Snaith group

Abstract:

Hybrid perovskites form an extremely attractive class of materials for large scale, low-cost photovoltaic applications. Fullerene-based charge extraction layers have emerged as a viable n-type charge collection layer, and in “inverted” p–i–n device architectures the solar cells are approaching efficiencies of 20%. However, the regular n–i–p devices employing fullerenes still lag behind in performance. Here, we show that partial solubility of fullerene derivatives in the aprotic solvents used for the perovskites makes it challenging to retain integral films in multilayer solution processing. To overcome this issue we introduce cross-linkable fullerene derivatives as charge collection layers in n–i–p planar junction perovskite solar cells. The cross-linked fullerene layers are insolubilized and deliver improved performance in solar cells enabled by a controllable film thickness.

Abstract:

Metal halide perovskites have emerged as one of the most promising materials for photovoltaics (PVs), with power conversion efficiency of over 22% already demonstrated. In order to compete with traditional crystalline silicon PV, cost and stability are equally important issues that need to be considered besides efficiency. Copper thiocyanate (CuSCN) is an interesting candidate to be used as an inexpensive, thermally stable p-type charge conducting material in perovskite solar cells. Here, we report 13% efficient perovskite solar cells employing CuSCN as the hole-transport material. We compare the stability of cells employing CuSCN with those employing the archetypical organic hole-transporter 2,2′,7,7′-Tetrakis (N,N-di-p-methoxyphenyl-amine) 9,9′-Spirobifluorene (Spiro-OMeTAD), under elevated temperature in ambient atmosphere. Surprisingly, we find that the devices employing CuSCN degrade faster under elevated temperatures than the devices employing Spiro-OMeTAD. We discover that an interfacial degradation mechanism occurs at the heterojunction between the perovskite absorber and the CuSCN, even in a dry nitrogen atmosphere, identifying the presence of a critical instability. Interestingly, with the additional coating of the completed cells with a thin film of insulating poly(methyl methacrylate) (PMMA), functioning as a rudimentary “on-cell” encapsulation, we significantly alleviate this issue and deliver efficient perovskite solar cells which survive for more than 1000 hours at 85 °C in air with only 25% degradation in performance. Beyond identifying a critical area to address in order to enable CuSCN to be useful for long term operation in perovskite solar cells, our findings indicate that the role of the “encapsulant” is to both keep the environment out, and keep degradation products within the cell.