substances and their influence on climate dynamics. There has been progress on large-scale dynamical effects and on 1D convection parameterization, but resolved 3D moist convection remains unexplored in nondilute conditions, though it can have a profound impact on temperature/humidity profiles and cloud structure. In this work, we tackle this problem for pure-steam atmospheres using three-dimensional, high-resolution numerical simulations of convection in postrunaway atmospheres. We show that the atmosphere is composed of two characteristic regions, an upper condensing region dominated by gravity waves and a lower noncondensing region characterized by convective overturning cells. Velocities in the condensing region are much smaller than those in the lower, noncondensing region, and the horizontal temperature variation is small. Condensation in the thermal photosphere is largely driven by radiative cooling and tends to be statistically homogeneous. Some condensation also happens deeper, near the boundary of the condensing region, due to triggering by gravity waves and convective penetrations and exhibits random patchiness. This qualitative structure is insensitive to varying model parameters, but quantitative details may differ. Our results confirm theoretical expectations that atmospheres close to the pure-steam limit do not have organized deep convective plumes in the condensing region. The generalized convective parameterization scheme discussed in Ding & Pierrehumbert is appropriate for handling the basic structure of atmospheres near the pure-steam limit but cannot capture gravity waves and their mixing which appear in 3D convection-resolving models.