Solar system

Abstract:

The Ultraviolet Spectrograph (UVS) instrument on the Juno mission records far-ultraviolet reflected sunlight from Jupiter. These spectra are sensitive to the abundances of chemical species in the upper atmosphere and to the distribution of the stratospheric haze layer. We combine observations from the first 30 perijoves of the mission in order to study the meridional distribution of acetylene (C2H2) in Jupiter's stratosphere. We find that the abundance of C2H2 decreases toward the poles by a factor of 2–4, in agreement with previous analyses of mid-infrared spectra. This result is expected from insolation rates: near the equator, the UV solar flux is higher, allowing more C2H2 to be generated from the UV photolysis of CH4. The decrease in abundance toward the poles suggests that horizontal mixing rates are not rapid enough to homogenize the latitudinal distribution.

Abstract:

Context. Reports on the detection of methane in the Martian atmosphere have motivated numerous studies aiming to confirm or explain its presence on a planet where it might imply a biogenic or more likely a geophysical origin.
Aims. Our intent is to complement and improve on the previously reported detection attempts by the Atmospheric Chemistry Suite (ACS) on board the ExoMars Trace Gas Orbiter (TGO). This latter study reported the results of a campaign that was a few months in length, and was significantly hindered by a dusty period that impaired detection performances.
Methods. We unveil 640 solar occultation measurements gathering 1.44 Martian years worth of data produced by the ACS.
Results. No methane was detected. Probing the clear northern summer season allowed us to reach 1σ upper limits of around 10 pptv (20 pptv at 2σ), with an annual mean of the smallest upper limits of 20 pptv. Upper limits are controlled by the amount of dust in the atmosphere, which impairs detection performance around the equator and during the southern spring and summer seasons. Observations performed near Gale crater yielded 1σ upper limits of up to four times less than the background values measured by the Curiosity rover during the corresponding seasons.
Conclusions. Reconciliation of the absence of methane in the TGO spectra with the positive detections by Curiosity is even more difficult in light of this annual survey performed by ACS. Stronger constraints are placed on the physical and chemical mechanism capable of explaining why the mean of the best overall upper limits of ACS is ten times below the smallest methane abundances measured by Curiosity.

Abstract:

Hydrogen chloride gas was recently discovered in the atmosphere of Mars during southern summer seasons. Its connection with potential chlorine reservoirs and the related atmospheric chemistry is now of particular interest and actively studied. Measurements by the Atmospheric Chemistry Suite mid-infrared channel (ACS MIR) on the ExoMars Trace Gas Orbiter allow us to measure the ratio of hydrogen chloride two stable isotopologues, H35Cl and H37Cl. This work describes the observation, processing technique, and derived values for the chloride isotope ratio. Unlike other volatiles in the Martian atmosphere, because it is enriched with heavier isotopes, the δ37Cl is measured to be - 7 ± 20°, which is almost indistinguishable from the terrestrial ratio for chlorine. This value agrees with available measurements of the surface materials on Mars. We conclude that chlorine in observed HCl likely originates from dust and is not involved in any long-term, surface-atmosphere cycle.