Solar system

Abstract:

Cycling of carbon dioxide between the atmosphere and interior of rocky planets can stabilize global climate and enable planetary surface temperatures above freezing over geologic time. However, variations in global carbon budget and unstable feedback cycles between planetary sub-systems may destabilize the climate of rocky exoplanets toward regimes unknown in the Solar System. Here, we perform clear-sky atmospheric radiative transfer and surface weathering simulations to probe the stability of climate equilibria for rocky, ocean-bearing exoplanets at instellations relevant for planetary systems in the outer regions of the circumstellar habitable zone. Our simulations suggest that planets orbiting G- and F-type stars (but not M-type stars) may display bistability between an Earth-like climate state with efficient carbon sequestration and an alternative stable climate equilibrium where CO₂ condenses at the surface and forms a blanket of either clathrate hydrate or liquid CO₂. At increasing instellation and with ineffective weathering, the latter state oscillates between cool, surface CO₂-condensing and hot, non-condensing climates. CO₂ bistable climates may emerge early in planetary history and remain stable for billions of years. The carbon dioxide-condensing climates follow an opposite trend in pCO₂ versus instellation compared to the weathering-stabilized planet population, suggesting the possibility of observational discrimination between these distinct climate categories.

Abstract:

Carbon monoxide is a non-condensable gas in the Martian atmosphere produced by the photolysis of CO2. Its abundance responds to the condensation and sublimation of CO2 from the polar caps, resulting in seasonal variations of the CO mixing ratio. ACS onboard the ExoMars Trace Gas Orbiter have measured CO in infrared bands by solar occultation. Here we provide the first long-term monitoring of the CO vertical distribution at the altitude range from 0 to 80 km for 1.5 Martian years from Ls = 163° of MY34 to the end of MY35. We obtained a mean CO mixing ratio of ∼960 ppmv at latitudes from 45°S to 45°N and altitudes below 40 km, mostly consistent with previous observations. We found a strong enrichment of CO near the surface at Ls = 100–200° in high southern latitudes with a layer of 3,000–4,000 ppmv, corresponding to local depletion of CO2. At equinoxes we found an increase of the CO mixing ratio above 50 km to 3,000–4,000 ppmv at high latitudes of both hemispheres explained by the downwelling flux of the Hadley circulation on Mars, which drags the CO enriched air. General circulation models tend to overestimate the intensity of this process, bringing too much CO. The observed minimum of CO in the high and mid-latitudes southern summer atmosphere amounts to 700–750 ppmv, agreeing with nadir measurements. During the global dust storm of MY34, when the H2O abundance peaks, we see less CO than during the calm MY35, suggesting an impact of HOx chemistry on the CO abundance.