Dynamics of liquid rope coiling.
Phys Rev E Stat Nonlin Soft Matter Phys 74:6 Pt 2 (2006) 066306
Abstract:
We present a combined experimental and numerical investigation of the coiling of a liquid "rope" falling on a solid surface, focusing on three little-explored aspects of the phenomenon: The time dependence of "inertio-gravitational" coiling, the systematic dependence of the radii of the coil and the rope on the experimental parameters, and the "secondary buckling" of the columnar structure generated by high-frequency coiling. Inertio-gravitational coiling is characterized by oscillations between states with different frequencies, and we present experimental observations of four distinct branches of such states in the frequency-fall height space. The transitions between coexisting states have no characteristic period, may take place with or without a change in the sense of rotation, and usually (but not always) occur via an intermediate "figure of eight" state. We present extensive laboratory measurements of the radii of the coil and of the rope within it, and show that they agree well with the predictions of a "slender-rope" numerical model. Finally, we use dimensional analysis to reveal a systematic variation of the critical column height for secondary buckling as a function of (dimensionless) flow rate and surface tension parameters.The pH-induced swelling and collapse of a polybase brush synthesized by atom transfer radical polymerization
Soft Matter 2:12 (2006) 1076-1080
Abstract:
We have used neutron reflectometry to characterize the swelling behaviour of brushes of poly[2-(diethyl amino)ethyl methacrylate], a polybase, as a function of pH. The brushes, synthesized by the "grafting from" method of atom transfer radical polymerization, were observed to approximately double their thickness in low pH solutions, although the pKa is shifted to a lower pH than in dilute solution. The composition-depth profile obtained from the reflectometry experiments for the swollen brushes reveals a region depleted in polymer between the substrate and the extended part of the brush. © The Royal Society of Chemistry.Chaos and residual correlations in pinned disordered systems.
Physical review letters 96:23 (2006) 235702
Abstract:
We study, using functional renormalization, two copies of an elastic system pinned by mutually correlated random potentials. Short scale decorrelation depends on a nontrivial boundary layer regime with (possibly multiple) chaos exponents. Large scale mutual displacement correlations behave as [x - x'](2zeta-mu), mu proportional to the difference between Flory (or mean field) and exact roughness exponents zeta. For short range disorder mu>0 and small; e.g., for random bond interfaces mu=5zeta-epsilon, epsilon=4-d, and mu=epsilon{[(2pi)(2)/36]-1} for the one component Bragg glass. Random field (i.e., long range) disorder exhibits finite residual correlations (no chaos mu=0) described by new functional renormalization fixed points. Temperature and dynamic chaos (depinning) are discussed.Counterions between charged polymers exhibit liquid-like organization and dynamics.
Proc Natl Acad Sci U S A 103:21 (2006) 7962-7967
Abstract:
Current understanding of electrostatics in water is based on mean-field theories like the Poisson-Boltzmann formalism and its approximations, which are routinely used in colloid science and computational biology. This approach, however, breaks down for highly charged systems, which exhibit counterintuitive phenomena such as overcharging and like-charge attraction. Models of counterion correlations have been proposed as possible explanations, but no experimental comparisons are available. Here, collective dynamics of counterions that mediate like-charge attraction between F-actin filaments have been directly observed in aqueous solution using high-resolution inelastic x-ray scattering down to molecular length-scales. We find a previously undescribed acoustic-like phonon mode associated with correlated counterions. The excitation spectra at high wave-vector Q reveal unexpected dynamics due to ions interacting with their "cages" of nearest neighbors. We examine this behavior in the context of intrinsic charge density variations on F-actin. The measured speed of sound and collective relaxation rates in this liquid agree surprisingly well with simple model calculations.Efficient in-depth trapping with an oil-immersion objective lens.
Opt Lett 31:6 (2006) 766-768