Novel Energy Materials and Advanced Characterisation

Abstract:

A. M. Glazer. A. M. Glazer CRYSTALLOGRAPHY A Very Short Introduction 1 Great Clarendon Street, Oxford, OX26DP, United Kingdom Oxford University Press Crystallography: A Very Short Introduction.

Abstract:

Solution-processed metal halide perovskite semiconductors, such as CH3NH3PbI3, have exhibited remarkable performance in solar cells, despite having non-negligible density of defect states. A likely candidate is halide vacancies within the perovskite crystals, or the presence of metallic lead, both generated due to the imbalanced I/Pb stoichiometry which could evolve during crystallization. Herein, we show that the addition of hypophosphorous acid (HPA) in the precursor solution can significantly improve the film quality, both electronically and topologically, and enhance the photoluminescence intensity, which leads to more efficient and reproducible photovoltaic devices. We demonstrate that the HPA can reduce the oxidized I2 back into I(-), and our results indicate that this facilitates an improved stoichiometry in the perovskite crystal and a reduced density of metallic lead.

Abstract:

Dye-sensitized TiO2 can be used as the active layer of solar-cell devices without an additional hole-transporting material. In this architecture, holes are transported through the dye monolayer.