Exoplanet atmospheres

Abstract:

Hot Jupiters have temperature gradients of several hundreds of degrees between their permanent daysides and nightsides. Such a strong gradient creates winds with speeds of the order of kilometres per second, which advect chemical species over the whole planet. When this transport is faster than the time needed for chemical species to react, it holds back the chemical equilibration of the atmospheric carbon reservoir, which would otherwise transition from CO on the dayside to CH4 on the nightside. Direct evidence of this process has remained elusive so far, as it is often degenerate with other atmospheric processes, such as vertical mixing or non-stellar elemental abundances. Here we present observational evidence for such a fast day-to-night horizontal transport of chemical species by observing the full 18-h orbit of the exoplanet NGTS-10A b with the JWST/NIRSpec instrument. We show that the carbon chemistry is dominated by CO in both the dayside and the nightside of the planet, with a strong depletion of CH4 on the nightside compared with expectations from chemical equilibrium. By measuring the atmospheric abundances of all the main carbon and oxygen molecules, we further demonstrate that the lack of CH4 on the planetary nightside cannot be attributed to non-solar elemental abundances or to vertical mixing mechanisms and must, therefore, be due to fast horizontal transport. Our study shows the fundamental role that atmospheric transport plays in shaping the distribution of chemical species on exoplanet atmospheres.

Abstract:

With its expanded wavelength coverage and increased precision compared to previous space-based observatories, JWST provides the opportunity to revisit benchmark planets and view them in a new light. Here, we conduct an in-depth study of the atmosphere of the hot-Saturn WASP-96 b combining a new JWST NIRSpec/G395H transit with archival NIRISS/SOSS and Very Large Telescope/FORS2 transmission spectra. The combined spectrum shows clearly visible features from H2O, CO2, and Na. CO, though, remains unconstrained, precluding a firm metallicity derivation from free retrievals alone. However, self-consistent grids yield a broadly superstellar atmospheric metallicity of 2–6× stellar. When combined with a roughly stellar C/O ratio ( 0.41−0.09+0.10 from self-consistent grids), we find that WASP-96 b potentially formed via core-accretion beyond the H2O snowline and subsequently accreted volatile-rich material. Free retrievals also find a moderate preference ( lnB = 2.69) for models with SO2 versus without. WASP-96 b falls directly on the proposed “SO2 shoreline” and the retrieved SO2 abundance is well-matched to predictions from photochemical models. Our combined spectrum displays an optical slope, which our models fit with opacity from scattering aerosols—either small-particle condensate clouds or photochemical hazes—though we cannot completely rule out the broad wings of Na or the effects of stellar contamination. Future observations are necessary to disentangle these effects. Finally, we explore the possibility for limb asymmetry in WASP-96 b’s transmission spectrum and provide several tests to identify asymmetries in our data. We encourage the community to prioritize the development of a robust pathway to quantify the presence of limb asymmetry—particularly for low signal-to-noise cases.

Abstract:

Previous analysis of Neptune’s atmosphere using near-infrared Gemini/NIFS observations found the strongest spectral signature of hydrogen sulphide (HS) to be at the planet’s south pole. Conversely, analysis of microwave observations with the Atacama Large Millimeter/submillimeter Array in 2019 suggested a distribution of HS that peaks in the mid-latitudes and is strongly depleted towards the pole. We analyse near-infrared observations from VLT-SINFONI in 2018 and fit a parametrized cloud model to the data using nested sampling. By prescribing a latitudinally varying methane (CH) profile previously derived from visible light observations, we find general agreement with the microwave analysis, with an enhancement of HS by a factor of 4 at the southern mid-latitudes compared to polar latitudes. The stronger spectral signature at the pole is explained with a deeper cloud top, resulting in a higher cloud-top HS column abundance in this region. Our results are indicative of deep upwelling at the mid-latitudes, with downwelling at the pole and possibly near the equator.

Abstract:

The extreme conditions in Venus’s lower atmosphere make robust calibration of in situ observations challenging. Consequently, measurements from past entry probes provided mixed evidence regarding the existence of a near-surface particulate layer (NSPL). Although the Venera 11 (1978) and Venera 13 and 14 (1982) landers performed in situ spectrophotometric observations during descent, the original datasets were later lost. However, a subset has been reconstructed by digitising graphical outputs produced during the missions’ initial data-processing phase [1]. Following careful analysis to identify and mitigate errors and other artefacts, the reconstructed dataset retains the reliable downward-looking spectra acquired by the three landers from ~62 km altitude to the surface.Previous retrievals from the reconstructed Venera 13 indicated an NSPL centred at ~3.5–5 km, with particulate optical properties consistent with a basaltic composition [2]. Following the methodology of [2], we use NEMESIS, a radiative transfer and retrieval code [3], to perform near-surface retrievals from the reconstructed Venera 11 and Venera 14 datasets. The results from Venera 11, 13, and 14 retrievals are compared with reported detections and non-detections from other instruments on earlier in situ missions, to explore potential formation pathways for the NSPL in light of the combined observational record.References:[1] Ignatiev, N. I., Moroz, V. I., Moshkin, B. E., Ekonomov, A. P., Gnedykh, V. I., Grigor’ev, A. V., and Khatuntsev, I. V. Cosmic Research 35(1), 1–14 (1997).[2] Kulkarni, S. V., Irwin, P. G. J., Wilson, C. F., & Ignatiev, N. I. Journal of Geophysical Research: Planets, 130, e2024JE008728, (2025).[3] Irwin, P. G., Teanby, N. A., de Kok, R., Fletcher, L. N., Howett, C. J., Tsang, C. C., Wilson, C. F., Calcutt, S. B., Nixon, C. A., and Parrish, P. D. Journal of Quantitative Spectroscopy and Radiative Transfer 109(6), 1136–1150 (2008).