Exoplanet atmospheres

Abstract:

Titan, Saturn’s largest satellite, maintains an atmosphere composed primarily of nitrogen (N2) and methane (CH4) that leads to complex organic chemistry. Some of the nitriles (CN-bearing organics) on Titan are known to have substantially enhanced 15N abundances compared to Earth and Titan’s dominant nitrogen (N2) reservoir. The 14N/15N isotopic ratio in Titan’s nitriles can provide better constraints on the synthesis of nitrogen-bearing organics in planetary atmospheres as well as insights into the origin of Titan’s large nitrogen abundance. Using high signal-to-noise ratio (>13), disk-integrated observations obtained with the Atacama Large Millimeter/submillimeter Array Band 6 receiver (211–275 GHz), we measure the 14N/15N and 12C/13C isotopic ratios of acetonitrile (CH3CN) in Titan’s stratosphere. Using the NEMESIS, we derived the CH3CN/13CH3CN ratio to be 89.2 ± 7.0 and the CH3CN/CH313CN ratio to be 91.2 ± 6.0, in agreement with the 12C/13C ratio in Titan’s methane and other solar system species. We found the 14N/15N isotopic ratio to be 68.9 ± 4.2, consistent with previously derived values for HCN and HC3N, confirming an enhanced 15N abundance in Titan’s nitriles compared with the bulk atmospheric N2 value of 14N/15N = 168, in agreement with chemical models incorporating isotope-selective photodissociation of N2 at high altitudes.

Abstract:

Secondary eclipse observations of exoplanets at near-infrared wavelengths enable the detection of thermal emission and reflected stellar light, providing insights into the thermal structure and aerosol composition of their atmospheres. These properties are intertwined as aerosols influence the energy budget of the planet. WASP-80 b is a warm gas giant with an equilibrium temperature of 825 K orbiting a bright late-K/early-M dwarf, and for which the presence of aerosols in its atmosphere has been suggested from previous Hubble Space Telescope and Spitzer observations. We present an eclipse spectrum of WASP-80 b obtained with JWST NIRISS/SOSS, spanning 0.68–2.83 μm, which includes the first eclipse measurements below 1.1 μm for this exoplanet, extending our ability to probe light reflected by its atmosphere. When a reflected light geometric albedo is included in the atmospheric retrieval, our eclipse spectrum is best explained by a reflected light contribution of ∼30 ppm at short wavelengths, although further observations are needed to statistically confirm this preference. We measure a dayside brightness temperature of TB=811−70+69 K and constrain the reflected light geometric albedo across the SOSS wavelength range to Ag=0.204−0.056+0.051 , allowing us to estimate a 1σ range for the Bond albedo of 0.148 ≲ AB ≲ 0.383. By comparing our spectrum with aerosol models, we find that manganese sulfide and silicate clouds are disfavored, while cloud species with weak-to-moderate near-infrared reflectance, along with soots or low formation-rate tholin hazes, are consistent with our eclipse spectrum.