Glassy behaviour in a simple topological model
Journal of Physics A: Mathematical and General 33:48 (2000) 8615-8625
Abstract:
In this paper we study a simple, purely topological, cellular model which is allowed to evolve through a Glauber-Kawasaki process. We find a non-thermodynamic transition to a glassy phase in which the energy (defined as the square of the local cell topological charge) fails to reach the equilibrium value below a characteristic temperature which is dependent on the cooling rate. We investigate a correlation function which exhibits ageing behaviour, and follows a master curve in the stationary regime when time is rescaled by a factor of the relaxation time tr. This master curve can be fitted by a von Schweidler law in the late β-relaxation regime. The relaxation times can be well fitted at all temperatures by an offset Arrhenius law. A power law can be fitted to an intermediate-temperature regime; the exponent of the power law and the von Schweidler law roughly agree with the relationship predicted by mode-coupling theory. By defining a suitable response function, we find that the fluctuation-dissipation ratio is held until sometime later than the appearance of the plateaux; non-monotonicity of the response is observed after this ratio is broken, a feature which has been observed in other models with dynamics involving activated processes.Mean-field fluid behavior of the gaussian core model.
Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics 62:6 Pt A (2000) 7961-7972
Abstract:
We show that the Gaussian core model of particles interacting via a penetrable repulsive Gaussian potential, first considered by Stillinger [J. Chem. Phys. 65, 3968 (1976)], behaves as a weakly correlated "mean-field fluid" over a surprisingly wide density and temperature range. In the bulk, the structure of the fluid phase is accurately described by the random phase approximation for the direct correlation function, and by the more sophisticated hypernetted chain integral equation. The resulting pressure deviates very little from a simple mean-field-like quadratic form in the density, while the low density virial expansion turns out to have an extremely small radius of convergence. Density profiles near a hard wall are also very accurately described by the corresponding mean-field free-energy functional. The binary version of the model exhibits a spinodal instability against demixing at high densities. Possible implications for semidilute polymer solutions are discussed.Optical conductivity of the half-filled hubbard chain
Phys Rev Lett 85:18 (2000) 3910-3913