Exoplanet atmospheres

Abstract:

The mid-infrared channel of the Atmospheric Chemistry Suite (ACS MIR) onboard the ExoMars Trace Gas Orbiter is capable of observing the infrared absorption of ozone (O3) in the atmosphere of Mars. During solar occulations, the 003←000 band (3,000-3,060 cm−1) is observed with spectral sampling of ∼0.045 cm−1. Around the equinoxes in both hemispheres and over the southern winters, we regularly observe around 200–500 ppbv of O3 below 30 km. The warm southern summers, near perihelion, produce enough atmospheric moisture that O3 is not detectable at all, and observations are rare even at high northern latitudes. During the northern summers, water vapor is restricted to below 10 km, and an O3 layer (100–300 ppbv) is visible between 20 and 30 km. At this same time, the aphelion cloud belt forms, condensing water vapor and allowing O3 to build up between 30 and 40 km. A comparison to vertical profiles of water vapor and temperature in each season reveals that water vapor abundance is controlled by atmospheric temperature, and H2O and O3 are anti-correlated as expected. When the atmosphere cools, over time or over altitude, water vapor condenses (observed as a reduction in its mixing ratio) and the production of odd hydrogen species is reduced, which allows O3 to build up. Conversely, warmer temperatures lead to water vapor enhancements and ozone loss. The LMD Mars Global Climate Model is able to reproduce vertical structure and seasonal changes of temperature, H2O, and O3 that we observe. However, the observed O3 abundance is larger by factors between 2 and 6, indicating important differences in the rate of odd-hydrogen photochemistry.

Abstract:

Cycling of carbon dioxide between the atmosphere and interior of rocky planets can stabilize global climate and enable planetary surface temperatures above freezing over geologic time. However, variations in global carbon budget and unstable feedback cycles between planetary sub-systems may destabilize the climate of rocky exoplanets toward regimes unknown in the Solar System. Here, we perform clear-sky atmospheric radiative transfer and surface weathering simulations to probe the stability of climate equilibria for rocky, ocean-bearing exoplanets at instellations relevant for planetary systems in the outer regions of the circumstellar habitable zone. Our simulations suggest that planets orbiting G- and F-type stars (but not M-type stars) may display bistability between an Earth-like climate state with efficient carbon sequestration and an alternative stable climate equilibrium where CO₂ condenses at the surface and forms a blanket of either clathrate hydrate or liquid CO₂. At increasing instellation and with ineffective weathering, the latter state oscillates between cool, surface CO₂-condensing and hot, non-condensing climates. CO₂ bistable climates may emerge early in planetary history and remain stable for billions of years. The carbon dioxide-condensing climates follow an opposite trend in pCO₂ versus instellation compared to the weathering-stabilized planet population, suggesting the possibility of observational discrimination between these distinct climate categories.