Solar system

Abstract:

Abstract:

Planets smaller than Neptune and larger than Earth make up the majority of the discovered exoplanets. Those with H2-rich atmospheres are prime targets for atmospheric characterization. The transition between the two main classes, super-Earths and sub-Neptunes, is not clearly understood as the rocky surface is likely not accessible to observations. Tracking several trace gases (specifically the loss of ammonia (NH3) and hydrogen cyanide (HCN)) has been proposed as a proxy for the presence of a shallow surface. In this work, we revisit the proposed mechanism of nitrogen conversion in detail and find its timescale on the order of a million years. NH3 exhibits dual paths converting to N2 or HCN, depending on the UV radiation of the star and the stage of the system. In addition, methanol (CH3OH) is identified as a robust and complementary proxy for a shallow surface. We follow the fiducial example of K2-18b with a 2D photochemical model on an equatorial plane. We find a fairly uniform composition distribution below 0.1 mbar controlled by the dayside, as a result of slow chemical evolution. NH3 and CH3OH are concluded to be the most unambiguous proxies to infer surfaces on sub-Neptunes in the era of the James Webb Space Telescope.

Abstract:

We demonstrate that the deep volatile storage capacity of magma oceans has significant implications for the bulk composition, interior, and climate state inferred from exoplanet mass and radius data. Experimental petrology provides the fundamental properties of the ability of water and melt to mix. So far, these data have been largely neglected for exoplanet mass–radius modeling. Here we present an advanced interior model for water-rich rocky exoplanets. The new model allows us to test the effects of rock melting and the redistribution of water between magma ocean and atmosphere on calculated planet radii. Models with and without rock melting and water partitioning lead to deviations in planet radius of up to 16% for a fixed bulk composition and planet mass. This is within the current accuracy limits for individual systems and statistically testable on a population level. Unrecognized mantle melting and volatile redistribution in retrievals may thus underestimate the inferred planetary bulk water content by up to 1 order of magnitude.